1,721,157 research outputs found

    Correcting for CO2 interference in soil radon flux measurements

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    In the present paper the interference of high CO2 concentration in soil radon flux measurement using a solid state silicon detector is discussed. A possible correction, making use of a chemical trap consisting of soda lime pellets, is successfully experimented at Cava dei Selci site (Roma, Italy). The interference is likely due to neutralization processes of 218Po ions in the CO2 dominant atmosphere occurring in the chamber of radon monitor and resulting in a reduced efficiency in electrostatic collection on the surface of the solid state detecto

    226Ra chronology of Holocene travertine from Esanatoglia (Central Italy)

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    Here we investigate the feasibility of using alpha-spectrometric 226Ra methodology to date low U freshwater carbonate deposits (<0.1 μg g-1) by analysing Holocene freshwater travertine deposits from Esanatoglia, Umbro-Marchean Apennines, Central Italy. Previously, such methods have been tested on hydrothermal deposits, which are characterised by high Ra and U. We calculate a 226Ra age estimate of 2.9 ± 0.4 ka (1σ) for Holocene travertine that is in reasonable agreement with archaeological evidence by assuming that the 226Ra initial activity of the Holocene travertine is comparable with that of present-day carbonate deposits in the same area. We also investigate the use of Ba to normalise 226Ra activities. Comparison of age estimates based on Ra methods with ages derived from alphaspectrometric 230Th/234U isochron techniques for the same co-eval sub-samples indicates that, where only alpha-spectrometric methods are available, the former are likely to be much more useful for Holocene travertine material, especially if there is a significant detrital component

    Using 222-Radon as tracer for areal and vertical distribution of hydrocarbon contaminations

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    Non-aqueous Phase Liquids (NAPLs), including crude oil and its refined products, produce a long lasting impact on the enviroment due to unwilling releases. Storage sites of fuel and pump stations are often involved in unwilling NAPL spills in the subsoil and/or groundwater. The non-polar nature of these contaminants confers them a slight solubility in water, causing a reduced efficency of the most common remediation techniques. These limitations result in long-term remediation activities with high related costs. Unconventional characterization methods like the Radon (222Rn)-deficit technique are meant to supplement and optimize the conventional approach by providing dense spatial information in quasi-real time, and at a reasonable cost (De Miguel et al., 2020). Schubert (2015) presented a comprehensive review of the use of 222Rn as a natural tracer to assess subsurface NAPL contamination. In the present work Radon deficit technique was applied to determine the vertical distribution of Rn in groundwater inside a gasoline contaminated area. Twelve passive accumulators PDMS-AC (polydimethylsiloxane mixed with activated carbon) were inserted at different depth inside fenestrated piezometers and left for two weeks to maximize the Rn accumulation. Then they were measured by high resolution gamma spectometry. PDMS-AC are characterized by a high permeability to Rn and impermeability to water (Voltaggio &amp; Spadoni, 2013). The obtained results suggest the possible application of Radon deficit to find not only the areal but also the vertical distribution of a NAPL contamination in the saturated level. This datum could offer interesting applications to estimate initial and residual volumes of the contaminant during remediation procedures
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