1,721,096 research outputs found
Repairability of CAD/CAM high-density PMMA- and composite-based polymers
Full text linkOBJECTIVE The study aimed to analyse the shear bond strength of computer-aided design and computer-aided manufacturing (CAD/CAM) polymethyl methacrylate (PMMA)- and composite-based polymer materials repaired with a conventional methacrylate-based composite after different surface pretreatments. METHODS Each 48 specimens was prepared from six different CAD/CAM polymer materials (Ambarino high-class, artBloc Temp, CAD-Temp, Lava Ultimate, Telio CAD, Everest C-Temp) and a conventional dimethacrylate-based composite (Filtek Supreme XTE, control) and aged by thermal cycling (5000 cycles, 5-55 °C). The surfaces were left untreated or were pretreated by mechanical roughening, aluminium oxide air abrasion or silica coating/silanization (each subgroup n = 12). The surfaces were further conditioned with an etch&rinse adhesive (OptiBond FL) before the repair composite (Filtek Supreme XTE) was adhered to the surface. After further thermal cycling, shear bond strength was tested, and failure modes were assessed. Shear bond strength was statistically analysed by two- and one-way ANOVAs and Weibull statistics, failure mode by chi(2) test (p ≤ 0.05). RESULTS Shear bond strength was highest for silica coating/silanization > aluminium oxide air abrasion = mechanical roughening > no surface pretreatment. Independently of the repair pretreatment, highest bond strength values were observed in the control group and for the composite-based Everest C-Temp and Ambarino high-class, while PMMA-based materials (artBloc Temp, CAD-Temp and Telio CAD) presented significantly lowest values. For all materials, repair without any surface pretreatment resulted in adhesive failures only, which mostly were reduced when surface pretreatment was performed. CONCLUSIONS Repair of CAD/CAM high-density polymers requires surface pretreatment prior to adhesive and composite application. However, four out of six of the tested CAD/CAM materials did not achieve the repair bond strength of a conventional dimethacrylate-based composite. CLINICAL RELEVANCE Repair of PMMA- and composite-based polymers can be achieved by surface pretreatment followed by application of an adhesive and a conventional methacrylate-based composite
Characterization of Methacrylate-Based Resins Containing Methacryl-Polyhedral Oligomeric Silsesquioxanes (MA-POSS-8)
No full textThe use of functionalized dental adhesives that might prevent degradation of the dentin hybrid layer has been proposed. The aim of the study was to characterize the physicochemical properties and the potential to induce mineral precipitation of methacrylate-based resins containing methacryl-functionalized polyhedral oligomeric silsesquioxane (MA-POSS-8). In total, six different compositions of resins based on bisphenol A glycerolate dimethacrylate (BisGMA, 40 to 60 wt.%), triethylene glycol dimethacrylate (TEGDMA, 5 to 35 wt.%) and 2-hydroxyethyl methacrylate (HEMA, 25 or 35 wt.%) were prepared and infiltrated with 5 wt.% MA-POSS-8. Unfilled resins served as control. Degree of conversion, viscosity, Martens hardness, indentation modulus, water sorption, and sol fraction were investigated. Polymerized specimens were examined by SEM/EDX for the presence of Ca/P precipitates after immersion in artificial saliva for 28 days at 37 °C. Statistical analysis was performed with two-way ANOVA and Tukey’s post-hoc test (p < 0.05). The degree of conversion ranged from 55.0 to 59.8% and was not affected by the addition of MA-POSS-8. Viscosity ranged from 60.0 to 422.3 mPa*s and was not affected by MA-POSS-8 except for one methacrylate-based resin with 60 wt.% BisGMA. Martens hardness and indentation modulus ranged from 161.3 to 138.1 N/mm2 and 4.2 to 3.9 kN/mm2 and were affected by MA-POSS-8 in only one resin (50 wt.% BisGMA, 25 wt.% TEGDMA, 25 wt.% HEMA). Water sorption was not affected by MA-POSS-8; sol fraction was below the detection limit. Formation of Ca/P precipitates was observed on all specimens of test and control groups. Material properties were not affected adversly by MA-POSS-8 except for slight differences in Martens Hardness, indentation modulus, viscosity, in some groups
Shear bond strength of orthodontic resins after caries infiltrant preconditioning
Full text linkOBJECTIVE: To investigate the influence of caries infiltrant preconditioning on the shear bond strength of orthodontic resin cements on sound and demineralized enamel.
