55 research outputs found

    Stable and efficient Li-ion battery anodes prepared from polymer-derived silicon oxycarbide-carbon nanotube shell/core composites

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    We demonstrate synthesis and electrochemical performance of polymer-derived silicon oxycarbide-carbon nanotube (SiOC-CNT) composites as a stable lithium intercalation material for secondary battery applications. Composite synthesis was achieved through controlled thermal decomposition of 1,3,5,7-tetramethyl 1,3,5,7-tetravinyl cyclotetrasiloxane (TTCS) precursor on carbon nanotubes surfaces that resulted in formation of shell/core type ceramic SiOC-CNT architecture. Li-ion battery anode (prepared at a loading of~ 1.0 mg cmˉ²) showed stable charge capacity of 686 mAh gˉ¹ even after 40 cycles. The average coulombic efficiency (excluding the first cycle loss) was 99.6 %. Further, the post electrochemical imaging of the dissembled cells showed no apparent damage to the anode surface, highlighting improved chemical and mechanical stability of these composites. Similar trend was observed in the rate capability tests, where the SiOC-CNT anode (with 5 wt.% loading in TTCS) again showed stable performance, completely recovering the first cycle capacity of ~ 750 mAh gˉ¹ when the current density was brought back to 50 mA gˉ¹ after cycling at higher current densities

    MoS2/graphene composite paper for sodium-ion battery electrodes.

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    We study the synthesis and electrochemical and mechanical performance of layered freestanding papers composed of acid-exfoliated few-layer molybdenum disulfide (MoS₂) and reduced graphene oxide (rGO) flakes for use as a self-standing flexible electrode in sodium-ion batteries. Synthesis was achieved through vacuum filtration of homogeneous dispersions consisting of varying weight percent of acid-treated MoS₂ flakes in GO in DI water, followed by thermal reduction at elevated temperatures. The electrochemical performance of the crumpled composite paper (at 4 mg cm⁻²) was evaluated as counter electrode against pure Na foil in a half-cell configuration. The electrode showed good Na cycling ability with a stable charge capacity of approximately 230 mAh g⁻¹ with respect to total weight of the electrode with Coulombic efficiency reaching approximately 99%. In addition, static uniaxial tensile tests performed on crumpled composite papers showed high average strain to failure reaching approximately 2%

    A Bibliometric Analysis and Visualisation of Research Trends in Toxicity of Nickel-implants

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    Nickel is one of the most used metals for implants. The bibliometric analysis had been conducted to understand the active authors, organizations, journals, and countries involved in the research domain of “Toxicity of Nickel-implants”. All published articles related to “Toxicity of Nickel-implants” from “Scopus”, were analyzed using the VOS viewer to develop analysis tables and visualization maps. This article had set the objective to consolidate the scientific literature regarding “Toxicity of Nickel-implants” and also to find out the trends related to the same. The most active journals in this research domain biomaterial. The most active country was the United States of America and United Kingdom. The leading organization engaged in the research regarding the toxicity of Nickel implants was the Rush University Medical Center, United States of America. The most active author who had made valuable contributions related to the toxicity of Nickel implants was Hallab N.J. &nbsp

    A Bibliometric Analysis and Visualisation of Research Trends in Nickel-Based Orthopaedic Implants

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    Nickel is one of the widely used metal for orthopaedic implants. The bibliometric analysis had been conducted to understand the active authors, organizations, journals, and countries involved in the research domain of “Nickel-based orthopaedic implants”. All published articles related to “Nickel-based orthopaedic implants” from “Scopus”, were analyzed using the VOS viewer to develop analysis tables and visualization maps. This article had set the objective to consolidate the scientific literature regarding “Nickel-based orthopaedic implants” and also to find out the trends related to the same. The most active journals in this research domain were the Journal of Orthopaedic Research and Biomaterials. The most active country was the United States of America. The leading organization engaged in research regarding knee implants was the City University of Hong Kong. The most active authors who had made valuable contributions related to orthopaedic implants were Chu. P.K

