1,721,208 research outputs found

    Mismatch Strain versus Dangling Bonds: Formation of "Coin-Roll Nanowires" by Stacking Nanosheets

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    (Figure Presented) The third dimension comes to the rescue in the synthesis of laterally confined 2D crystals. Graphene-type sheets of layered metal(IV) chalcogenides are stabilized by stacking to form nano-objects that resemble a coin roll. Mismatch strain between NbS2 and WS2 lattices is important for the stabilization of the coin-roll structure as well as for preventing the formation of the intrinsically more stable scroll structures such as fullerenes or nanotubes. © 2010 Wiley-VCH Verlag GmbH &. Co. KGaA

    New Synthetic Approaches to Functionalized Chalcogenide Nanostructures

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    New synthetic approaches to MS2 (M = Sn, Nb, Mo, W) chalcogenide nanostructures are highlighted. Most chalcogenide particles can be functionalized directly with inorganic nanoparticles such as Au, ZnO or MnO. Depending on the Pearson hardness of the metal involved, the functionalization may be reversible or irreversible. A covalent functionalization strategy is based on a steric shielding of the coordination sphere of transition metal atoms in such a way that only coordination sites are available for bonding to the chalcogenide surface. This allows the immobilization of fluorophors, redox active groups or proteins onto chalcogenide nanoparticles. © 2010 by The International Society of Offshore and Polar Engineers (ISOPE)

    Going Beyond Counting First Authors in Author Co-citation Analysis

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    The present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed
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