MATERIALS AND METHODS: Stainless-steel brackets were bonded to sound or artificially demineralized (14 d, acidic buffer, pH 5.0) bovine enamel specimens using a resin cement or a combination of caries infiltrant preconditioning (Icon, DMG) and the respective resin cement (light-curing composite: Heliosit Orthodontic, Transbond XT, using either Transbond XT Primer or Transbond Plus Self Etching Primer; light-curing resin-modified glass ionomer cement: Fuji Ortho; or self-curing composite: Concise Orthodontic Bonding System). Each group consisted of 15 specimens. Shear bond strength was evaluated after thermo-cycling (10,000×, 5°C to 55°C) at a crosshead speed of 1 mm/min, and data were statistically analyzed by analysis of variance, Mann-Whitney test, and Weibull statistics. Adhesive Remnant Index (ARI) scores and enamel fractures were determined at 25× magnification and were statistically analyzed by regression analyses (P < .05).
RESULTS: The caries infiltrant system significantly increased the shear bond strength of Transbond XT Primer, Transbond Plus Self Etching Primer, and Fuji Ortho in sound specimens, and of all resin cements except for the Concise Orthodontic Bonding System in demineralized enamel. Overall, caries infiltrant preconditioning decreased significantly the number of enamel fractures, but it did not affect ARI scores.
CONCLUSION: Preconditioning of sound and demineralized enamel with the caries infiltrant system did not impair but rather increased the shear bond strength of most orthodontic resin cements while decreasing the risk of enamel fracture at debonding
Influence of caries infiltrant contamination on shear bond strength of different adhesives to dentin
Full text linkOBJECTIVES: To analyze whether the contamination with a caries infiltrant system impairs the adhesive performance of etch-and-rinse and self-etching adhesives on dentin.
MATERIALS AND METHODS: Dentin contamination with the caries infiltrant system (Icon, DMG) was simulated by applying either hydrochloric acid (15 % HCl, Icon Etch, 15 s), the resin infiltrant (Icon infiltrant, 4 min), or both prior to the application of the respective adhesives (each group n = 10). In the control groups, the etch-and-rinse adhesive (Optibond FL, Kerr) and the self-etching adhesive (iBOND Self Etch, Hereaus) were applied without former contamination with the infiltrant system. Additionally, the adhesive performance of the resin infiltrant alone was tested. Shear bond strength of a nano-hybrid composite was analyzed after thermocycling (5,000×, 5-55°C) of the specimens and analyzed by ANOVA/Scheffé post hoc tests (p < 0.05) and Weibull statistics. Failure mode was inspected under a stereomicroscope at × 25 magnification.
RESULTS: Contamination with the resin infiltrant alone did not impair shear bond strength, while contamination with hydrochloric acid or with hydrochloric acid and the resin infiltrant reduced shear bond strength (MPa) of the adhesives (Optibond FL: 20.5 ± 3.6, iBOND Self Etch: 17.9 ± 2.6) significantly. Hydrochloric acid contamination increased the number of adhesive failures. The adhesive performance of the caries infiltrant system alone was insufficient.
CONCLUSION: The contamination with the caries infiltrant system impaired the shear bond strength of conventional dental adhesives.
CLINICAL RELEVANCE: Contamination of the caries infiltrant system on dentin should be avoided due to the detrimental effect of hydrochloric acid etching
Effect of final temperature and heating rate on the mechanical and optical properties of a zirconia veneering ceramic.
Full text linkPURPOSE
To evaluate the effect of firing temperature and heating rate on the volumetric shrinkage, translucency, flexural strength, hardness, and fracture toughness of a zirconia veneering ceramic.
MATERIAL AND METHODS
Zirconia veneering ceramic specimens (N = 45) with varying final temperatures (730 °C, 750 °C, and 770 °C) and heating rates (70 °C/min, 55 °C/min, and 40 °C/min) were fabricated (n = 5). Each specimen's shrinkage, translucency, flexural strength, hardness, and fracture toughness were determined. Two-way analysis of variance, Scheffé test, and Pearson's correlation analysis were used to evaluate data (α = 0.05).