    Achieving operational excellence in service sector using lean six sigma

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    Lean Six Sigma is a process improvement methodology that has been used in several industries and sectors for years. Even though Lean and Six Sigma come from distinct backgrounds, over a period of time, they have been used in conjunction with each other by companies to solve problems, increase efficiency and reduce waste in the processes. In the traditional schema of things, Lean Six Sigma methodology is more commonly used in a manufacturing setting. Further, the impact of organizational culture and leadership style is often ignored in the deployment of Lean Six Sigma methodologies. The objective of this dissertation is to study the impact of organizational culture and leadership styles on the deployment of Lean Six Sigma and its outcomes in a service sector. In particular, this research focuses on Healthcare sector. In Chapter 1, we provide an introduction to Lean and Six Sigma and provide an insight into the evolution of the methodology from Quality Management. We discuss one of the most common approaches, DMAIC, used in Lean Six Sigma to improve existing processes. We also introduce the various belts that individuals can earn in Lean Six Sigma Chapter 2 discusses the literature that was reviewed for this research and also introduces our hypothesis and propositions for the study. Chapter 3 describes the methodology we sued to conduct the research. We studied the deployment of Lean Six Sigma in 3 different companies; a healthcare company, a medical devices company, and a pharmaceutical company. For study 1, we reviewed the procurement process at Company A. For study 2, we reviewed the Facilities work order process at Company B and for study 3, we reviewed the mail distribution process for Company C. Chapter 3 provides backgrounds of all 3 studies, one at a time, and also provides details of data collection and analysis conducted on all 3 studies. In Chapter 4, we discuss the results from deploying Lean Six Sigma in 3 projects in 3 different companies. We also discuss the cultural implications and interaction effects of leadership and organizational culture on the results. Chapter 5 summarizes the overall conclusions of the research and we discuss the findings and also discuss the strengths and limitations of our research and areas for future research.Ph.D.Includes bibliographical referencesby Gurpreet Singh Khuran

    Name Recognition to Identify Patients of South Asian Ethnicity within the Cancer Registry

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    Objective: The goal of this project was to develop a list of forenames and surnames of South Asian (SA) women that could be used to identify SA breast cancer patients within the cancer registry. This list was compiled, evaluated, and validated to ensure comprehensiveness, accuracy, and applicability of SA names. Methods: This project was conducted by Canadian researchers who are immersed in conducting behavioral studies with SA women diagnosed with cancer in the province of British Columbia. Recruiting SA cancer patients for research can be a difficult task due to social and cultural factors. Methods used by other researchers to identify ethnicity related unique names were employed to filter surnames and forenames that were not common to this ethnic group. Co-author (Gurpreet Oshan) of SA ethnicity rigorously identified and deleted multiple lists and redundant entries along with common English forenames which resulted in a list of 16,888 SA forenames. All co-authors of Indian ethnicity (Gurpreet Oshan, Savitri Singh-Carlson, Harajit Lail) were involved in critiquing and manually reviewing the names list throughout this process. Comprehensive lists of SA surnames and women′s forenames were reviewed to identify those that were unique to SA ethnicity. Accuracy was ensured by constantly filtering the redundancy by using an Excel program which helped to illustrate the number of times each name was spelled in different ways. Results: The final lists included 9112 surnames and 16,888 forenames of SA ethnicity. On the basis of the surname linkage only, the sensitivity of the list was 76.6%, specificity was 62.9%, and the positive predictive value was 58.5%. On the basis of both the surname and forename linkage, the specificity of the list was 88.6%. These lists include variations in spelling forenames and surnames as well. Conclusions: The list of surnames and forenames can be useful tools to identify SA ethnic groups from large population database in healthcare-related research. Ethnicity-specific population research is important in order to help identify how cancer care should be delivered for the SA population, as well as for planning and provision of other related health services. We are willing to share this list upon request to the authors

    Bringing It All Back Home: Boulware and the Unfortunate Demise of the Miller Rule

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    In this Note, the author addresses the underlying tension between criminal intent and the complexity of the tax code in criminal tax prosecution in light of the recent Supreme Court opinion in U.S. v. Boulware. The author takes a look at the facts and circumstances of Boulware, the body of precedent supporting the Ninth Circuit\u27s opinion, and the reasoning of the Supreme Court in its subsequent reversal of that opinion. He revisits the oft cited opinion of Judge Learned Hand in Helvering v Gregory, and asks whether the courts have taken Judge Hand\u27s famous approval of tax planning so far out of context that it justifies the very behavior that he reproved. The author then asks if it is time to do away with the actual tax deficiency requirement in tax evasion cases-a rule bom in dictum and forged in repetition
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