1,731,035 research outputs found
Preferential concentration of particles in compressible turbulence
No full textThe behavior of particles in compressible turbulence has been seldom investigated to date despite its importance in many natural and industrial flows. Direct numerical simulations of particle-laden compressible isotropic turbulence are performed to study the preferential concentration of particles and the underling mechanisms. It turns out that heavy particles tend to concentrate in regions of low enstrophy and high fluid density (i.e, strain regions between vortex rings), especially the particles of Kolmogorov scale, which show the largest number density. Due to the compressibility, fluid particles do not distribute uniformly as in incompressible case, but show a tendency to bunch up in high density zones. The preliminary result might give some insights into compressible turbulent transport, dispersion and mixing as well as the subgrid-scale modeling for large-eddy simulation of particle-laden compressible flows
Observation and modelling for terrestrial processes in alpine meadow
No full textThe water-heat transfer process between land and atmosphere in Haibei alpine meadow area has been systematically observed. A multi-layer coupling model for land-atmosphere interaction was presented with special attention paid to the moisture transfer in leaf stomata under unsaturated condition. A profound investigation on the physical process of turbulent transfer inside the vegetation has been performed with a revised formula of water absorption for root system. The present model facilitates the study of vertically distributed physical variables in detail. Numerical simulation was conducted according to the transfer process of Kinesia humility meadow in the area of Haibei Alpine Meadow Ecosystem Station, CAS. The calculated results agree well with observation
Going Beyond Counting First Authors in Author Co-citation Analysis
Full text linkThe present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation
counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings
are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that
only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into
account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed
Synthesis, characterization and structural analysis of isostructural dinuclear molybdenum and tungsten oxo-bis-mu-sulfido-benzenedithiolene complexes
No full textReactions of the molybdenum and tungsten precursors [MO(2)S(2)](2) with equimolar amounts of benzenedithiol in acetonitrile give the title compounds [M(2)O(2)(mu-S)(2)(bdt)(2)](2) with M = Mo, W and bdt = benzenedithiolate. In case a tungsten to ligand ratio of 1:2 is used the dimer forms as well but only as a minor species whereas the monomer [WO(bdt)(2)](2) is the main product. In both dimeric compounds the syn-isomers are formed referring to the position of the apical oxo ligands with respect to the M(2)S(2) plane. For the molybdenum compound this contrasts with a published crystal structure of the anti-isomer. Both complexes give highly symmetric isomorphous crystals but still show subtle differences in their bond lengths and angles around the central metal. The X-ray crystal structures of both are analyzed in detail and compared with each other and with the isomeric molybdenum compound. Differences and similarities between tungsten and both isomers of molybdenum complexes are shown to be more influenced by the conformation than by the central metal and a reason for the formation of syn- and anti-isomers based on the respective synthetic procedures is proposed. (C) 2010 Elsevier B.V. All rights reserved.DFG (Deutsche Forschungsgemeinschaft
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