RESULTS
The shrinkage (44.9 ± 3.1-47.5 ± 1.6 vol%) and flexural strength (74.1 ± 17.4-107.0 ± 27.1 MPa) were not affected by tested parameters (P ≥ 0.288). The interaction between the main factors affected the translucency, hardness, and fracture toughness of the specimens (P ≤ 0.007). Specimens with 770 °C final temperature and 70 °C/min heating rate had the lowest (21.8 ± 3.2 %) translucency (P ≤ 0.039). The hardness ranged between 4.98 ± 0.51 GPa (730 °C; 70 °C/min) and 5.60 ± 0.37 GPa (770 °C; 70 °C/min). Fracture toughness ranged between 0.54 ± 0.04 MPa√m and 0.67 ± 0.08 MPa√m with the highest values for specimens fired at 730 °C with 70 °C/min (P ≤ 0.001). There was a positive correlation between translucency and hardness (r = 0.335, P = 0.012), and a negative correlation between fracture toughness and all parameters other than shrinkage (translucency: r = -0.693/P < 0.001, flexural strength: r = -0.258/P = 0.046, hardness: r = -0.457/P < 0.001).
CONCLUSIONS
Heating rate and final temperature should be considered while fabricating veneered zirconia restorations with tested ceramic as they affected the translucency, hardness, and fracture toughness
Repair of silorane composite - using the same substrate or a methacrylate-based composite?
No full textOBJECTIVE: The study aimed to analyze the shear bond strength of aged silorane composite repaired with the same substrate or a conventional methacrylate-based composite after different mechanical and adhesive surface treatments. METHODS: Silorane composite specimens were aged by thermal cycling (5000 cycles, 5-55°C) and randomly assigned to different surface treatments (each group n=16): diamond bur abrasion, aluminum oxide sandblasting, silica coating, or hydrofluoric acid etching. Then, an adhesive system corresponding to the repair composite or a combination of silane agent and the respective adhesive was applied. Silorane composite or a nanofiller composite were adhered onto the conditioned surfaces. In the control group (n=16), silorane composite was adhered to fresh substrate (incremental build up). After further thermal cycling, shear bond strength was tested and failure modes were assessed. Data were analyzed by ANOVA/post hoc tests, Weibull statistics and Chi(2)-test (p≤0.05). RESULTS: Incremental shear bond strength (control group: 21.0±10.5MPa) was achieved by all groups except those etched with hydrofluoric acid or samples abraded with diamond bur and repaired with the nanofiller composite without silane application. Generally, the application of the silane agent improved repair bond strength of the nanofiller but not of the silorane composite. Cohesive failure was observed more frequently than adhesive failure when the silane agent was applied or when silorane composite was used for repair. SIGNIFICANCE: Silorane composite can be repaired with either the same substrate or a methacrylate-based nanofiller composite but requires mechanical surface treatment and - in case of the methacrylate-based composite - silanization prior to adhesive application
Impact of multiple firings on thermal properties and bond strength of veneered zirconia restorations.
No full textOBJECTIVES
This investigation evaluated the impact of multiple firings during the veneering process of all-ceramic restorations on the thermal properties and bond strength between veneering ceramics and zirconia.
METHODS
For the measurements of the coefficient of thermal expansion (CTE) prismatic specimens of four different veneering ceramics (ZRT/ZRO/HFZ/STR; N = 40/n = 10 per veneering ceramic) and rod-shaped zirconia specimens (N = 2) were produced. 2 specimens of each veneering ceramic were fired 2, 4, 6, 8, and 10 times simulating dentine-firing. Measurements were performed in a dilatometer and glass transition temperature (Tg) was determined graphically. To analyze bond strength (BS), crack initiation test specimens were prepared using the same veneering ceramics and zirconia (N = 600/n = 150 per veneering ceramic). 30 specimens of each veneering ceramic were fired 2, 4, 6, 8, and 10 times. Half of them were thermocycled (5000 cycles, 5 °C/55 °C, 20s). The crack initiation test was conducted in a universal testing machine. Data was analyzed using ANOVA with partial eta squared statistics and post-hoc Scheffé test as well as Pearson correlation test.
