1,720,969 research outputs found
Thermodynamic Analysis and Possible Applications of the Integrated Pyrolysis Fuel Cell Plant (IPFCP)
No full textBiomass and waste are generally considered as a very promising option for fossil fuel substitution and greenhouse effect reduction in a sustainable energy scenario. This paper examines the possible lay-out and performance of an innovative energy system based on the integration of a high temperature fuel cell with a pyrolysis reactor. The pyrolyzer converts biomass or solid waste into syngas, which is cleaned from impurities and feeds a Solid Oxide Fuel Cell (SOFC), operating at 1000°C. A combustor supplies the energy required for pyrolysis, burning the solid
and liquid fraction of the pyrolysis yield, as well as the un-oxidized fuel leaving the cell anode. Literature data have been used for determining pyrolysis yield as a function of reactor temperature and evaluating its effect on the plant thermodynamic efficiency. The coupling of the system to a gas turbine using the fuel cell as its combustion chamber is also evaluated. Results show that very interesting efficiencies are obtainable in the 20%–30% range
Rotary Kiln Slow Pyrolysis for Syngas and Char Production From Biomass and Waste-Part II: Introducing Product Yields in the Energy Balance
No full textA microscale electrically heated rotary kiln for slow pyrolysis of biomass and waste was designed and built at the University of Perugia. The reactor is connected to a wet scrubbing section, for tar removal, and to a monitored combustion chamber to evaluate the lower heating value of the syngas. The system allows the evaluation of gas, tar and char yields for different pyrolysis temperature and residence time. The feeding screw conveyor and the kiln are rigidly connected; therefore a modification of the flow rate implies a modification of the inside solid motion and of residence time. Part I of the paper describes the theoretical and experimental evaluation of the working envelope of the reactor that is, rotational speed as a function of feedstock density and humidity content, to obtain pyrolysis conditions inside the kiln. This paper describes the development and resolution of an energy balance of the reactor under pyrolysis conditions. Once the rotational speed n is fixed, the aim of the balance is to obtain the yield of wood biomass pyrolysis products such as syngas, tar and char Results can be used to choose the correct rotational speed of kiln and feeding screw before doing the real pyrolysis test
Gas Turbines Fired With Biomass Pyrolysis Syngas: Analysis of the Overheating of Hot Gas Path Components
No full textAlternative resources, such as biomass, and municipal and industrial waste are being considered as a source for the production of syngas to replace natural gas as a power turbine fuel. Pyrolysis of biomass produces a syngas composed primarily of CO, CO2, CH4, and H2 with a medium-low lower heating value that is strongly dependent on the process boundary conditions such as the pyrolysis temperature and product residence time in the reactor. The issues associated with conventional gas turbines also apply to syngas turbines with the added complexity of the fuel and impurities. At present, syngas turbines are operated at firing temperatures similar to those of turbines fired on natural gas by increasing the fuel mass flow through the turbine. While this produces a higher turbine power output, the heat transferred to the hot flow-path vanes and blades is also greater. The aim of this paper is to report on the use of numerical modeling to analyze the fundamental impact of firing gas turbines with biomass pyrolysis syngas. To complete the analysis, the results have been compared with data from the literature on gas turbines fired with coal gasification syngas. The test engine used to perform this
analysis is a General Electric GE10-2 gas turbine. The performance, aerodynamics and secondary flows were computed using proprietary software, while a commercial finite element software was used to perform the thermal and local creep analyses
Rotary Kiln Slow Pyrolysis for Syngas and Char Production From Biomass and Waste-Part I: Working Envelope of the Reactor
No full textA microscale electrically heated rotary kiln for slow pyrolysis of biomass and waste was designed and built at the University of Perugia. The reactor is connected to a wet scrubbing section, for tar removal, and to a monitored combustion chamber to evaluate the lower heating value of the syngas. The system allows the evaluation of gas, tar and char yields for different pyrolysis temperatures and residence times. The feeding screw conveyor and the kiln are rigidly connected, therefore, a modification of the flow rate implies a modification of the inside solid motion and of residence time. The paper provides the theoretical and experimental calculation of the relationships between residence time and flow rate used to determine the working envelope of the reactor as a function of the feedstock bulk density and moisture content, given the actual heat rate of the electric heaters. The methodology is extendable to any rotary kiln reactor with a rigidly connected feeding screw conveyor given its geometric and energetic specifications. Part II of the paper will extend the energy balance, also introducing the yields of pyrolysis products
Going Beyond Counting First Authors in Author Co-citation Analysis
Full text linkThe present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation
counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings
are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that
only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into
account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed
Variations on the Author
Full text link“Variations on the Author” discusses two of Eduardo Coutinho’s recent films (Um Dia na Vida, from 2010, and Últimas Conversas, posthumously released in 2015) and their contribution to the general question of documentary authorship. The director’s filmography is characterized by a consistent yet self-effacing form of authorial self-inscription: Coutinho often features as an interviewer that rather than express opinions propels discourses; an interviewer that is good at listening. This mode of self-inscription characterizes him as an author who is not expressive but who is nonetheless markedly present on the screen. In Um Dia na Vida, however, Coutinho is completely absent form the image, while Últimas Conversas, on the contrary, includes a confessional prologue that moves the director from the margins to the center of his films. This article examines the ways in which these works stand out in the filmography of a director who offers new insights into the notion of cinematic authorship
Appropriate Similarity Measures for Author Cocitation Analysis
Full text linkWe provide a number of new insights into the methodological discussion about author cocitation analysis. We first argue that the use of the Pearson correlation for measuring the similarity between authors’ cocitation profiles is not very satisfactory. We then discuss what kind of similarity measures may be used as an alternative to the Pearson correlation. We consider three similarity measures in particular. One is the well-known cosine. The other two similarity measures have not been used before in the bibliometric literature. Finally, we show by means of an example that our findings have a high practical relevance.information science;Pearson correlation;cosine;similarity measure;author cocitation analysis
Dispelling the Myths Behind First-author Citation Counts
Full text linkWe conducted a full-scale evaluative citation analysis study of scholars in the XML research field to explore just how different from each other author rankings resulting from different citation counting methods actually are, and to demonstrate the capability of emerging data and tools on the Web in supporting more realistic citation counting methods. Our results contest some common arguments for the continued
use of first-author citation counts in the evaluation of scholars, such as high correlations between author rankings by first-author citation counts and other citation
counting methods, and high costs of using more realistic citation counting methods that are not well-supported by the ISI databases. It is argued that increasingly available digital full text research papers make it possible for citation analysis studies to go beyond what the ISI databases have directly supported and to employ more
sophisticated methods
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