1,720,960 research outputs found
Preparation of functional nanostructured materials by facile and green methods
Full text linkA challenging goal of Chemistry is its sustainability towards a circular no-waste approach. This statement has been the mainstream of this PhD work, applied to innovative functional materials based on inorganic hosting substrates.
The experimental work has used synthetic strategies, optimization tools and characterization methods to identify and pursue materials with facile, rapid and green preparations for functional photoactive materials, improving durability and performances.
A part of the work dealt with the study and optimization of the preparation of tailored inorganic hosts, as synthetic layered clay-like materials (saponite), with a study of the synthetic conditions and the thermal treatment features to achieve high yield, morphological and compositional quality with a reduced energetic payload. Aside, in a waste-reduction strategy, a highly innovative approach was carried on using biomasses (i.e. rice husk and straw) as sources of inorganics for materials with controlled composition. The preparation of functional materials via host-guest architectures was targeted on photoactive
systems using anionic (i.e. DyeA) and neutral (GAM2-35) photoactive dyes, to be incorporated in hydrotalcite and synthetic saponite clay respectively.
A mechanochemical methodology of intercalation of DyeA into hydrotalcite based on the Liquid Assisted Grinding (LAG) was fully optimized using statistical tools as factorial design and Simplex. Intercalating neutral optically active dyes in saponite was then pursued using a quasi-solid state co-intercalation of GAM2-35 and a proper cationic surfactant (CTAB), avoiding the use of harsh conditions of temperature and pH. To fulfill an approach to sustainable hotoactive host-guest materials, a full asset of high throughput characterization techniques, as in situ XRPD and Uv-Vis methods and chemometric methodologies, was applied to an established fully thermal process coming from the past, the Maya Blue formation from palygorskite and indigo
Crystal packing and layered morphology relationships in naphthalene sulfonate compounds
No full textThe crystal structure of sodium naphthalene 2-sulfonate (Na2-NS) is reported. This compound raised the attention as a pollutant, being widely used in industry, and its intercalation in inorganic matrices, such as layered double hydroxides (LDH), could be a suitable removal strategy. The crystal structure of the title compound, despite its simplicity, is not known in the literature, so we looked for a strategy to grow crystals suitable for a single crystal study. Although many attempts were made to recrystallize it, Na2-NS grows in bunches of very thin laminae, with a high degree of mosaicity and intergrowth, explaining the absence of a reported crystal structure. The crystal structure shows layers of Na+ cations with the organic part arranged in between. The crystals grow easily in the layer plane, whilst the growth perpendicular to the layers is driven by weak non-bonding interaction and thus unfavored. The crystal packing features were related to the density of charges in the cationic layer with respect to the size of the anion. By comparing the crystal structures of 2-NS salts with different cations, and with or without an amino substituent in different positions, it was possible to find the relationship between the density of the positive charges and the deepness of interdigitation of the 2-NS moieties. We exploited this information to shed light on the structural features of 2-NS and related compounds intercalated into LDH. The X-ray powder diffraction pattern of 2-NS intercalated LDH (V. Toson, E. Conterosito, L. Palin, et al. Facile intercalation of organic molecules into hydrotalcites by liquid-assisted grinding: yield optimization by a chemometric approach. Cryst. Growth Des. 2015, 15, 5368) resulted consistent with a crystal packing characterized by the partial interdigitation of the 2-NS anions
Single step eco-efficient mild chemical process for the total valorisation of rice husk: a focus on the inorganics as a cement additive
No full textThe rice husk biomass remaining from the industrial processing of rice constitutes approximately 25 wt% of the edible rice produced, and its disposal is challenging due to its high silica content. Here, we describe the optimization of a single step innovative chemical process for the conversion of rice husk-based biomass into useable products which tackles all fractions of the input biomass. The chemical process consists of a single step hydrothermal low temperature treatment of rice husk biomass leading to three easy-to-recover fractions. With appropriate chemical treatments, each of these fractions can serve specific applications effectively, overcoming the issues present in the original biomass. This paper will present the treatment method and the optimization of chemical conditions for ideal fractionation as well as include the characterization of the recovered materials. Additionally, the paper will explore the use of one of these materials—the inorganic precipitate fraction (P), which is rich in calcium silicate hydrate (C-S-H) phase—as an additive to promote C-S-H nucleation in cementitious materials. The process also yields a liquid fraction (S) rich in sugars and soluble inorganic species, and a fibrous fraction (HR) containing lignin and cellulose residues. All these components were characterized to assess their suitability for potential applications. A detailed study on the application of these materials in the fields of plant biology and polymer science will be presented in (a) subsequent publication(s). The three fractions were characterized by a multi-technique approach involving PXRD, XRF, TGA/DSC, Electron microscopy and NMR. The above chemical process can be extended to any straw and husk-based cereal crops (wheat or barley), broadening and strengthening the bio-based industries and improving the circularity of food-related byproducts