RESULTS
CTE was mostly affected by the choice of veneering ceramic (p < 0.001/ηp2 = 0.983). For the leucite-free ceramic, the CTE values were in same value range (p = 0.171) along the number of firings. Tg was not influenced by the number of firings. The highest effect on BS showed veneering ceramics (p < 0.001/ηp2 = 0.055) followed by the number of firings (p = 0.011/ηp2 = 0.023). The global difference in BS was lower for 10 firings compared to 2 firings (p = 0.048). Highest BS were measured for the leucite-free veneering ceramic (ZRT). Artificial aging by thermocycling showed no impact on BS (p = 0.755). Correlations were found for HFZ between the BS and the CTE (r = -0.651/p = 0.021). A correlation between CTE and Tg was observed (r = 0.303/p = 0.029).
SIGNIFICANCE
Thermal stability seemed to be more predictable for leucite-free veneering ceramics with superior BS. All BS results exceeded the minimum clinical requirements
Impact of multiple firings on fracture load of veneered zirconia restorations.
No full textOBJECTIVES
This investigation evaluated the impact of multiple firings during the veneering process of anterior all-ceramic restorations on the fracture load (FL) of zirconia crowns veneered with different ceramics (ZRT, ZRO, HFZ, STR).
METHODS
All-ceramic crowns with anatomically reduced zirconia frameworks were prepared using four different veneering ceramics (N = 192/n = 48 per veneering ceramic). The crowns were fired 2 and 10 times. Half of them were thermocycled (5000 cycles, 5 °C/55 °C, 20s). FL using Voss shear test was measured. Data was analyzed using ANOVA with partial eta squared and post-hoc Scheffé-test as well as t-test and Weibull analysis.
RESULTS
Regarding FL, greatest differences were among the number of firings (p<0.001, ηp2 = 0.369). FL was not influenced by the interaction of both number of firings and aging level (p = 0.231) and the interaction of number of firings and veneering ceramic (p = 0.222). Differences were found comparing FL values of ZRT and STR (p<0.001) and of HFZ and STR (p<0.001). No differences occurred among the veneering ceramics after 2 (p = 0.430) and after 10 firings (p = 0.057) in respect to initial FL. For all initially tested veneering ceramics, FL showed higher values after 10 firings (p≤0.001-0.014). When aged, ZRO, HFZ, and STR also provided higher FL values after 10 firings (p≤0.001). For ZRT, FL values differed between initial and aged testing after 2 firings (p = 0.001) with aged specimens providing higher FL values. After 10 firings, none of the veneering ceramics showed differences regarding FL values between initial and aged testing. Weibull modulus was higher for ZRT specimens after 10 firings when tested initially (m = 10.1) and for aged ZRT specimens after 2 firings (m = 11.1). Failures occurred either with chipping of the veneer or total fracture.
SIGNIFICANCE
Veneered zirconia restorations tested presented higher FL after 10 firings compared to 2 firings. Aging via thermocycling showed a positive effect on the FL
Additive Manufacturing for dental restorations by layerwise slurry deposition (LSD-print) technology
No full textThe growing market of custom-made dental restorations offers a major potential for an application of ceramic additive manufacturing (AM).
The possibility to individualize patient specific design and to establish new efficient workflows, from model generation to manufacturing, can be fully exploited by AM technologies. However, for mass customization to be truly envisioned, ceramic AM needs to achieve a level of maturity, aesthetic quality, and productivity comparable to established manufacturing processes.
In this presentation, the potential of the “layerwise slurry deposition” LSD-print technology for dental applications will be explored. It has been shown in the past years that the LSD-print can be applied to advanced ceramic materials such as alumina and silicon-infiltrated silicon carbide. For these materials, the LSD-print technology combines the high-speed printing of binder jetting with the possibility of producing a variety of high-quality ceramics.
The current development deals with the challenges of applying this technology to a feldspar dental material, comparing the quality of AM restorations with the equivalent material for an established CAD/CAM workflow.
Preliminary results not only indicate that the AM material produced by LSD-print can be competitive in terms of mechanical properties, but also that aesthetically satisfactory restorations can be manufactured for veneers, inlays and onlays as well as single unit fixed dental prostheses (FDPs).
The presentation focuses on the material and technological challenges alongside the process chain, from the printing process, to debinding, firing and finishing the restorations
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