1,721,511 research outputs found
JGIXA — A software package for the calculation and fitting of grazing incidence X-ray fluorescence and X-ray reflectivity data for the characterization of nanometer-layers and ultra-shallow-implants
No full textAbstractGrazing incidence XRF (GIXRF) is a very surface sensitive, nondestructive analytical tool making use of the phenomenon of total external reflection of X-rays on smooth polished surfaces. In recent years the method experienced a revival, being a powerful tool for process analysis and control in the fabrication of semiconductor based devices. Due to the downscaling of the process size for semiconductor devices, junction depths as well as layer thicknesses are reduced to a few nanometers, i.e. the length scale where GIXRF is highly sensitive. GIXRF measures the X-ray fluorescence induced by an X-ray beam incident under varying grazing angles and results in angle dependent intensity curves. These curves are correlated to the layer thickness, depth distribution and mass density of the elements in the sample. But the evaluation of these measurements is ambiguous with regard to the exact distribution function for the implants as well as for the thickness and density of nanometer-thin layers. In order to overcome this ambiguity, GIXRF can be combined with X-ray reflectometry (XRR). This is straightforward, as both techniques use similar measurement procedures and the same fundamental physical principles can be used for a combined data evaluation strategy. Such a combined analysis removes ambiguities in the determined physical properties of the studied sample and, being a correlative spectroscopic method, also significantly reduces experimental uncertainties of the individual techniques.In this paper we report our approach to a correlative data analysis, based on a concurrent calculation and fitting of simultaneously recorded GIXRF and XRR data. Based on this approach we developed JGIXA (Java Grazing Incidence X-ray Analysis), a multi-platform software package equipped with a user-friendly graphic user interface (GUI) and offering various optimization algorithms. Software and data evaluation approach were benchmarked by characterizing metal and metal oxide layers on Silicon as well as Arsenic implants in Silicon. The results of the different optimization algorithms have been compared to test the convergence of the algorithms. Finally, simulations for Iron nanoparticles on bulk Silicon and on a W/C multilayer are presented, using the assumption of an unaltered X-ray Standing Wave above the surface
Implementing light elements detection and quantification in aluminosilicate materials using a Low-Z total-reflection X-ray fluorescence spectrometer
Full text linkTotal-reflection X-ray fluorescence (TXRF) is a well-established atomic spectroscopy technique used for the elemental characterization of different kinds of matrixes in several fields. Previous works demonstrated its applicability for the elemental quantification of aluminosilicates and, in particular, clays. However, one of the limits of the previously developed methods was the detection and quantification of light elements, in particular for those elements with an atomic number (Z) below 13 (Al). In the present work a new TXRF-based analytical method for the quantification of light elements in aluminosilicate materials is described, using an in-house built Low-Z TXRF spectrometer equipped with a Cr source, a multilayer monochromator, an SDD detector equipped with an ultrathin Si3N4 window and a vacuum chamber. Samples were prepared as simple slurries (dispersing 50 mg of powder into 2.5 mL of 1%-Triton X-100 water solution and adding Ag as internal standard) and 10 mu L were deposited onto a quartz carrier and dried before the analysis. Light elements such as F, Na and Mg were quantified with a limit of detection of 682, 260 and 133 mg/kg, respectively. Carbon and oxygen could also be detected. The new method allowed a complete analysis of major elements in aluminosilicates from F to Fe. The method showed a good accuracy in the range of 80-120% and the results agreed with the data obtained with a commercial TXRF spectrometer (for elements >13) and WDXRF, employed as reference methods. Despite a lower precision in respect to WDXRF, in some samples the quantification of F was possible only by using the Low-Z TXRF spectrometer. Finally, the method demonstrated to be suitable for the analysis of aluminosilicates, in particular when low amounts of sample (few milligrams) are available
Going Beyond Counting First Authors in Author Co-citation Analysis
Full text linkThe present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation
counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings
are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that
only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into
account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed
Variations on the Author
Full text link“Variations on the Author” discusses two of Eduardo Coutinho’s recent films (Um Dia na Vida, from 2010, and Últimas Conversas, posthumously released in 2015) and their contribution to the general question of documentary authorship. The director’s filmography is characterized by a consistent yet self-effacing form of authorial self-inscription: Coutinho often features as an interviewer that rather than express opinions propels discourses; an interviewer that is good at listening. This mode of self-inscription characterizes him as an author who is not expressive but who is nonetheless markedly present on the screen. In Um Dia na Vida, however, Coutinho is completely absent form the image, while Últimas Conversas, on the contrary, includes a confessional prologue that moves the director from the margins to the center of his films. This article examines the ways in which these works stand out in the filmography of a director who offers new insights into the notion of cinematic authorship
Appropriate Similarity Measures for Author Cocitation Analysis
Full text linkWe provide a number of new insights into the methodological discussion about author cocitation analysis. We first argue that the use of the Pearson correlation for measuring the similarity between authors’ cocitation profiles is not very satisfactory. We then discuss what kind of similarity measures may be used as an alternative to the Pearson correlation. We consider three similarity measures in particular. One is the well-known cosine. The other two similarity measures have not been used before in the bibliometric literature. Finally, we show by means of an example that our findings have a high practical relevance.information science;Pearson correlation;cosine;similarity measure;author cocitation analysis
Dispelling the Myths Behind First-author Citation Counts
Full text linkWe conducted a full-scale evaluative citation analysis study of scholars in the XML research field to explore just how different from each other author rankings resulting from different citation counting methods actually are, and to demonstrate the capability of emerging data and tools on the Web in supporting more realistic citation counting methods. Our results contest some common arguments for the continued
use of first-author citation counts in the evaluation of scholars, such as high correlations between author rankings by first-author citation counts and other citation
counting methods, and high costs of using more realistic citation counting methods that are not well-supported by the ISI databases. It is argued that increasingly available digital full text research papers make it possible for citation analysis studies to go beyond what the ISI databases have directly supported and to employ more
sophisticated methods
2D-XRF-imaging of biological samples in scattering matrix
Full text linkDiese Diplomarbeit beschreibt die Entwicklung eines Röntgenfluoreszenzscanners (XRF- Scanner)für zweidimensionale biologische Proben mit Flüssigkeits-und Lufteinschlüssen. Durch diesen optimalen Aufbau kann Streustrahlung, die in der Matrix entsteht, reduziert werden. Anwendung findet der XRF Scanner bei der Untersuchung von Elektrophorese-Gel, welches zuvor mit Metalloproteinen befüllt wird.Der Scanner ermöglicht die Untersuchung von Proben mit der Große von 120mm x 180mm. Durch geeignete Wahl eines Kollimators ist die zweidimensionale Auflösung einer Pixelgröße von 3mm und 6mm möglich. Der XRF Scanner zeichnet sich durch seinen kompakten und stabilen Aufbau aus und liefert eine durch Farbcodierung übersichtliche zweidimensionale Elementverteilung
koamabayili/VECTRON-author-checklist: VECTRON author checklist
No full textWe have done our best to complete the author checklist relating to the use of animals in the hut study. Note that the objective for the hut study was to evaluate the IRS treatment applications for residual efficacy against Anopheles mosquitoes, including the local An. coluzzii mosquito population. Cows were only used to attract mosquitoes into the huts and no tests were carried out directly on the cows. The author checklist is intended for use with studies where experiments are carried out on animals, which is why we have had such difficulty in completing this for the hut study, as many of the questions do not relate to how the cows were used
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