Analytical Characterization of the Intercalation of Neutral Molecules into Saponite
No full textOrgano-modified layered materials characterization poses challenges due to their complexity and how other aspects such as contamination, preparation methods and degree of intercalation influence the properties of these materials. Consequently, a deep understanding of their interlayer organization is of utmost importance to optimize their applications. These materials can in fact improve the stability of photoactive molecules through intercalation, avoiding the quenching of their emission at the solid state, to facilitate their use in sensors or other devices. Two synthetic methods for the preparation of saponites with a cationic surfactant (CTABr) and a neutral chromophore (Fluorene) were tested and the obtained products were initially characterized with several complementary techniques (XRPD, SEM, TGA, IR, UV-Vis, Fluorescence and Raman spectroscopy), but a clear understanding of the organization of the guest molecules in the material could not be obtained by these techniques alone. This information was obtained only by thermogravimetry coupled with gas chromatography and mass spectroscopy (TGA-GC-MS) which allowed identifying the species present in the sample and the kind of interaction with the host by distinguishing between intercalated and adsorbed on the surface
Going Beyond Counting First Authors in Author Co-citation Analysis
Full text linkThe present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation
counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings
are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that
only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into
account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed
Variations on the Author
Full text link“Variations on the Author” discusses two of Eduardo Coutinho’s recent films (Um Dia na Vida, from 2010, and Últimas Conversas, posthumously released in 2015) and their contribution to the general question of documentary authorship. The director’s filmography is characterized by a consistent yet self-effacing form of authorial self-inscription: Coutinho often features as an interviewer that rather than express opinions propels discourses; an interviewer that is good at listening. This mode of self-inscription characterizes him as an author who is not expressive but who is nonetheless markedly present on the screen. In Um Dia na Vida, however, Coutinho is completely absent form the image, while Últimas Conversas, on the contrary, includes a confessional prologue that moves the director from the margins to the center of his films. This article examines the ways in which these works stand out in the filmography of a director who offers new insights into the notion of cinematic authorship
Appropriate Similarity Measures for Author Cocitation Analysis
Full text linkWe provide a number of new insights into the methodological discussion about author cocitation analysis. We first argue that the use of the Pearson correlation for measuring the similarity between authors’ cocitation profiles is not very satisfactory. We then discuss what kind of similarity measures may be used as an alternative to the Pearson correlation. We consider three similarity measures in particular. One is the well-known cosine. The other two similarity measures have not been used before in the bibliometric literature. Finally, we show by means of an example that our findings have a high practical relevance.information science;Pearson correlation;cosine;similarity measure;author cocitation analysis
Dispelling the Myths Behind First-author Citation Counts
Full text linkWe conducted a full-scale evaluative citation analysis study of scholars in the XML research field to explore just how different from each other author rankings resulting from different citation counting methods actually are, and to demonstrate the capability of emerging data and tools on the Web in supporting more realistic citation counting methods. Our results contest some common arguments for the continued
use of first-author citation counts in the evaluation of scholars, such as high correlations between author rankings by first-author citation counts and other citation
counting methods, and high costs of using more realistic citation counting methods that are not well-supported by the ISI databases. It is argued that increasingly available digital full text research papers make it possible for citation analysis studies to go beyond what the ISI databases have directly supported and to employ more
sophisticated methods
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