765 research outputs found
An iron(II) complex of trans, trans, trans-bis(azido)bis(4-amino-3,5-bis(2-pyridyl)-1,2,4-triazole): insight into molecular and supramolecular structures using hirshfeld surface analysis and DFT studies
No full textThe solvothermal synthesis and structural characterization of the new high-spin iron(II) complex trans,trans,trans-[bis(azido)bis(4-amino-3,5-bis(2-pyridyl)-1,2,4-triazole)iron(II)] is reported. The complex crystallizes in the triclinic space group Pī with Z = 1, a = 6.6648(3) Å, b = 8.4012(3) Å, c = 11.7970(5) Å, α = 85.063(2)°, β = 95.063(2)°, γ = 98.5080(10)°. It is centrosymmetric with mutually trans pairs of azido, pyridyl and triazole N atoms, the Fe–N distances indicate a high-spin configuration. A combination of N–H···N hydrogen bonds and π···π stacking interactions generates a sheet structure in which the shortest Fe···Fe distance is 6.6648(3) Å. Hirshfeld surface analysis has been performed for visualizing, exploring and quantifying intermolecular interactions that stabilize the crystal packing of the complex. Non-covalent interactions present in the crystal structure have also been analysed by means of computational tools. The interaction energies associated with the different interaction topologies were calculated and QTAIM and NBO analyses were applied to study the origin and nature of the attractive forces.Fil: Setifi, Zouaoui. Université Ferhat Abbas; ArgeliaFil: Setifi, Fatima. Université Ferhat Abbas; ArgeliaFil: Glidewell, Christopher. University of St. Andrews; Reino UnidoFil: Gil, Diego Mauricio. Universidad Nacional de Tucumán. Instituto de Biotecnología Farmacéutica y Alimentaria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Biotecnología Farmacéutica y Alimentaria; ArgentinaFil: Kletskov, Alexey V.. University of Russia; RusiaFil: Echeverria, Jorge. Universidad de Barcelona; EspañaFil: Mirzaei, Masoud. University of Mashhad; Irá
A combined experimental, Hirshfeld surface analysis, and theoretical study on fac-[tri(azido)(tris(2-pyridyl)amine)iron(III)]
No full textA novel Fe(III) complex with the general formula [Fe(tpa)(N3)3] (1) (tpa = tris(2-pyridyl)amine), has been prepared by solvothermal synthesis and characterized by standard spectroscopic and analytical methods to determine its composition. Crystal structure analysis at 170 K shows that the tris(2-pyridyl)amine ligand is coordinated in tridentate fashion via the pyridyl N atoms and the complex as a whole has approximate threefold rotational symmetry: the Fe–N distances indicate that the metal centre adopts a low-spin configuration at 170 K. A combination of two C-H···N hydrogen bonds and two azido···π(pyridyl) interactions link the molecules into a continuous three-dimensional array. An analysis of the complex total energy evaluated the preference of the high-, intermediate- and low-spin complexes. DFT calculations showed that the high-spin complex is the least energetic of the three possible spin states. The Quantum Theory of Atoms In Molecules (QTAIM), Reduced Density Gradient (RDG), and Natural Bond Orbitals (NBO) analysis showed an azido···azido interactions cooperatively assisted by weak hydrogen bonds and lone-pair···π interactions between N3– and the pyridine fragment from the tris(2-pyridyl)amine ligand. The amine and N3– arrange to bear a caged anion. The azido···azido interaction nature can be related to the donation from the N lone-pair to the π* of the opposite anion.Fil: Setifi, Zouaoui. Université 20 Août 1955-Skikda; Argelia. Université Ferhat Abbas Sétif 1; ArgeliaFil: Cubillán, Néstor. Universidad del Atlántico; ColombiaFil: Glidewell, Christopher. University of St. Andrews; Reino UnidoFil: Gil, Diego Mauricio. Universidad Nacional de Tucumán. Instituto de Biotecnología Farmacéutica y Alimentaria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Biotecnología Farmacéutica y Alimentaria; Argentina. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química Orgánica; ArgentinaFil: Torabi, Elham. Ferdowsi University Of Mashhad; IránFil: Morales Toyo, Miguel. Universidad Central del Este; República DominicanaFil: Dege, Necmi. Ondokuz Mayıs University; TurquíaFil: Setifi, Fatima. Université Ferhat Abbas Sétif 1; ArgeliaFil: Mirzaei, Masoud. Ferdowsi University Of Mashhad; Irá
HERMENEUTIKA HADIS ALA FATIMA MERNISSI
