1,721,032 research outputs found

    Palaeomagnetic, astrochronological, and environmental magnetic perspective on Oligocene-Miocene climate, using drift sediments from the northwest Atlantic Ocean

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    The Antarctic ice sheet oscillated between nearly deglaciated and near-­‐modern proportions, sometimes within ~110 kyr, during transient glacial phases of the Oligocene-­‐Miocene icehouse world (5.33-­‐33.9 Ma). Ice sheet hysteresis is closely coupled with carbon-­‐cycle feedback mechanisms that are strongly affected by ocean circulation. However, the absence of high-­‐resolution records representing the North Atlantic end member, a key region driving modern climate variability and ocean circulation, hamper full understanding of Oligocene-­‐Miocene ocean circulation and climate. In this thesis, I integrate palaeomagnetic, X-­‐ray fluorescence (XRF), and environmental magnetic records to date and reconstruct current variability from contourite drift sediments, recovered at Integrated Ocean Drilling Program (IODP) Site U1406 (northwest Atlantic). The revised splice ensures stratigraphic continuity for the studied section. The presented novel palaeomagnetic data processing protocol, which is applicable to all weakly magnetised sediments, ensures the use of only high quality directional data for the construction of a reliable magnetostratigraphy between Chrons C6Ar – C9n (21-­‐27 Ma). Astronomical tuning using XRF-­‐based ln(Ca/K), a proxy for CaCO3 content, provides independent dates for the identified geomagnetic reversals. I determine the best age estimates of reversals using a set of criteria to reconcile the Oligocene-­‐Miocene geomagnetic polarity time scale. Congruent obliquity-­‐paced CaCO3 cycles at Ocean Drilling Program Site 926 (equatorial Atlantic) and IODP Site U1406 suggest that one corrosive bottom water mass influences the CaCO3 content of the boreal Atlantic. The location and occurrence of contourite drift sediments at IODP Site U1406 advocates that the Deep Western Boundary Current (DWBC) is the candidate for such corrosive bottom waters. DWBC variability around the Oligocene-­‐Miocene Transition (~23 Ma) is traced using the detrital magnetic fraction, containing titanohaematite, recognised through detailed rock and environmental magnetic measurements. During the last ca. 1 Myr of the Oligocene, the decrease in CaCO3-­‐corrected concentration and coercivity of titanohaematite indicates an invigorated DWBC. If these characteristics of the DWBC are substantiated, this will have major implications for CO2 reconstructions on orbital time scales and Oligocene-­‐Miocene climate models

    Rotated declination, intensity and MAD of IODP Site 342-U1406

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    In supplement to: van Peer, TE et al. (2017): Extracting a Detailed Magnetostratigraphy From Weakly Magnetized, Oligocene to Early Miocene Sediment Drifts Recovered at IODP Site U1406 (Newfoundland Margin, Northwest Atlantic Ocean). Geochemistry, Geophysics, Geosystems, 18(11), 3910-3928</span

    Geochemical evidence of Milankovitch cycles in Atlantic Ocean ferromanganese crusts

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    Hydrogenetic ferromanganese crusts are considered a faithful record of the isotopic composition of seawater influenced by weathering processes of continental masses. Given their ubiquitous presence in all oceans of the planet at depths of 400–7000 meters, they form one of the most well-distributed and accessible records of water-mass mixing and climate. However, their slow accumulation rate and poor age constraints have to date limited their use to explore 100 ka paleoclimatic phenomena. Here it is shown how the Pb isotope signature and major element content of a Fe-Mn crust from the north-east Atlantic responded to changes in the intensity and geographic extent of monsoonal rainfall over West Africa, as controlled by climatic precession during the Paleocene. The studied high-spatial resolution (4 μm) laser-ablation multi-collector inductively coupled plasma mass spectrometer (LA-MC-ICP-MS) Pb isotope data is a nearly 2 order of magnitude improvement in spatial and temporal resolution compared to micro-drill subsamples. The record demonstrates cyclicity of the 206Pb/204Pb and 208, 207Pb/206Pb ratios at the scale of single Fe-Mn oxide laminae, in conjunction with variations in the Fe/Mn ratio, Al, Si and Ti content. Time-frequency analysis and astronomical tuning of the Pb isotope data demonstrates the imprint of climatic precession (∼20 ka) modulated by eccentricity (∼100 and 405 ka), yielding growth rates of 1.5–3.5 mm/Ma consistent with previous chemostratigraphic age models. In this context, boreal summer at the perihelion causes stronger insolation over West Africa, resulting in more intense and geographically extended monsoonal rainfalls compared to aphelion boreal summer conditions. This, in turn, influences the balance between the weathering endmembers feeding the north-east Atlantic basin. These results provide a new approach for calibrating Fe-Mn crust records to astronomical solutions, and allow their isotopic and chemical archive to be exploited with an improved temporal resolution of 1000–5000 years

