196,300 research outputs found

    Oxidative alkylation of (η5-C5Me5)2TiR (R = Cl, Me, Et, CH=CH2, Ph, OMe, N=C(H)tBu) to (η5-C5Me5)2Ti(Me)R by group 12 organometallic compounds MMe2

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    Oxidative alkylation of Cp*2TiX (Cp*: η5-C5Me5; X = OMe, Cl, N=C(H)tBu) and Cp* 2TiMe by CdMe2 or ZnMe2 gives diamagnetic Cp*2Ti(Me)X and Cp*2TiMe2 respectively, and cadmium or zinc. The reactions of Cp*2TiR (R = Et, CH=CH2, Ph) with MMe2 (M = Cd, Zn) give statistical mixtures of Cp*2Ti(Me)R, Cp*2TiMe2 and Cp*2TiR2. Dimethylmercury does not react with Cp*2TiX.

    Dr. Duane M. Jackson, Morehouse College, July 2011

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    This video is a conversation with Dr. Duane M. Jackson. Dr. Jackson talks about his paper, "Recall and the Serial Position Effect: The Role of Primacy and Recency on Accounting Students' Performance." Jackie Daniel, AUC Woodruff Library, is the interviewer

    "Reflections on the subject of Emigration from Europe with a view to Settlement in the United States" By M. Carey.

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    "Reflections on the subject of Emigration from Europe with a view to Settlement in the United States: containing bried sketches of the moral and political character of those states. By M. Carey, member of the American philosophical, and of the American Antiquarian Society, and author of The Olive Branch, Cindiciae Hibernicae, essays on banking, on political economy, and on internal improvement. To which are now added the English editor's comments on the subject; together with Important Advice to Emigrants, and Cautions Against Impositions Practiced in the Outports

    Towards New Solutions for Scientific Computing: The Case of Julia

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    This year marks the consolidation of Julia (https://julialang.org/), a programming language designed for scientific computing, as the first stable version (1.0) has been released, in August 2018. Among its main features, expressiveness and high execution speeds are the most prominent: the performance of Julia code is similar to statically compiled languages, yet Julia provides a nice interactive shell and fully supports Jupyter. Moreover, it can transparently call external codes written in C, Fortran, and even Python and R without the need of wrappers. The usage of Julia in the astronomical community is growing, and a GitHub organization named JuliaAstro takes care of coordinating the development of packages. In this paper we present the features and shortcomings of this language, and discuss its application in astronomy and astrophysics

    Dispelling the Myths Behind First-author Citation Counts

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    We conducted a full-scale evaluative citation analysis study of scholars in the XML research field to explore just how different from each other author rankings resulting from different citation counting methods actually are, and to demonstrate the capability of emerging data and tools on the Web in supporting more realistic citation counting methods. Our results contest some common arguments for the continued use of first-author citation counts in the evaluation of scholars, such as high correlations between author rankings by first-author citation counts and other citation counting methods, and high costs of using more realistic citation counting methods that are not well-supported by the ISI databases. It is argued that increasingly available digital full text research papers make it possible for citation analysis studies to go beyond what the ISI databases have directly supported and to employ more sophisticated methods

    Dr. Glendon Swarthout

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    Hosted by Roger M. Busfield, MSU Assistant Professor of Speech and Theater, Meet the Author is designed to introduce a general audience to a contemporary author and their work through in-depth interviews. This episode features a conversation between Dr. Glendon Swarthout, prolific author and English professor at MSU, and assistant professors Sam S. Baskett and Theodore B. Strandness

    Simulation of thermal plant optimization and hydraulic aspects of thermal distribution loops for large campuses

