1,721,171 research outputs found
Reversing the Resistivity Contrast in the Phase-Change Memory Material GeSb2Te4 Using High Pressure
No full textPhase-change memory devices distinguish "1" and "0" states by the electrical contrast between the amorphous and the crystalline phases. Under ambient conditions, the amorphous phase normally exhibits a higher resistivity, exceeding its crystalline counterpart by 2-5 orders of magnitude. Here, however, it is demonstrated that such pronounced resistivity contrast is remarkably reduced and even reversed with increasing hydrostatic-like pressure in the prototypical phase-change material GeSb2Te4 (GST). This anomalous resistivity reversal originates from the differences in the pressure-induced atomic rearrangement of these two phases, as revealed by ab initio molecular dynamics simulations. Specifically, a low to medium pressure (<7 GPa) primarily compresses the bonds in crystalline GST without significantly displacing the atoms and vacancies off the lattice sites. As a result, only relatively small changes in the band structure are induced. In contrast, in amorphous GST, the fraction of voids changes drastically with pressure and the Peierls-like distortion is greatly reduced, yet the average bond length remains almost constant. These effects eventually turn the semiconducting glass into a metallic one. Our work reveals distinct behaviors of amorphous and crystalline phase-change materials under stress, shedding light on the mechanisms of electronic transport in different phases, and thus may have important implications on the design of phase-change memory devices
Changes of Structure and Bonding with Thickness in Chalcogenide Thin Films
Full text linkExtreme miniaturization is known to be detrimental for certain properties, such as ferroelectricity in perovskite oxide films below a critical thickness. Remarkably, few-layer crystalline films of monochalcogenides display robust in-plane ferroelectricity with potential applications in nanoelectronics. These applications critically depend on the electronic properties and the nature of bonding in the 2D limit. A fundamental open question is thus to what extent bulk properties persist in thin films. Here, this question is addressed by a first-principles study of the structural, electronic, and ferroelectric properties of selected monochalcogenides (GeSe, GeTe, SnSe, and SnTe) as a function of film thickness up to 18 bilayers. While in selenides a few bilayers are sufficient to recover the bulk behavior, the Te-based compounds deviate strongly from the bulk, irrespective of the slab thickness. These results are explained in terms of depolarizing fields in Te-based slabs and the different nature of the chemical bond in selenides and tellurides. It is shown that GeTe and SnTe slabs inherit metavalent bonding of the bulk phase, despite structural and electronic properties being strongly modified in thin films. This understanding of the nature of bonding in few-layers structures offers a powerful tool to tune materials properties for applications in information technology
Effects of stoichiometry on the transport properties of crystalline phase-change materials
No full textIt has recently been shown that a metal-insulator transition due to disorder occurs in the crystalline state of the GeSb2Te4 phase-change compound. The transition is triggered by the ordering of the vacancies upon thermal annealing. In this work, we investigate the localization properties of the electronic states in selected crystalline (GeTe)(x)-(Sb2Te3)(y) compounds with varying GeTe content by large-scale density functional theory simulations. In our models, we also include excess vacancies, which are needed to account for the large carrier concentrations determined experimentally. We show that the models containing a high concentration of stoichiometric vacancies possess states at the Fermi energy localized inside vacancy clusters, as occurs for GeSb2Te4. On the other hand, the GeTe-rich models display metallic behavior, which stems from two facts: a) the tail of localized states shrinks due to the low probability of having sizable vacancy clusters, b) the excess vacancies shift the Fermi energy to the region of extended states. Hence, a stoichiometry-controlled metal-insulator transition occurs. In addition, we show that the localization properties obtained by scalar-relativistic calculations with gradient-corrected functionals are unaffected by the inclusion of spin-orbit coupling or the use of hybrid functionals
Going Beyond Counting First Authors in Author Co-citation Analysis
Full text linkThe present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation
counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings
are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that
only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into
account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed
Variations on the Author
Full text link“Variations on the Author” discusses two of Eduardo Coutinho’s recent films (Um Dia na Vida, from 2010, and Últimas Conversas, posthumously released in 2015) and their contribution to the general question of documentary authorship. The director’s filmography is characterized by a consistent yet self-effacing form of authorial self-inscription: Coutinho often features as an interviewer that rather than express opinions propels discourses; an interviewer that is good at listening. This mode of self-inscription characterizes him as an author who is not expressive but who is nonetheless markedly present on the screen. In Um Dia na Vida, however, Coutinho is completely absent form the image, while Últimas Conversas, on the contrary, includes a confessional prologue that moves the director from the margins to the center of his films. This article examines the ways in which these works stand out in the filmography of a director who offers new insights into the notion of cinematic authorship
Appropriate Similarity Measures for Author Cocitation Analysis
Full text linkWe provide a number of new insights into the methodological discussion about author cocitation analysis. We first argue that the use of the Pearson correlation for measuring the similarity between authors’ cocitation profiles is not very satisfactory. We then discuss what kind of similarity measures may be used as an alternative to the Pearson correlation. We consider three similarity measures in particular. One is the well-known cosine. The other two similarity measures have not been used before in the bibliometric literature. Finally, we show by means of an example that our findings have a high practical relevance.information science;Pearson correlation;cosine;similarity measure;author cocitation analysis
Designing crystallization in phase-change materials for universal memory and neuro-inspired computing
No full textThe global demand for data storage and processing has increased exponentially in recent decades. To respond to this demand, research efforts have been devoted to the development of non-volatile memory and neuro-inspired computing technologies. Chalcogenide phase-change materials (PCMs) are leading candidates for such applications, and they have become technologically mature with recently released competitive products. In this Review, we focus on the mechanisms of the crystallization dynamics of PCMs by discussing structural and kinetic experiments, as well as ab initio atomistic modelling and materials design. Based on the knowledge at the atomistic level, we depict routes to improve the parameters of phase-change devices for universal memory. Moreover, we discuss the role of crystallization in enabling neuro-inspired computing using PCMs. Finally, we present an outlook for future opportunities of PCMs, including all-photonic memories and processors, flexible displays with nanopixel resolution and nanoscale switches and controllers
Dispelling the Myths Behind First-author Citation Counts
Full text linkWe conducted a full-scale evaluative citation analysis study of scholars in the XML research field to explore just how different from each other author rankings resulting from different citation counting methods actually are, and to demonstrate the capability of emerging data and tools on the Web in supporting more realistic citation counting methods. Our results contest some common arguments for the continued
use of first-author citation counts in the evaluation of scholars, such as high correlations between author rankings by first-author citation counts and other citation
counting methods, and high costs of using more realistic citation counting methods that are not well-supported by the ISI databases. It is argued that increasingly available digital full text research papers make it possible for citation analysis studies to go beyond what the ISI databases have directly supported and to employ more
sophisticated methods
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