    Extracting a detailed magnetostratigraphy from weakly magnetized, Oligocene to early Miocene sediment drifts recovered at IODP Site U1406 (Newfoundland margin, northwest Atlantic Ocean)

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    Fine-grained magnetic particles in deep-sea sediments often statistically align with the ambient magnetic field during (and shortly after) deposition and can therefore record geomagnetic reversals. Correlation of these reversals to a geomagnetic polarity time scale is an important geochronological tool that facilitates precise stratigraphic correlation and dating of geological records globally. Sediments often carry a remanence strong enough for confident identification of polarity reversals, but in some cases a low signal-to-noise ratio prevents the construction of a reliable and robust magnetostratigraphy. Here we implement a data-filtering protocol, which can be integrated with the UPmag software package, to automatically reduce the maximum angular deviation and statistically mask noisy data and outliers deemed unsuitable for magnetostratigraphic interpretation. This protocol thus extracts a clearer signal from weakly magnetized sediments recovered at Integrated Ocean Drilling Program (IODP) Expedition 342 Site U1406 (Newfoundland margin, northwest Atlantic Ocean). The resulting magnetostratigraphy, in combination with shipboard and shore-based biostratigraphy, provides an age model for the study interval from IODP Site U1406 between Chrons C6Ar and C9n (∼21-27 Ma). We identify rarely observed geomagnetic directional changes within Chrons C6Br, C7r, and C7Ar, and perhaps within Subchron C8n.1n. Our magnetostratigraphy dates three intervals of unusual stratigraphic behavior within the sediment drifts at IODP Site U1406 on the Newfoundland margin. These lithostratigraphic changes are broadly concurrent with the coldest climatic phases of the middle Oligocene to early Miocene and we hypothesize that they reflect changes in bottom-water circulation

    Oligo-Miocene oxygen isotope and carbon record from IODP Site 342-U1406

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    These data contain a new high-resolution benthic foraminiferal oxygen isotope (d18Ob) record spanning ~26-22 Ma from Integrated Ocean Drilling Program Expedition 342 Site U1406 (Newfoundland Margin, Northwest Atlantic Ocean, ~40°N, 51°W; 3.8 km water depth). Oxygen isotopes of Cibicidoides mundulus (size range 125-250 micrometer) were generated using a Thermo Fisher Scientific MAT 253 mass-spectrometer coupled to a Thermo-Finnigan Kiel IV Carbonate Device in Southampton, Heidelberg, and Leipzig, and coupled to a Gasbench II in Frankfurt. International standards (NBS-18 and NBS-19) and in-house quality control standards were used to calibrate d18Ob. The record was astronomically tuned by recognising obliquity cycles in the X-ray fluorescence based CaCO3 record using newly generated coulometric carbonate content data (wt.% CaCO3), generated at the University of Southampton's Waterfront Campus, National Oceanography Centre Southampton (UoS-NOCS), using a CM5015 coulometer equipped with an AutoMate automated analysis devic

    Evaluation of geomagnetic relative palaeointensity as a chronostratigraphic tool in the Southern Ocean: Refined Plio-/Pleistocene chronology of IODP Site U1533 (Amundsen Sea, West Antarctica)

