126,354 research outputs found
Going Beyond Counting First Authors in Author Co-citation Analysis
No full textThe present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation
counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings
are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that
only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into
account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed
B. L. Ullmann. Classical authors in mediaeval florilegia.
No full textPeeters Félix. B. L. Ullmann. Classical authors in mediaeval florilegia.. In: L'antiquité classique, Tome 2, fasc. 1, 1933. pp. 249-251
Total Synthesis of Hirsutellone B via Ullmann-Type Direct 13-Membered Macrocyclization
No full textTotal synthesis of Hirsutellone B has been achieved by a convergent synthetic strategy. This synthesis features direct construction of the highly strained 13-membered macrocycle of Hirsutellone B utilizing the Ullmann-type reaction. To the best of our knowledge, this is the first application of macrocyclization utilizing an intramolecular Ullmann-type reaction between an aliphatic alcohol and aryl halide
Dispelling the Myths Behind First-author Citation Counts
No full textWe conducted a full-scale evaluative citation analysis study of scholars in the XML research field to explore just how different from each other author rankings resulting from different citation counting methods actually are, and to demonstrate the capability of emerging data and tools on the Web in supporting more realistic citation counting methods. Our results contest some common arguments for the continued
use of first-author citation counts in the evaluation of scholars, such as high correlations between author rankings by first-author citation counts and other citation
counting methods, and high costs of using more realistic citation counting methods that are not well-supported by the ISI databases. It is argued that increasingly available digital full text research papers make it possible for citation analysis studies to go beyond what the ISI databases have directly supported and to employ more
sophisticated methods
Microwave-Assisted Intramolecular Ullmann Diaryl Etherification as the Post-Ugi Annulation for Generation of Dibenz[b,f][1,4]oxazepine Scaffold
No full textA sequence of the Ugi four-component reaction (U-4CR) and microwave-assisted intramolecular Ullmann etherification has been established for efficient generation of a dibenz[b,f][1,4]oxazepine scaffold. The U-4CR, using 2-aminophenols and 2-bromobenzoic acids or 2-bromobenzaldehydes as the inputs, was carried out in MeOH at 50-60 °C for 2-3 days to form a collection of 22 linear products in 46-90% yields. A microwave-assisted intramolecular Ullmann etherification was then used to transform these acyclic U-4CR products into the cleft-shaped 6/7/6-fused tricyclic heterocycles. The intramolecular Ullmann diaryl ether formation was catalyzed by 10 mol % of CuI and 30 mol % of N,N-dimethylglycine hydrochloride (DMG·HCl) in the presence of Cs2CO3 with microwave irradiation (150 °C, 30 min) to furnish dibenz[b,f][1,4]oxazepin-11(10H)-ones and dibenz[b,f][1,4]oxazepin-11(10H)-carboxamides in 64-100% yields.</p
Sea Surges in Camargue: Trends over the 20th century.
No full textContinental Shelf Research 27 (2007) 922–934
Sea surges in Camargue: Trends over the 20th century
A. Ullmanna,b,, P.A. Pirazzolic, A. Tomasind,e
aUFR des Sciences Ge´ographiques et de l’Ame´nagement, Universite´ d’Aix-Marseille I, Aix en -Provence, France
bCEREGE—UMR 6635, Aix en Provence, France
cCNRS-Laboratoire de Ge´ogrphie Physique, 1 place Aristide Briand, 92 195-Meudon, France
dCNR-ISMAR, Venezia, Italy
eUniversita` di Venezia, Venezia, Italy
Received 8 November 2005; received in revised form 24 November 2006; accepted 4 December 2006
Available online 25 January 2007
Abstract
The vulnerability to short-term and long-term sea-level rises is particularly high in subsiding deltaic areas, especially in
microtidal seas, when surges (the differences between the observed sea heights and the simultaneous astronomical tide) are
frequent. At the Grau-de-la-Dent tide-gauge in the Camargue (Rhone delta, France), daily sea-level records are available
since 1905. Hourly tide data spanning the period 1979–1995 were obtained through the digitisation of the original paper
records: the local harmonic constants and the surges for the whole 20th century have been computed from these hourly
observations. It appears that the annual maximum observed sea-level height increases by 4 mm/yr at a rate that is two
times faster than the average observed relative sea level. The increasing trend of the annual maximum positive sea surges
(+1.9 mm/yr), which is equal to the average relative sea-level rise, is thus responsible for this difference. The most
important meteorological factor associated with local sea-surge occurrences is wind blowing from 1001 to 1201 sectors,
which tends to push the water toward the coasts. Since 1961, the frequency and the speed of wind from this sector
increased, although with some variability, thus contributing in part to the increase in the frequency and intensity of the
surges. Due to the changing hydrodynamics phenomenon in the Camargue, a positive feedback mechanism between
extreme marine events and shoreline regression is another factor to explain the sea-surge rise over the long term. The
increase in sea-surge frequency and height during the last century is especially of concern in the deltaic area if the nearfuture
global sea-level rise predicted by climate models is also taken into account.
r 2007 Elsevier Ltd. All rights reserved.
