1,720,961 research outputs found
Transformation of a terminal to a bridging carbonyl ligand accompanied by iridium-iridium bond cleavage: an example of transmission of electronic effects from one metal center to another
No full textThe alkyne-bridged complex [Ir2Cl2(CO)(μ-DMA)(DPM)2] [DMA = di-Me acetylenedicarboxylate, DPM = bis(diphenylphosphino)methane] reacts with 1 equiv of CO, PMe3, P(OMe)3, or NCMe to give one of two types of species. Reaction with CO yields the complex [Ir2Cl2(CO)2(μ-DMA)(DPM)2], in which both carbonyl groups are terminally bound, one to each metal. However, reaction with L = PMe3, P(OMe)3, or NCMe yields the adduct [Ir2Cl2L(μ-CO)(μ-DMA)(DPM)2], in which the carbonyl group bridges the metals with no accompanying Ir-Ir bond. The long metal-metal sepn. of 3.4580 (7) Å results in a geometry at the bridging carbonyl ligand that is reminiscent of sp2 hybridization [Ir-C(O)-Ir angle of 119.4 (6)°]
Going Beyond Counting First Authors in Author Co-citation Analysis
Get PDFThe present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation
counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings
are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that
only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into
account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed
Variations on the Author
Get PDF“Variations on the Author” discusses two of Eduardo Coutinho’s recent films (Um Dia na Vida, from 2010, and Últimas Conversas, posthumously released in 2015) and their contribution to the general question of documentary authorship. The director’s filmography is characterized by a consistent yet self-effacing form of authorial self-inscription: Coutinho often features as an interviewer that rather than express opinions propels discourses; an interviewer that is good at listening. This mode of self-inscription characterizes him as an author who is not expressive but who is nonetheless markedly present on the screen. In Um Dia na Vida, however, Coutinho is completely absent form the image, while Últimas Conversas, on the contrary, includes a confessional prologue that moves the director from the margins to the center of his films. This article examines the ways in which these works stand out in the filmography of a director who offers new insights into the notion of cinematic authorship
Appropriate Similarity Measures for Author Cocitation Analysis
Get PDFWe provide a number of new insights into the methodological discussion about author cocitation analysis. We first argue that the use of the Pearson correlation for measuring the similarity between authors’ cocitation profiles is not very satisfactory. We then discuss what kind of similarity measures may be used as an alternative to the Pearson correlation. We consider three similarity measures in particular. One is the well-known cosine. The other two similarity measures have not been used before in the bibliometric literature. Finally, we show by means of an example that our findings have a high practical relevance.information science;Pearson correlation;cosine;similarity measure;author cocitation analysis
Pozessstudien zur Erzeugung nah-inertialer interner Schwerewellen durch den Wind
No full textThe generation of internal gravity waves in the ocean associated to wind stress forcing is studied with the aid of two numerical models. In a non-linear, axisymmetric and Boussinesq model the response to an idealized stationary wind stress pulse is investigated. The major generation mechanisms for internal gravity waves, inertial pumping, excites radially outward propagating low mode wave packets. The energy radiated relative to the wind work is found to be only about 0.02%, which is 2-3 orders of magnitude lower than generally observed. In addition to the detailed axisymmetric simulation, a simplified hybrid slab model based on the classical slab model of (Pollard and Millard, 1970) is considered. In particular, the inertial pumping resulting from the divergent, horizontal, near-inertial response of the surface slab is regarded the boundary condition to the internal gravity wave field below the mixed layer. In a set of idealized experiments, laterally moving wind stress fronts are the most efficient driver for vertical motion depending on their translation speed. The application of the hybrid slab model to the North Atlantic for the years 1989 and 1996 as examples of opposite phases of the North Atlantic Oscillation shows latitude bands with characteristic ratio of energy radiated as internal gravity waves to the wind work. These are partly associated to the wind field structure in these meridional regimes. The ratio of total energies transferred equals to 9% for both years. In an application of the hybrid slab model to the axisymmetric setup it is found that the structure of the inertial oscillations of the axisymmetric simulation are well reproduced. However, the near-inertial response of the hybrid slab model has an 8 times larger amplitude and does not include non-linear effects. The ratio of radiated energy to the wind work for the stationary storm estimated with the hybrid slab model is about 1%. This ratio is increased by a factor 30 when the same wind stress structure is moving across the domain with 21 km/h
Dispelling the Myths Behind First-author Citation Counts
Get PDFWe conducted a full-scale evaluative citation analysis study of scholars in the XML research field to explore just how different from each other author rankings resulting from different citation counting methods actually are, and to demonstrate the capability of emerging data and tools on the Web in supporting more realistic citation counting methods. Our results contest some common arguments for the continued
use of first-author citation counts in the evaluation of scholars, such as high correlations between author rankings by first-author citation counts and other citation
counting methods, and high costs of using more realistic citation counting methods that are not well-supported by the ISI databases. It is argued that increasingly available digital full text research papers make it possible for citation analysis studies to go beyond what the ISI databases have directly supported and to employ more
sophisticated methods
koamabayili/VECTRON-author-checklist: VECTRON author checklist
No full textWe have done our best to complete the author checklist relating to the use of animals in the hut study. Note that the objective for the hut study was to evaluate the IRS treatment applications for residual efficacy against Anopheles mosquitoes, including the local An. coluzzii mosquito population. Cows were only used to attract mosquitoes into the huts and no tests were carried out directly on the cows. The author checklist is intended for use with studies where experiments are carried out on animals, which is why we have had such difficulty in completing this for the hut study, as many of the questions do not relate to how the cows were used
Author-wise bibliometric analysis based on entropy.
No full textAuthor-wise bibliometric analysis based on entropy.</p
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