629 research outputs found

    Dissemination of innovative teaching and learning practice : the global studio

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    This project aims to disseminate teaching and learning resources from an innovative programme called the Global Studio to the ADM-HEA community. The area of innovation developed in the Global Studio was to link student teams across the globe in ‘designer’ and ‘client’ roles in order to undertake a product development project. This built on and extended the learning philosophy of learning in and through doing provided in a more traditional design studio. Throughout the project students worked in geographically distributed work groups in order to provide them with experience in using skills that would enable them to work successfully in distributed design teams

    Simple, controllable and environmentally friendly synthesis of FeCoNiCuZn-based high-entropy alloy (HEA) catalysts, and their surface dynamics during nitrobenzene hydrogenation

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    High-entropy alloys (HEAs) have rapidly become one of the hottest research topics in several fields, including materials science, corrosion technology, and catalysis because of their multiple advantages and their potential applications. In this study, using a novel straightforward electroless deposition method, multi-elemental alloys (FeCoNiCuZn) supported on graphite were prepared with controlled metal loading (HEA/g-X; X = 40, 80, 100) without any high temperature post-treatments. These materials were characterized using scanning electron microscopy, transmission electron microscopy, energy-dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, and X-ray diffraction, and showed a composition ranging from 11 at.% to 31 at.% for each metallic element, a total metal loading varying from 1.3 to 5.2 at.% (5.9 to 21.5 wt.%), homogeneous distribution, and an amorphous structure. Electrochemical impedance spectroscopy, cyclic voltammetry, linear sweep voltammetry, and chronoamperometry were used to evaluate the surface dynamics and the effect of the solution pH during the electrochemical hydrogenation of nitrobenzene using the HEA/g-40 material. The nitrobenzene conversion (>9 mmolNB gcat-1 h−1) and aniline production (≈ 4 mmolAN gcat-1 h−1) rates in Na2SO4 solution (at −1.0 V vs. Ag/AgCl) demonstrated a strong dependence on the applied potential. After comparing the results in alkaline medium (KOH), a competitive adsorption of species (nitrobenzene and H2O) was observed, showing a synergistic effect that greatly improved the selectivity of the nitrobenzene hydrogenation to aniline, from 23% in Na2SO4 to an outstanding 94% in KOH at the same applied potential, surpassing the results of a platinum electrode (34% in KOH). These results provide insightful information regarding the nature of the active sites involved in each step of the reaction mechanism, and gives useful means to develop new, tailored multifunctional HEA electrocatalyst materials.Green Open Access added to TU Delft Institutional Repository 'You share, we take care!' - Taverne project https://www.openaccess.nl/en/you-share-we-take-care Otherwise as indicated in the copyright section: the publisher is the copyright holder of this work and the author uses the Dutch legislation to make this work public.Micro and Nano Engineerin

    The urban environment : agendas and problems

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    The United Nations estimate that by 2025 there will be around 5 billion people living in urban areas, more than the total world population 20 years ago. Currently, the developed nations are the most urbanised with, on average around three-quarters of their population living in cities, but this is changing. Increased levels of economic growth, of migration, of population expansion and, in some cases, of unprecedented industrial growth, mean that Asia and Africa will be the regions most radically affected by urban development over the next twenty years. Increasing debate on issues of urban sustainability has led to the consolidation of environmental agendas and the definition of a specific body of problems and policy issues on two levels. The first involves green agenda problems occupying the concerns of many in the developed nations such as global warming, ozone-layer depletion, loss of bio-diversity, deforestation, and the exhaustion of non-renewable resources. For the developing world, however, these global environmental problems are less immediate than the need to resolve acute problems relating to poverty and the so-called brown agenda problems of air and water pollution, inadequate waste management, the lack of basic services and green areas, declining infrastructure, and poor housing conditions, as well as issues of health, crime, violence, and social exclusion. It is now a commonly held belief that the green agenda cannot be addressed until the urgent problems of urban social deprivation and inequalities are resolved. This paper reviews the scale and character of contemporary urbanisation and the rapid growth of cities, particularly within the developing nations, and examines associated implications with respect to the physical arrangement of cities, their resource consumption and their environmental impact

    Working at the edges

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    In this short article, the author explains how approaches to programme philosophy, curriculum structure and assessment design have liberated students to work creatively at the edges of their disciplines where they intersect with others. The article outlines the development of a Masters programme in Multidisciplinary Design Innovation

    Learning Development and Education for Sustainability: what are the links?