Keywords: Sea level; Surge; Tide; Wind; Flooding risk; Camargue; Rhone delta
1. Introduction
Any rise in sea level will have adverse impacts
such as coastal erosion and flooding, depending on
the time scale and the magnitude of the rise and the
human response to it (Paskoff, 1993). A rise in sea
level may be due to several factors acting on various
time scales, i.e., atmospheric storms (Bouligand and
Pirazzoli, 1999; Pirazzoli, 2000; Trigo and Davies,
2002; Pirazzoli and Tomasin, 2002), river flooding
in estuaries (Svensson and Jones, 2002), but also
land sinking or similar non climate-related changes,
linked to sediment compaction, isostasy, coastal
geomorphologic evolutions or urban development.
ARTICLE IN PRESS
www.elsevier.com/locate/csr
0278-4343/$ - see front matter r 2007 Elsevier Ltd. All rights reserved.
doi:10.1016/j.csr.2006.12.001
Corresponding author. CEREGE, Europoˆ le Me´diterrane´en
de l’Arbois, B.P 80, 13545 Aix-en-Provence, France.
E-mail address: [email protected] (A. Ullmann)
Microwave-Assisted Intramolecular Ullmann Diaryl Etherification as the Post-Ugi Annulation for Generation of Dibenz[<i>b</i>,<i>f</i>][1,4]oxazepine Scaffold
No full textA sequence
of the Ugi four-component reaction (U-4CR) and microwave-assisted
intramolecular Ullmann etherification has been established for efficient
generation of a dibenz[b,f][1,4]oxazepine
scaffold. The U-4CR, using 2-aminophenols and 2-bromobenzoic acids
or 2-bromobenzaldehydes as the inputs, was carried out in MeOH at
50–60 °C for 2–3 days to form a collection of 22
linear products in 46–90% yields. A microwave-assisted intramolecular
Ullmann etherification was then used to transform these acyclic U-4CR
products into the cleft-shaped 6/7/6-fused tricyclic heterocycles.
The intramolecular Ullmann diaryl ether formation was catalyzed by
10 mol % of CuI and 30 mol % of N,N-dimethylglycine hydrochloride (DMG·HCl) in the presence of
Cs2CO3 with microwave irradiation (150 °C,
30 min) to furnish dibenz[b,f][1,4]oxazepin-11(10H)-ones and dibenz[b,f][1,4]oxazepin-11(10H)-carboxamides in 64–100%
yields
Pragmatic Case Studies as a Source of Unity in Applied Psychology
No full textTo unify or not to unify applied psychology: that is the question. In this article we review pendulum swings in the historical efforts to answer this question—from a comprehensive, positivist, “top-down,” deductive yes between the 1930s and the early 60s, to a postmodern no since then. A rationale and proposal for a limited, “bottom-up,” inductive yes in applied psychology is then presented, employing a case-based paradigm that integrates both positivist and postmodern themes and components. This paradigm is labeled “pragmatic psychology” and, its specific use of case studies, the “Pragmatic Case Study Method” (“PCS Method”). We call for the creation of peer-reviewed journal-databases of pragmatic case studies as a foundational source of unifying applied knowledge in our discipline. As one example, the potential of the PCS Method for unifying different angles of theoretical regard is illustrated in an area of applied psychology, psychotherapy, via the case of Mrs. B. The article then turns to the broader historical and epistemological arguments for the unifying nature of the PCS Method in both applied and basic psychology.Peer reviewe
Diastereospecific Intramolecular Ullmann Couplings: Unique Chiral Auxiliary for the Preparation of 3,3‘-Disubstituted MeO-BIPHEP Derivatives
No full textA chiral auxiliary is described that provides only one diastereomer during intramolecular Ullmann couplings. Treatment of five Ullmann coupling
precursors with Cu powder in DMF at 115 °C provides 2,2‘,3,3‘,6,6‘-hexasubstituted 1,1‘-biphenyls as single diastereomers in yields ranging
from 66% to 91%
David Niven, Liv Ullmann, Fred Zinnemann, and others at cast party for MAN'S FATE, ca. 1970
No full textStanding front center, from left: David Niven, Liv Ullmann, and director Fred Zinnemann at cast party for MAN'S FATE, ca. 1970. Others unidentified. 8x10 b&w photographic print
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