44,949 research outputs found
Erratum: Redox Switchable Thianthrene Cavitands (Synthesis (Germany) DOI: 10.1055/s-0036-1588659)
No full textThere is a mistake in Figure 8 and 9 (protonated sulfur). The correct Figures are shown below. (Figure presented). There is also a mistake in the HRMS data of cavitand 1. It should read: HRMS (MALDI) m/z calculated for C108H89N8O8S8 [M+H]+: 1882.46; found: 1882.61
Cavitand-Functionalized SWCNTs for N-Methylammonium Detection
No full textSingle-walled carbon nanotubes (SWCNTs) have been functionalized with highly selective tetraphosphonate cavitand receptors. The binding of charged N-methylammonium species to the functionalized SWCNTs was analyzed by X-ray photoelectron spectroscopy and confirmed by [superscript 31]P MAS NMR spectroscopy. The cavitand-functionalized SWCNTs were shown to function as chemiresistive sensory materials for the detection of sarcosine and its ethyl ester hydrochloride in water with high selectivity at concentrations as low as 0.02 mM. Exposure to sarcosine and its derivative resulted in an increased conductance, in contrast to a decreased conductance response observed for potential interferents such as the structurally related glycine ethyl ester hydrochloride.European Union. Project BION (ICT-2007-213219)Massachusetts Institute of Technology. Institute for Soldier Nanotechnologies (DAAD-19-02-0002
Settling of finite-size particles in isotropically forced, homogeneous turbulence: interface-resolved simulations
No full textWe have simulated the gravity-induced settling of finite-size particles in a turbulent background flow which is forced in a statistically-stationary fashion. The simulations are accurately resolving the solid-fluid interface with the aid of an immersed boundary technique [1]. The parameters of the simulation are (apart from background turbulence) identical to those of reference [2], where particle clustering was observed at a Galileo number of 178 and a solid volume fraction of 0.005. In the present case, it is found that a relative turbulence intensity of 0.24 leads to the disappearance of the clusters; as a consequence, the increase in average particle settling velocity found in [2] also vanishes. [1] M. Uhlmann. An immersed boundary method with direct forcing for the simulation of particulate flows. J. Comput. Phys., 209(2):448–476, 2005. [2] M. Uhlmann and T. Doychev. Sedimentation of a dilute suspension of rigid spheres at intermediate Galileo numbers: the effect of clustering upon the particle motion. J. Fluid Mech., 752:310–348, 2014
Factors affecting the dispersion of MWCNTs in electrically conducting SEBS nanocomposites
No full textThe accessible concentration of exfoliated and undamaged multi-walled carbon nanotubes (MWCNTs) in polymer nanocomposites is an essential issue to the future of these materials. In this work, we report two methodologies directed at obtaining electrically conducting poly(styrene-b-(ethylene-co-butylene)-b-styrene) (SEBS) nanocomposites with different MWCNT contents. The first depends on the time modulation of ultrasonication of toluene mixtures, whereas the second relies on the use of alkyl-functionalized MWCNTs (f-MWCNTs). UV‚Äìvis spectroscopy investigations and thermogravimetric analyses allowed the quantification of exfoliated CNTs incorporated in the SEBS mixture. TEM micrographs denoted that a prolonged sonication time (40 min) induced an extensive MWCNTs degradation (average length decreased of 40%), which affected the electrical conductivity of the nanocomposites. The f-MWCNTs appeared to be more effective in preparing SEBS nanocomposites due to the higher dispersion efficiency, negligible nanotube degradation and higher electrical conductivity. The temperature dependence of the resistance of the SEBS/MWCNT system was investigated in the range 20 - 60 °C to explore its potential for sensor development
Mesophilic-hydrothermal-thermophilic (M-H-T) digestion of green corn straw
No full textMesophilic-hydrothermal (80-160 degrees C, 30 min)-thermophilic (M-H-T) digestion and control tests of mesophilic (M), thermophilic (T), hydrothermal-mesophilic (H-M), and mesophilic-thermophilic digestion (M-T) of green corn straw were conducted for a 20-day fermentation period. The results indicate that M-H-T is an efficient method to improve methane production. A maximum methane yield of 371.74 mL/g volatile solid was obtained by the M (3 days)-H (140 degrees C)-T (17 days) process, which was 20.44%, 16.55%, 31.44%, and 14.31% higher than the yields of the M, T, 140-M, and M-T processes. The enhanced methane production was attributed to (1) the improved hemicellulose degradation and lignin disorganization; (2) prevention of the degradation of soluble sugar, easily hydrolyzed hemicellulose and cellulose into furfural and methylfurfural; and (3) lack of formation of Maillard reaction products during initial hydrothermal treatment. (C) 2015 Elsevier Ltd. All rights reserved
Dr. Glendon Swarthout
