12,449 research outputs found
Stephen Schofield : Milk Milk Lemonade, Chocolate Around the Corner
In this artist's book published in conjunction with an exhibition of Schofield's work in Buffalo, photographs by various artists accompany remembered street-chants of children in various cities around the world
Stephen Schofield
Sangster explains how Schofield's visual language stems from recognizable images linked to identity, the body, childhood, and the effects of socialization. Biographical notes. 9 bibl. ref
Stephen Schofield
Tisseron analyses the multiple aspects of Schofield's recent soft-sculptures. The author notes their characteristic relationship with depth, links them to the preverbal experience of maternal touching, and examines the interface function of the materials. Artist's statement. Biographical notes. 11 bibl. ref
Service-oriented models for audiovisual content storage
What are the important topics to understand if involved with storage services to hold digital audiovisual content? This report takes a look at how content is created and moves into and out of storage; the storage service value networks and architectures found now and expected in the future; what sort of data transfer is expected to and from an audiovisual archive; what transfer protocols to use; and a summary of security and interface issues
The preparation of C-3 building blocks and their use in heterocyclic synthesis
This work concerns the investigation of new synthetic routes to heterocycles via a building block strategy. Three classes of heterocycle are targeted - pyrimidines, pyrazoles and isoxazoles. These classes cover both five- and six-membered ring systems and are representative of a much wider range of target molecules, having possible bioactivity. All three classes of heterocycle can also be produced from the same type of building block by altering the nature of the bisnucleophile used to close the ring (a 2- or 3-atom unit).The building blocks employed contain a 1,3-dicarbonyl structure with a protected carbonyl group at the 2-position. The first building blocks prepared have a protected ester by way of a ketene dithioacetal. The reduction of this group (by dissolving metal) leads to a dithiane, equivalent to a formyl group. Both the ketene dithioacetals and the dithianes are subsequently cyclised to the five- and six-membered heterocycles. Ketene dithioacetal building blocks generate heterocycles that bear a novel mercapto thioether side chain. Building blocks based on dithianes show complex cyclisation patterns by offering multiple reaction sites.The incorporation of fluorine into this class of building block proved to be troublesome so attention was focused on the use of vinyl ethers and enamines as masked formyl equivalents. By adapting the work of Schreiber and developing a novel procedure to form fluorinated building blocks, it is possible to isolate three heterocyclic precursors - a bis(trifluoroacetyl)-and mono)trifluoroacetyl)-enamine and an analogous compound containing a dithiane-masked formyl unit. These building blocks have then been converted into all three classes of heterocycle described earlier.By comparing the data of molecules generated by this route with those in recent literature it is possible to gain a much more complete view of the cyclisation processes. For example, many of the building blocks used in this work contain more than two sites for reaction which lead to complex mechanistic possibilities which can be rationalised.The initial objective of merging an intrinsically bioactive molecule (the classes of heterocycle chosen) with a bioactive enhancer (the inclusion of fluorine into these molecules) has proven successful.</p
AC-6-U.S. Naval Planes Flying in Formation, Langley Field, VA/Thank-You Card from Stephen Tury to the Hungarian Defense Council.
This postcard, which depicts U.S. Naval planes flying in formation, was sent to the Hungarian Defense Council by Private Stephen Tury. The Council was organized in New Brunswick by leaders of local Hungarian churches and societies. During the Second World War it sent supplies, such as the carton of cigarettes Tury is thanking it for, to members of the military of Hungarian descent from the New Brunswick area
Author Stephen Flynn Discusses Resiliency
Center for Homeland Defense and Security, PRESS RELEASESOn September 25, Author Stephen E. Flynn stopped by the Center’s National Capital Region campus to speak with CHDS Master’s degree students about his latest book, answer questions and discuss..
Letter from Carl Hayden to Stephen Mather, National Park Service
Letter from Carl Hayden to Stephen Mather regarding the sale of Bass properties
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