No full textHermeneutics is a new method in understanding and meaning of the hadiths. It used by some contemporary moslem scholars. One of them is Fatima Mernissi. She concentrates to misoginic hadiths that discriminate women. In this article, the author tries to see her hermeneutics methodology. The methodology that is offered by Fatima Mernissi in studying hadith is double investigation with psycho-history as her approach. There are two steps in her method, that are historical aspect and methodology aspect. The first step is analyzing situation and condition that happen when hadith released and then, analyzing about the first transmitter, when, why and to whom that hadith is released
HERMENEUTIKA HADIS ALA FATIMA MERNISSI
No full textHermeneutics is a new method in understanding and meaning of the hadiths. It used by some contemporary moslem scholars. One of them is Fatima Mernissi. She concentrates to misoginic hadiths that discriminate women. In this article, the author tries to see her hermeneutics methodology. The methodology that is offered by Fatima Mernissi in studying hadith is double investigation with psycho-history as her approach. There are two steps in her method, that are historical aspect and methodology aspect. The first step is analyzing situation and condition that happen when hadith released and then, analyzing about the first transmitter, when, why and to whom that hadith is released
Fatima Jinnah
No full textAlthough fifty years have passed since the death of Fatima Jinnah - author, activist and stateswoman known in Pakistan as the &apos;mother of the nation&apos; - this is the first scholarly biography to tackle her life in full. Her background and contribution to Muslim nationalism under the British Raj, as well as her various efforts to consolidate the state, including a run for president in 1964, are told through previously untapped archival sources. Examining her life in the context of scholarship on South Asia and on women in Islam, Pirbhai assesses Fatima Jinnah&apos;s role through the theoretical lens of the colonial &apos;new woman&apos;. This is essential reading for all those interested in modern South Asian and Islamic history, particularly the themes of gender and colonialism, the roots of Muslim nationalism and the early challenges facing the Pakistani state, as shown through the extraordinary lived experience of its most influential female activist.</jats:p
HERMENEUTIKA HADIS ALA FATIMA MERNISSI
No full textHermeneutics is a new method in understanding and meaning of the hadiths. It used by some contemporary moslem scholars. One of them is Fatima Mernissi. She concentrates to misoginic hadiths that discriminate women. In this article, the author tries to see her hermeneutics methodology. The methodology that is offered by Fatima Mernissi in studying hadith is double investigation with psycho-history as her approach. There are two steps in her method, that are historical aspect and methodology aspect. The first step is analyzing situation and condition that happen when hadith released and then, analyzing about the first transmitter, when, why and to whom that hadith is released.</jats:p
Actuality of the Messages of Fatima in the Churches of Our Lady of Fatima in Croatia
No full textStotinu godina nakon fatimskih događaja u Crkvi u Hrvata prisutne su i aktualne Gospine poruke iz Fatime. O tome svjedoče i crkve posvećene Gospi Fatimskoj u kojima Kristovi vjernici svoj život nadahnjuju na fatimskim porukama molitve i pokore, obraćenja i mira. U ovom radu autor predstavlja te crkve i analizira kako se u njima prihvaćaju i aktualiziraju fatimske Gospine poruke. U uvodnom dijelu prikazuje dolazak vijesti o fatimskim zbivanjima na hrvatska područja, početak hodočašćenja hrvatskih vjernika u Fatimu te nastanak i ukorjenjivanje pobožnosti Gospi Fatimskoj među hrvatskim katolicima, što se očitovalo i u gradnji crkava, kapela i kapelica njoj u čast. U zaključnom dijelu vrednuje prihvaćanje i aktualiziranje fatimskih poruka vezanih uz te crkve te njihov utjecaj na marijansku pobožnost u hrvatskim krajevima.A hundred years after the events at Fatima, the messages from Our Lady of Fatima are present and active among the faithful Croatians. This is evident through the amount of churches dedicated to Our Lady of Fatima, in which Christ’s believers are inspired by the Fatima messages of prayer and penance, conversion and peace. In this article, the author presents these churches and remarks on the acceptance of the messages of Our Lady of Fatima in them over time. In the introduction, he writes about the arrival of news regarding the Fatima events to the Croatian territory, the start of the pilgrimage of believers in Fatima and the beginning and delving devotion to Our Lady of Fatima among Croatian Catholics. This is evident through the construction of churches, chapels, and small chapels in her honour. In the conclusion, he evaluates the acceptance and actualization of Fatima’s messages in these churches and their influence on the Marian devotion in the Croatian regions