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    Learning Development (LD) is an emerging discipline developing a unique disciplinary identity. In common with many other new fields, it considers its position and relevance to other disciplines and bodies of thought, and in particular, educational development, applied linguistics and the sociology and philosophy of education. This paper considers one such area of debate: the link between Learning Development and Education for Sustainability (EfS). EfS is an area of pedagogic practice and a field of enquiry of considerable and growing importance in Higher Education (HE) and universities. Its underpinning systemic and epistemic philosophies suggest the need for integration across all facets of university activity, including LD. In this paper, we argue that there are identifiable links between LD and EfS that extend these philosophies, practices and fields of enquiry, characterised by the following: 1) commonalities surrounding the foci of their pedagogic practices, 2) shared methodologies for undertaking their practices, and 3) ways in which these methodologies are helping to situate both professions and disciplines within organisational contexts. The commonalities and possible distinctions between LD and EfS form a starting point for discussion, and raise the possibility that explicit identification of the links may encourage increased collaboration between the respective communities of practice, and the development of new ideas and innovative practice

    Scalability analysis of radical technologies to various aircraft class: Part 2: Sensitivity Analysis

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    This study aims at providing a landscape of opportunities and limitations for hybrid-electric aircraft (HEA) and hydrogen-powered aircraft by investigating several technological combinations applied to three aircraft classes: Regional (REG), Short-Medium Range (SMR) and Large Passenger Aircraft (LPA). The preliminary sizing of HEA using different hybrid-electric powertrain architectures, combined with various distributed propulsion layouts is conducted. The resulting HEA are then compared to a conventional design, on the basis of several performance metrics, for variations in harmonic range and passenger capacity. Throughout the design space considered, it is found that opportunities for radical aircraft design are scarce and offer limited prospective.<br/

    Educational environmental geoscience e-gaming to provide stimulating and effective learning

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    Current Higher Education students mostly comprise so-called Generation Y who have grown up with personal computer and e-gaming technologies. As such, they may respond positively to educational gaming as stimulating and effective complementary learning tools. This paper reports on evaluation of an environmental geoscience e-game developed with other complementary learning technologies for a final year option module for GEES-subject undergraduate students. The e-game was based on an author-published academic article. Semi-quantitative and qualitative evaluation evidences this was an effective approach and complemented more traditional educational learning methods, with a high level of student engagement, including, unexpectedly, with the academic article

    Impact on contrails coverage when flying with hybrid electric aircraft

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    iation is responsible for approximately 5% of global warming and is expected to increase substantially in the future. In the face of the continuing expansion of air traffic, mitigation of the aviation’s climate impact becomes challenging, but imperative. Among various mitigation options, hybrid electric aircraft (HEA) has drawn intensive attention due to its large potential in reducing the greenhouse gas emissions. The non-CO2 effects (especially the contrails) of the HEA on the climate change, however, remains ambiguous. As the first step to understand the climate impact of HEA, this research aims to investigate the impact on the formation of persistent contrails when flying with HEA. The simulation is performed using the Earth System model (EMAC) coupled with a CONTRAIL submodel, where the Schmidt Appleman Criterion (SAC) is adapted to estimate changes in the potential contrail coverage (PCC) globally. The analysis shows that the HEA forms contrails at relatively lower temperature than conventional aircraft. At the same altitude, the reduction in contrails formation is mainly observed in the tropical regions where the temperature is warmer. With a smaller fraction of electric power in use, the contrail coverage remains nearly unchanged. As the degree of hybridization increases further to 90%, an exponential reduction in the contrail formation is expected with a maximum value of about 40%.Aircraft Noise and Climate Effect

    On Perspective for Painting

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    perspective drawing, human hea

    Impact of Hybrid-Electric Aircraft on Contrail Coverage

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    Aviation is responsible for approximately 5% of global warming and is expected to increase substantially in the future. Given the continuing expansion of air traffic, mitigation of aviation’s climate impact becomes challenging but imperative. Among various mitigation options, hybrid-electric aircraft (HEA) have drawn intensive attention due to their considerable potential in reducing greenhouse gas emissions (e.g., CO2). However, the non-CO2 effects (especially contrails) of HEA on climate change are more challenging to assess. As the first step to understanding the climate impact of HEA, this research investigates the effects on the formation of persistent contrails when flying with HEA. The simulation is performed using an Earth System Model (EMAC) coupled with a submodel (CONTRAIL), where the contrail formation criterion, the Schmidt–Appleman criterion (SAC), is adapted to globally estimate changes in the potential contrail coverage (PCC). We compared the HEA to conventional (reference) aircraft with the same characteristics, except for the propulsion system. The analysis showed that the temperature threshold of contrail formation for HEA is lower; therefore, conventional reference aircraft can form contrails at lower flight altitudes, whereas the HEA does not. For a given flight altitude, with a small fraction of electric power in use (less than 30%), the potential contrail coverage remained nearly unchanged. As the electric power fraction increased, the reduction in contrail formation was mainly observed in the mid-latitudes (30° N and 40° S) or tropical regions and was very much localized with a maximum value of about 40% locally. The analysis of seasonal effects showed that in non-summer, the reduction in contrail formation using electric power was more pronounced at lower flight altitudes, whereas in summer the changes in PCC were nearly constant with respect to altitude
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