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    Following an introduction, the author describes Texas A&M University and its utilities system. After that, the author presents how to construct simulation models for chilled water and heating hot water distribution systems. The simulation model was used in a $2.3 million Ross Street chilled water pipe replacement project at Texas A&M University. A second project conducted at the University of Texas at San Antonio was used as an example to demonstrate how to identify and design an optimal distribution system by using a simulation model. The author found that the minor losses of these closed loop thermal distribution systems are significantly higher than potable water distribution systems. In the second part of the report, the author presents the latest development of software called the Plant Optimization Program, which can simulate cogeneration plant operation, estimate its operation cost and provide optimized operation suggestions. The author also developed detailed simulation models for a gas turbine and heat recovery steam generator and identified significant potential savings. Finally, the author also used a steam turbine as an example to present a multi-regression method on constructing simulation models by using basic statistics and optimization algorithms. This report presents a survey of the author??s working experience at the Energy Systems Laboratory (ESL) at Texas A&M University during the period of January 2002 through March 2004. The purpose of the above work was to allow the author to become familiar with the practice of engineering. The result is that the author knows how to complete a project from start to finish and understands how both technical and nontechnical aspects of a project need to be considered in order to ensure a quality deliverable and bring a project to successful completion. This report concludes that the objectives of the internship were successfully accomplished and that the requirements for the degree of Degree of Engineering have been satisfied

    AIDA, a Modular Web Application for Astronomical Data Analysis and Instrument Monitoring Services

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    In the last decade, Astronomy has been the scene of the realization of panchromatic surveys, with sophisticated instruments acquiring a huge quantity of exceptional quality data. This poses the need to integrate advanced data-driven science methodologies for the automatic exploration of huge data archives, and the need for efficient short- and long-term monitoring and diagnostics systems. The goal is to keep the quality of the observations under control and to detect and circumscribe anomalies and malfunctions, facilitating rapid and effective corrections, ensuring correct maintenance of all components and the good health of scientific data over time. In particular, this requirement is crucial for space-borne observation systems, both in logistical and economic terms. AIDA (Advanced Infrastructure for Data Analysis) is a portable and modular web application, designed to provide an efficient and intuitive software infrastructure to support monitoring of data acquiring systems over time, diagnostics and both scientific and engineering data quality analysis, particularly suited for astronomical instruments. Given its modular system prerogative, it is possible to extend its functionalities, by integrating and customizing monitoring and diagnostics systems, as well as scientific data analysis solutions, including machine/deep learning and data mining techniques and methods. A specialized version of AIDA has been recently appointed as focal plane instrument operation diagnostics, analytics and monitoring service within the Science Ground Segment of the Euclid space mission

    Intern experience at CH���M Hill, Inc.: an internship report

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    Includes author's vita"Submitted to the College of Engineering of Texas A&M University in partial fulfillment of the requirement for the degree of Doctor of Engineering."Includes bibliographical referencesA review of the author's internship experience with CH���M HILL, Inc. during the period September 1975 through May 1976 is presented. During this nine month internship the author worked as an Engineer II in the Industrial Processes discipline of this large consulting engineering firm... The author's prime responsibility was as one of three lead design engineers on the design of a large wastewater treatment facility for a pulp mill in Hoquiam, Washington owned by ITT Rayonier Inc. The work generally consisted of the design of individual treatment units and associated piping and pumping. The purpose of the project was to provide wastewater treatment capabilities that would satisfy the effluent limitations (standards) imposed upon the mill by the State of Washington Department of Ecology and the U.S. Environmental Protection Agency. The author's assignment also entailed necessary interaction with the project manager and other CH���M HILL design engineers and support staff members, the client's representatives, and representatives of two other consulting engineering firms working on the project. Thus, the internship position at CH���M HILL provided considerable experience coordinating the author's work with the work of other engineers, guiding the design and administrative efforts of a support staff, and interacting regularly with the client and other consulting firms. This broad exposure to a variety of engineering and organizational problems provided a valuable educational experience

    Reactions of (C5Me5)M(2,3-dimethyl-1,3-butadiene)Cl (M = Ti, Hf) with symmetrical acetylenes

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    The reactivity of the electronically unsaturated diene complexes (C5Me5)M(2,3-dimethyl-1,3-butadiene)Cl (M = Ti, Hf) with symmetrical acetylenes RC≡CR (R = H, Me, Ph) is reported. Whereas the reaction of the Hf complex with ethyne resulted in a product derived from initial insertion into the metal-diene bond, elimination of the diene was observed in the other reactions. Two types of metallacyclo-2,4-pentadiene products, formed by oxidative coupling of acetylenes, were isolated: monomeric (C5Me5)Hf(C4Ph4)Cl and dimeric [(C5Me5)TiCl]2C4Me4)
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