The synthesis, characterization, X-ray structure and magnetism of dinuclear-based bis[μ-(1,1,3,3-tetracyano-2-ethoxypropenido-κ2N,N′) (1,1,3,3-tetracyano-2-ethoxypropenido-κN)(2,2′-bipyridine)copper(II)] organized in alternating chains via semi-coordinating Cu–N distances
No full textThe monoanionic ligand 1,1,3,3 tetracyano-2 ethoxypropenide (tcnoet) is reported with its Cu(II)–bpy complex of formula [Cu2(µ-tcnoet)2(tcnoet)2(bpy)2]. The structure has been determined using X-ray diffraction and features an alternating chain with bridging tcnoet ligands. One ligand acts as a bidentate, dinucleating ligand with one short Cu–N and one medium Cu–N bond, whereas the other tcnoet is largely monodentate, albeit with a very weak interdimer Cu–N bond. Despite the arrangement in dinuclear units, further arranged into linear chains through the non-bridging tcnoet ligand, the compound shows no significant magnetic exchange, as deduced from magnetic susceptibility down to 4 K. Ligand-field, IR and EPR spectra in the solid state and in frozen solution are reported and are consistent with the overall structure
Belenggu Patriarki dalam Novel Perempuan-Perempuan Harem Karya Fatima Mernissi
No full textThis study discusses the shackles of women, the structure of the work and the author\u27s worldview in the novel Perempuan-Perempuan Harem by Fatima Mernissi. Women\u27s shackles are a limitation of women in obtaining their rights as a woman. The structure of the work is the constituent element of literary works and is often also called the intrinsic element. The structure of the work analyzed in this study includes: Themes, characterizations, plot, setting and point of view. The author\u27s world view is a form of mediation (compromise) between the structure of society and elements of literary works. The method used in this research is descriptive analysis method. Descriptive method of analysis is done by describing the facts and then doing the analysis, The theoretical approach taken is Lucian Goldman\u27s. Analysis of the novel Perempuan-Perempuan Harem by Fatima Mernissi found that there are female shackles, the structure of the work is the theme, plot, characters and characterizations, setting and point of view. The world view of the author that Fatima Mernissi feels as the author of the novel Perempuan-Perempuan Harem is that there are limitations for women in their family environment because they adhere to traditions that limit women\u27s behavior, unlike Moroccan women in general
The Topic of Fatima in Leon Lovrenčić’s Collection of Sermons Imakulata
No full textAutor u radu analizira marijanske propovijedi Leona Lovrenčića objavljene 1957. godine u zbirci naslovljenoj Imakulata, tražeći u njima govor o ukazanjima Gospe u Fatimi, fatimskim porukama i događajima koji su s tim povezani. U uvodnom dijelu rada ukratko je ocrtan život i rad Leona Lovrenčića da bi u središnjem dijelu prvo bila opisana zbirka objavljenih propovijedi Imakulata i bilježnica istoga naslova iz koje su one preuzete, zatim naznačena bitna obilježja Lovrenčićevih propovijedi, a potom predstavljen njegov govor o Fatimi i fatimskim događajima. U tom dijelu autor se referira i na neobjavljene propovijedi iz bilježnice Imakulata, koja se nalazi u Lovrenčićevoj ostavštini u Franjevačkom samostanu na Kaptolu. Na kraju rada, u zaključku, autor naznačuje nekoliko karakteristika traženog govora o Gospi Fatimskoj, Fatimi i fatimskim događanjima u propovijedima Leona Lovrenčića iz zbirke Imakulata.In the article the author analyses Leon Lovrenčić’s Marian sermons, published in 1957 in the collection entitled Imakulata, by focusing on how they discuss apparitions of our Lady in Fatima, Fatima messages, and events related to them. The introductory part sketches the life and work of Leon Lovrenčić, while the central part of the article describes the collection of published sermons, Imakulata, and the notebook of the same title from which these sermons were taken over. This is followed by an account of essential characteristics of Lovrenčić’s sermons and an overview of his discourse on Fatima and Fatima events. In this last section the author also takes into account unpublished sermons from the notebook Imakulata that is preserved in the legacy of Leon Lovrenčić in the Franciscan monastery on Kaptol and from which published sermons have been taken over. At the end of the article, in conclusion, the author sketches a few characteristics of the analysed discourse on Our Lady of Fatima, Fatima, and Fatima events in Leon Lovrenčić’s sermons from the collection Imakulata
- …
