177,106 research outputs found

    Growth and characterisation of uranium multilayers.

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    This thesis investigates the extents of the 5f-3d and 5f-4f electronic interactions in U/Fe, U/Co and U/Gd thin films, where electronic hybridisation effects are expected to influence the magnetism of the U 5f states. The samples were prepared by DC magnetron sputtering and included niobium buffer and capping layers to instigate crystalline growth and prevent oxidation of the multilayer stack. Layer thicknesses were varied between 5A and 90A with up to 30 bilayer repeats. The majority of the samples were grown at room temperature, but selected compositions were grown at elevated substrate temperatures. Many well-defined Bragg peaks were evident in the X-ray reflectivity spectra of multilayers of all three systems, indicating a low impurity contamination and a well-reproduced bilayer structure. High-angle X-ray diffraction spectra of the transition metal multilayers revealed poorly crystalline, oriented transition metal layers with a non-crystalline component of Fe and Co of 17A. U/Gd X-ray diffraction spectra displayed intensities up to two orders of magnitude greater than those observed for U/Fe or U/Co samples of similar composition and contained satellite peaks, indicating some degree of coherency between the two species. An intense peak was observed, arising from a crystalline uranium component at a position close to that expected for an exotic hep U phase, oriented in the 001 direction. Bulk magnetisation measurements revealed magnetically 'dead' Fe and Co layers of 15A and magnetic moments tending towards the bulk values of 2.2/zb and 1.7/iB for thick Fe and Co layers respectively. A study of the bulk magnetic properties of the U/Gd system did not indicate the presence of any significant 'dead' layer, but reported a saturation magnetic moment for thick Gd layers of 4.5//b> considerably reduced from the bulk value of 7.63//B- Calculations of the magnetic anisotropy for U/Gd samples revealed a possible transition from the gadolinium moments aligned within the plane of the film to samples displaying perpendicular magnetic anisotropy (PMA), at a gadolinium layer thickness of 5A. This transition could be achieved for thicker Gd layers if the thickness of the U layers were increased. A finite-size scaling effect was observed in a gadolinium layer thickness dependent study of the Curie temperature, indicating a transition from three to two dimensional behaviour for very thin Gd layers. Polarised neutron reflectivity spectra were taken in the specular geometry at magnetic saturation, and were simulated with separate, reduced moment and bulk moment ferromagnetic layers for U/Fe and U/Co samples and a simple bilayer structure for U/Gd samples. This simultaneous measurement of both the physical composition and bulk magnetisation measurements supported results obtained by X-ray reflectivity and magnetometry. The hybridisation of the electronic states in U/Fe and U/Gd resulted in an induced polarisation, detected using element selective techniques. X-ray magnetic circular dichroism measurements at the U Mrv and My edges were used to investigate the spin and orbital components of the uranium magnetic moment and a total magnetic moment on the U site of 0.1/b for the case of U/Fe multilayers, 0.01/zb in U/Gd samples and a signal only barely detectable above the statistical noise in the U/Co system were revealed. A uranium layer thickness dependent study of the magnetic moment values was used to indirectly deduce the profile of uranium magnetisation within the layers. X-ray resonant magnetic reflectivity measurements provided a depth dependent measure of the induced U 5f moment for selected U/Fe samples, which indicated a more complicated interfacial structure than that deduced by X- ray and neutron reflectivity techniques and showed that the majority of the U 5f moment was located at the interface region

    Appropriate Similarity Measures for Author Cocitation Analysis

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    We provide a number of new insights into the methodological discussion about author cocitation analysis. We first argue that the use of the Pearson correlation for measuring the similarity between authors’ cocitation profiles is not very satisfactory. We then discuss what kind of similarity measures may be used as an alternative to the Pearson correlation. We consider three similarity measures in particular. One is the well-known cosine. The other two similarity measures have not been used before in the bibliometric literature. Finally, we show by means of an example that our findings have a high practical relevance.information science;Pearson correlation;cosine;similarity measure;author cocitation analysis

    Epitaxial UN and α-U2N3 thin films

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    Single crystal epitaxial thin films of UN and α-U2N3 have been grown for the first time by reactive DC magnetron sputtering. These films provide ideal samples for fundamental research into the potential accident tolerant fuel, UN, and U2N3, its intermediate oxidation product. Films were characterised using x-ray diffraction (XRD) and x-ray photoelectron spectroscopy (XPS), with XRD analysis showing both thin films to be [001] oriented and composed of a single domain. The specular lattice parameters of the UN and U2N3 films were found to be 4.895 Å and 10.72 Å respectively, with the UN film having a miscut of 2.6°. XPS showed significant differences in the N-1 s peak between the two films, with area analysis showing both films to be stoichiometric

    "Closing the R&D Gap, Evaluating the Sources of R&D Spending"

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    Both spending and tax policies have been implemented in the United States with the goal of stimulating private sector research and development (R&D). Karier questions whether current R&D policy, especially the research and experimentation tax credit, can contribute to closing the gap between nondefense expenditures on R&D in the United States and such expenditures in other countries, such as Japan and Germany. He also explores possible changes to our current R&D policy to make it more effective.

