30 research outputs found

    Computational Abstraction of Films for Quantitave Analysis of Cinematography

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    Currently, film viewers’ options for getting objective information about films before watching them, are limited. Comparisons are even harder to find and often require extensive film knowledge both by the author and the reader. Such comparisons are inherently subjective, therefore they limit the possibilities for scalable and effective statistical analyses. Apart from trailers, information about films cannot reach viewers audibly or visibly, which seems absurd considering the very nature of film. The thesis examines repeatable quantification methods for computationally abstracting films in order to extract informative data for visualizations and further statistical analy- ses. Theoretical background empowered by multidisciplinary approach and design processes are described. Visualizations of analyses are provided and evaluated for their accuracy and efficiency. Throughout the thesis foundations for the future automated quantification player/plugin, are described aiming to facilitate further developments. Theoretical structures of the website which may act as a gateway that collects and provides data for statistical cinematic research are also discussed

    Metallurgical Assessment of Novel Mg-Sn-La Alloys Produced by High-Pressure Die Casting

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    Sakarya University Scientific Research Project Council [2017-0908-014]; Turkish National Scientific Council (Tubitak) via 2219 - International Postdoctoral Research Fellowship ProgramTurkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [1059B191800747]This work was supported by the Sakarya University Scientific Research Project Council under Grant [number 2017-0908-014]. The author also would like to acknowledge funding assistance provided by the Turkish National Scientific Council (Tubitak) via 2219 - International Postdoctoral Research Fellowship Program Grant no 1059B191800747. The help of Ipek GOKCE, Murat GOKCE, Paramjot SINGH and Arulselvan ARUMUGHAM AKILAN in the experimental work are gratefully acknowledged.Mg alloys containing Al are widely used for industrial applications, but the use of these alloys as an automotive part is limited due to the low melting temperature of the Mg17Al12 intermetallic phase. Therefore, magnesium alloys without aluminum that can withstand higher operating temperatures are of interest to the automotive industry. The objective of this work is to develop Al-free Mg alloys for industrial applications. In the current work, four types of alloys were produced with varying La contents. The high-pressure die casting method was selected to overcome the problems inherent in the gravity casting method with respect to the production of parts with complex shapes and thin walls. X-ray diffraction analysis revealed that the base alloy (Mg-5Sn wt%) comprises of alpha-Mg and Mg2Sn phases whereas La containing alloys included intermetallic phases such as LaMg3, Mg17La2, and La5Sn3. Corresponding grain sizes of the alloys with La are lower than those of the Mg5Sn alloy. Due to this lower grain size and emerging dispersoids, the tensile strength of the Mg5Sn4La alloy (205 MPa) is roughly double that of Mg5Sn. Moreover, the addition of the 4% wt. La to the Mg5Sn alloys led to an increase in yield strength and ductility by 25% and 50%, respectively

    Spectroscopic (FT-IR, Raman, NMR and UV-vis.) and quantum chemical investigations of (E)-3-[4-(pentyloxy)phenyl]-1-phenylprop-2-en-1-one

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    Gokce, Halil/0000-0003-2258-859X; Naseer, Muhammad Moazzam/0000-0003-2788-2958WOS: 000342254500042In this study, the molecular structure and vibrational and electronic transition spectra and H-1 and C-13 NMR chemical shift values (gas phase and in chloroform solvent), HOMO-LUMO analysis, molecular electrostatic potential (MEP), thermodynamic properties and Mulliken atomic charges of (E)-344-(pentyloxy)phenyl]-1-phenylprop-2-en-1-one molecule, C20H22O2, which has many biological activities have been calculated using the DFT/B3LYP method with 6-311++G(d,p) basis set in the ground state. The obtained results indicate a good harmony among the calculated and the experimental FT-IR, Raman, UV vis. (in methanol solvent) and H-1 and C-13 NMR (in chloroform-d solvent) spectra of the mentioned compound. (C) 2014 Elsevier B.V. All rights reserved.Higher Education Commission of PakistanHigher Education Commission of PakistanThe author AA is grateful to Higher Education Commission of Pakistan for financial support

    A Study on Copolymer Systems of Styrene with Diethanolamine Side Group and Methyl Methacrylate

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    4-Diethanolaminomethyl styrene (DEAMSt) monomer was prepared by the modification of 4-chloromethyl styrene with diethanolamine. The copolymers in different combinations (0.11, 0.19, and 0.30 by mole) of DEAMSt and methyl methacrylate (MMA) were prepared by free radical polymerization method at 60°C in the presence of 1,4-dioxane and AIBN as initiator. The structures of DEAMSt and DEAMSt-MMA copolymer were characterized by FT-IR and 1H-NMR. The glass transition temperature (Tg) of the copolymers was measured by DSC. Thermal decomposition behavior of the copolymers was investigated by TGA. The average molecular weights of the copolymers were determined by GPC. The dye uptaking properties of the copolymers were investigated using bromocresol green. Then, the dielectric constant, dielectric loss factor, and conductivity of copolymers were investigated as a function of temperature and frequency. The activation energies (Ea) of the copolymers were determined by impedance analyzer