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    International Ocean Discovery Program (IODP) Expedition 379 to the Amundsen Sea margin of West Antarctica recovered drill cores at two sites spanning the Latest Miocene–Holocene interval with the aim of reconstructing past West Antarctic Ice Sheet dynamics. The recovered Plio-/Pleistocene sediment sequences offer an opportunity to apply and test different dating approaches in an Antarctic deep-sea drift setting, where the records are nearly continuous and unaffected by scouring of icebergs or grounded ice. Here, through palaeomagnetic analysis of continuous u-channel samples and application of X-ray fluorescence (XRF) scanning, we revise the IODP Exp. 379 Site U1533 age model for the uppermost Pliocene and Pleistocene composite interval (0.0–2.9 Ma). We first refine the magnetostratigraphic age model with high-resolution u-channel analysis and interpreted directional data. Consistent with shipboard results, all major geomagnetic polarity chrons and subchrons are identified in the Pleistocene section. The new high-resolution u-channel dataset also allows us to identify a geomagnetic polarity excursion at ∼884 ka (interpreted as the Kamikatsura excursion) and another excursion at ∼2734 ka with confidence (potentially the Porcupine excursion). Based on the improved polarity stratigraphy, we then develop two new highly resolved age models for Site U1533 using: (i) barium enrichment cycles identified in XRF scanning data, and (ii) geomagnetic relative palaeointensity (RPI). In our first age model, we correlate cyclic variations in sedimentary barium enrichment, inferred to represent changes in export productivity, to glacial‒interglacial cycles of the Lisiecki and Raymo (2005) benthic foraminiferal oxygen isotope (δ18O) stack (LR04). Nearly all Pleistocene Marine Isotope Stages (MIS) are interpreted to be present in the barium enrichment record of Site U1533, assuming simultaneous changes in Antarctic sea-ice extent/local export productivity and global oxygen isotope stratigraphy. We then construct the second, independent age model using the Plio-/Pleistocene RPI record developed for Site U1533, which represents the longest (nearly) continuous RPI record currently available for the Antarctic margin. Comparison of the two, independently derived age models shows a variable offset, on average ± 12 kyr, with the RPI-based ages consistently older than the barium-based ages in the interval from 1.9 to 2.9 Ma and then consistently younger from 0.0 to 1.9 Ma. We interpret these offsets to result from a combination of lock-in depth effects in the younger interval (due to the relatively low sedimentation rates at this site, ∼2 cm/kyr), temporal offsets between global δ18O changes in the deep ocean and productivity response on the Antarctic margin, and/or systematic miscorrelation in the construction of the two age models. Finally, we construct a hybrid age model for the Pleistocene section of Site U1533 by combining a mixture of RPI- and barium-based age tie points that are deemed to be robust. The Site U1533 RPI record is then used, together with other Southern Ocean RPI records, to construct an Antarctic RPI stack (designated as ‘ANT-1600’) for the interval 0.0–1.6 Ma. Although sedimentation rates at two-thirds of the sites selected for the stack are lower than 10 cm/kyr, the new ANT-1600 stack is strongly coherent with the SINT-2000 RPI stack (Valet et al., 2005) on time scales of ∼20–200 kyr, allowing for its use as a regional RPI reference curve in future studies. Overall, we demonstrate that RPI at Antarctic margin/Southern Ocean sites provides a viable and valuable independent dating method for application to Plio-/Pleistocene Antarctic sediments

    Extracting a Detailed Magnetostratigraphy From Weakly Magnetized, Oligocene to Early Miocene Sediment Drifts Recovered at IODP Site U1406 (Newfoundland Margin, Northwest Atlantic Ocean)

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    Fine-grained magnetic particles in deep-sea sediments often statistically align with the ambient magnetic field during (and shortly after) deposition and can therefore record geomagnetic reversals. Correlation of these reversals to a geomagnetic polarity time scale is an important geochronological tool that facilitates precise stratigraphic correlation and dating of geological records globally. Sediments often carry a remanence strong enough for confident identification of polarity reversals, but in some cases a low signal-to-noise ratio prevents the construction of a reliable and robust magnetostratigraphy. Here we implement a data-filtering protocol, which can be integrated with the UPmag software package, to automatically reduce the maximum angular deviation and statistically mask noisy data and outliers deemed unsuitable for magnetostratigraphic interpretation. This protocol thus extracts a clearer signal from weakly magnetized sediments recovered at Integrated Ocean Drilling Program (IODP) Expedition 342 Site U1406 (Newfoundland margin, northwest Atlantic Ocean). The resulting magnetostratigraphy, in combination with shipboard and shore-based biostratigraphy, provides an age model for the study interval from IODP Site U1406 between Chrons C6Ar and C9n (approximate to 21-27 Ma). We identify rarely observed geomagnetic directional changes within Chrons C6Br, C7r, and C7Ar, and perhaps within Subchron C8n.1n. Our magnetostratigraphy dates three intervals of unusual stratigraphic behavior within the sediment drifts at IODP Site U1406 on the Newfoundland margin. These lithostratigraphic changes are broadly concurrent with the coldest climatic phases of the middle Oligocene to early Miocene and we hypothesize that they reflect changes in bottom water circulation.</p
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