    Oxidation and passivation of the uranium nitride (001) surface

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    The oxidation of uranium mononitride is a potential issue when considering this material as a nuclear fuel. This work investigates the rate and mechanism of this reaction at room temperature, giving insight into fuel surface oxidation during manufacture and storage. Chemical and structural investigation of the ideal surface of an epitaxial (001) UN thin film, shows that a UO2+xNy layer forms on the surface, highlighting the need for better understanding of the U-N-O system. Below this, a U2N3 interlayer is detected. The topotactic formation of these layers is predicted to play a critical role in the passivation measured during long-duration structural investigation

    Going Beyond Counting First Authors in Author Co-citation Analysis

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    The present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed

    Letter from R. R. Zellick, Assistant Trust Officer, Anglo California National Bank of San Francisco, to Joseph R. Goodman, October 2, 1942

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    Letter from R. R. Zellick, Assistant Trust Officer at The Anglo California National Bank of San Francisco, to Joseph R. Goodman, regarding property owned by Dave Tatsuno. Zellick mentions a dispute between current tenants and Tatsuno, and that Tatsuno has asked Goodman to help locate trustworthy tenants.Personal correspondence, organizational records, government documents, publications, and other papers created or collected by Joseph R. Goodman documenting the forced removal and incarceration of Japanese Americans during World War II, as well as organized resistance to incarceration. Included in the collection are records of the Japanese Young Men's Christian Association and the Japanese American Citizens' League in San Francisco, including papers of the Japanese YMCA's executive secretary Lincoln Kanai; Sakai family papers; Goodman's correspondence to and from Japanese American incarcerees, organizations opposing forced removal and incarceration of Japanese Americans, the War Relocation Authority, and others; publications, photographs, and ephemera from the Topaz Relocation Center, where Goodman taught high school; War Relocation Authority records and publications; and newspaper clippings, pamphlets, and reports about forced removal and incarceration created by various government, religious, and civic organizations, in California and nationwide

    Dispelling the Myths Behind First-author Citation Counts

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    We conducted a full-scale evaluative citation analysis study of scholars in the XML research field to explore just how different from each other author rankings resulting from different citation counting methods actually are, and to demonstrate the capability of emerging data and tools on the Web in supporting more realistic citation counting methods. Our results contest some common arguments for the continued use of first-author citation counts in the evaluation of scholars, such as high correlations between author rankings by first-author citation counts and other citation counting methods, and high costs of using more realistic citation counting methods that are not well-supported by the ISI databases. It is argued that increasingly available digital full text research papers make it possible for citation analysis studies to go beyond what the ISI databases have directly supported and to employ more sophisticated methods

    Liftings for noncomplete probability spaces

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    The current state of knowledge concerning liftings for noncomplete probability spaces is discussed. This is a somewhat expanded version of the author's talk given at the 1991 Summer Conference on General Topology and Applications in Honor of Mary Ellen Rudin and Her Work.PT: S; CR: BURKE MR, IN PRESS P AM MATH S BURKE MR, 1991, ISRAEL J MATH, V73, P33 BURKE MR, 1992, ISRAEL J MATH, V79, P289 CARLSON T, THEOREM LIFTING CHRISTENSEN JPR, 1974, TOPOLOGY BOREL STRUC FREMLIN DH, 1989, HDB BOOLEAN ALGEBRAS, P877 INOESCUTULCEA A, 1966, 5TH P BERK S MATH ST, V2 IONESCUTULCEA A, 1967, CONTRIBUTIONS PROB 1, P63 IONESCUTULCEA A, 1969, TOPICS THEORY LIFTIN JECH TJ, 1978, SET THEORY JOHNSON RA, 1980, P AM MATH SOC, V80, P234 JUST W, IN PRESS T AM MATH S KUPKA J, 1983, INDIANA U MATH J, V32, P717 LOSERT V, 1983, LNM, V1080, P95 MAHARAM D, 1958, P AM MATH SOC, V9, P987 SHELAH S, 1983, ISRAEL J MATH, V45, P90 TALAGRAND M, 1982, P AM MATH SOC, V84, P379 VONNEUMANN J, 1931, CRELLES J MATH, V165, P109; NR: 18; TC: 0; J9: ANN N Y ACAD SCI; PG: 4; GA: BZ86BSource type: Electronic(1

    Hansen, Lee (Lee R.). Union, non-union, and managerial pay plan state employees, 2008-2019

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    1 online resource (2 pages)"July 1, 2021."Provides the number of union and non-union state employees in each of the last 14 years. Also provides the number of state employees paid under the state's managerial pay plan during each of those years. Updates OLR research report 2019-R-011
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