    Giving money to the poor: the political payoffs of allocating conditional cash transfers in Turkey

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    This dissertation analyzes the political consequences of the Conditional Cash Transfer program (CCT) in Turkey, The purpose is three-fold: first, to investigate the political incentives and payoffs that motivate policymakers to adopt CCTs; second, to test whether political or technocratic criteria explain the allocation of CCTs in Turkey, and third, to examine whether conditionally transferring cash to the poor empowers poor citizens, or produces/reproduces pressure on the poor to reciprocate by supporting the political party that made the cash transfer. My research draws on six months of fieldwork conducted in Malkara, Tekirdağ (with Roma beneficiaries) and Diyarbakır (with Kurdish beneficiaries), and on regression analysis of original district level data on the allocation of CCTs. I reach three primary conclusions. First, the adoption of CCTs under the coalition government, influenced and pushed by the World Bank, led to a relatively strict formulation of the social assistance scheme in Turkey, which provides a promising attempt to make a transition to programmatic social policy. Second, although on balance, social and economic indicators guide the distribution of funds, Kurdish districts appear to receive favorable treatment. Third, due to the lack of CCTs requirements for increased social participation and active social engagement on the part of beneficiaries, the CCT program does not have a transformative impact on the enhancement of citizenship and the empowerment of women for both the Kurdish and Roma communities. Rather, more politicized groups, such as the Kurdish people, view the benefit as their social right due to state’s inefficiency in creating jobs in the eastern part of Turkey and their uneasy relations with the state. Among less politicized groups, such as the Roma people, the program triggers feelings of gratitude and appreciation to the politicians providing this program, especially Prime Minister Erdoğan.Ph. D.Includes bibliographical referencesby Ozgen Gokce Bayka

    Spectrophotometric pKa Values of 3-(m-Nitrophenyl)-1,5-Diphenyl Formazan (MNF) and 3-(p-Nitrophenyl)-1,5-Diphenyl Formazan (PNF) in Different MeCN-Water Binary Mixtures

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    The acid dissociation constants of 3-(m-nitrophenyl)-1,5-diphenyl formazan (MNF) and 3-(p-nitrophenyl)-1,5-diphenyl formazan (PNF) have been determined in acetonitrile-water binary mixtures [50%, 60% and 70% (v/v)] by spectrophotometric method at 25 degrees C and an ionic strength of 0.1 mol .L-1 KCl. The absorption spectra were recorded in solutions of varying pH-values. Data evaluation was performed using the STAR software program which calculates stability constants and molar absorbances of the pure species by multilinear regression. A linear relationship between acidity constants and the mole fraction of acetonitrile in the solvent mixture was observed. The effect of solvent properties on acid-base behavior was discussed. The effect of nitro groups attached to para and meta positions on the ionization constant were investigated and the results were recorded.Kafkas University [2008-FEF-18]The author greatly acknowledges the financial support from Kafkas University (project no: 2008-FEF-18) and Jose L. Beltran from Universitat de Barcelona for kindly providing the spectral data processing software, STAR

    Developing three-dimensional spatial embodiment in architectural design education: underwater experiences

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    Three-dimensional thinking, observation, and practice have long been an important part of architectural education. Reduced awareness of corporeality and the senses can impair a student's capacity to create and develop an architectural environment holistically. Simulation programmes are an important tool to fill this gap, as they can broaden a student's perceptual framework. This article aims to understand the potential of underwater contact experiences to serve this purpose, especially underwater (UW) rugby which is one of the few sports that is three-dimensional. The article also aims to understand how simulation programmes, virtual reality, or augmented environments of UW rugby can contribute to design and architecture education by increasing student awareness. The article is grounded in the impact of this sport on the author and the author's perceptions based on personal experience as a former UW rugby player. It is argued that the simulation of UW rugby can contribute to design-related topics such as free form-finding, role-sharing and group collaboration, the development of awareness to sensorial design processes, risk- taking and action-oriented processes, designing with environmental uncertainty, and even design management, as these immersive environments provide a new agenda for future designers. Due to practical limitations, the article presents a theoretical argument as a first step toward developing a theoretical framework. Future studies with cognitive research methods and quantitative approaches in sports simulation design research will address these constraints

    Usability assessment of scholarly publishers’ online journal interfaces

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    A well-designed and user-friendly online journal interface not only enhances researchers’ satisfaction but also bolsters the reputation of academic publishers within the scholarly community. Consequently, the present study undertakes an examination of the usability aspects pertaining to online journal interfaces offered by five prominent academic publishers: Wiley, Sage, Elsevier, Springer, and Taylor & Francis. This investigation encompasses a combination of user testing and post-questionnaire methodologies, aiming to accrue both quantitative and qualitative data concerning user task execution and satisfaction. The research findings spotlight the varying degrees of usability across major academic publishers and emphasize the critical role of design in enhancing researchers’ experiences. By identifying both usability strengths and weaknesses, along with offering actionable areas for improvement, this study adds a valuable perspective to the enhancement of academic journal interfaces. © The Author(s), under exclusive licence to Springer Nature Switzerland AG 2023
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