No full textHosted by Roger M. Busfield, MSU Assistant Professor of Speech and Theater, Meet the Author is designed to introduce a general audience to a contemporary author and their work through in-depth interviews. This episode features a conversation between Dr. Glendon Swarthout, prolific author and English professor at MSU, and assistant professors Sam S. Baskett and Theodore B. Strandness
Unveiling Local Dynamics of a Triptycene-Based Porous Polymer by Solid-State NMR
No full textMembrane-based technologies for gas separation and capture are promising low-energy alternatives to the most common energy-consuming processes such as distillation and absorption. In this frame, porous polymers are attracting considerable interest, but issues related to a trade-off between permeability and selectivity as well as to the long-term stability of the membrane performances need to be overcome. To this end, the study of local dynamics is crucial as it directly correlates with the transport and separation characteristics of polymer-based membranes while also shedding light on plasticization and physical aging phenomena. This work presents a comprehensive characterization of the dynamic properties of a triptycene-based porous polymer with potential application in membrane-based gas separation technology by means of molecular dynamics (MD) simulations and solid-state NMR (SSNMR). The investigated polymer has triptycene-based structural repeating units bearing t-butyl groups that are connected by perfluorinated biphenyl repeats. The combination of different SSNMR variable temperature experiments including measurements of 1H, 13C, and 19F spin-spin and spin-lattice relaxation times, 1H-13C and 19F-13C dipolar chemical shift correlation experiments, and 2H experiments provided selective and detailed information on the molecular motions involving the t-butyl, triptycene, and perfluorinated biphenyl groups. A synergistic analysis of the acquired data, employing theoretical dynamic models and comparisons with MD simulations and calculated potential energy scans (PES), has enabled the determination of motion parameters, including activation energies and correlation times. This approach also yielded insights into the motion amplitudes and geometry. These findings can be valuable for future research aimed at elucidating the molecular origins of membrane performance, not only for the polymer under investigation but also for similar polymer-based membranes
The maternal immune system during pregnancy and its influence on fetal development
No full textThe maternal immune system plays a critical role in the establishment, maintenance, and completion of a healthy pregnancy. However, the specific mechanisms utilized to achieve these goals are not well understood. Various cells and molecules of the immune system are key players in the development and function of the placenta and the fetus. Effector cells of the immune system act to promote and yet limit placental development. The T helper 1 (Th1)/T helper 2 (Th2) immune shift during pregnancy is well established. A fine balance between proinflammatory and anti-inflammatory influences is required. We herein review the evidence regarding maternal tolerance of fetal tissues and the underlying cell-mediated immune and humoral (hormones and cytokines) mechanisms. We also note the many unanswered questions in our understanding of these mechanisms. In addition, we summarize the clinical manifestations of an altered maternal immune system during pregnancy related to susceptibility to common viral, bacterial, and parasitic infections, as well as to autoimmune diseases.Peer reviewe
Erosie door open taludbekledingen. Samenvattend verslag + Bijlage A t/m D
No full textOpen taludbekledingen die bestaan uit in verband geplaatste betonblokken met gaten, bieden de mogelijkheid vegetatie te doen groeien, waardoor mogelijk een milieuvriendelijke oever kan worden verkregen. In het pioniersstadium van de vegetatie is het evenwel ongewenst dat de gatvulling uitspoelt. Teneinde de relatie tussen waterbeweging en erosie van de gatvulling vast te stellen, is door de Dienst Weg- en Waterbouwkunde van Rijkswaterstaat per brief d.d. 16 maart 1987 (kenmerk WB 570), opdracht verleend aan het Waterloopkundig Laboratorium tot het uitvoeren van onderzoek naar de erosie door open taludbekledingen. Het doel van het onderzoek is het ontwikkelen van ontwerprichtlijnen voor taludbekledingen met gaten die groter zijn dan de zand- of filterkorrels eronder. Hiertoe dient de kritieke waterbeweging bij een oever- of dijkbekleding te worden vastgesteld, waarbij nog toelaatbare erosie is te verwachten. De toelaatbare erosie mag daarbij maximaal gelijk zijn aan de hoeveelheid sediment in de gaten. Filter- of basismateriaal gelegen onder de elementen mag dus niet uitspoelen. Bij oeverbekledingen waar vegetatie een rol moet gaan spelen, is de toelaatbare erosie kleiner, dat wil zeggen in de gaten dient sediment achter te blijven.Steenzettingen - TAW/EN
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