1,720,963 research outputs found
Complexos macrocíclicos polinucleares mediados por ponte cianeto. Síntese, caracterização e aplicações em química supramolecular
Get PDFOrientador : Prof. Dr. Fábio Souza NunesDissertação (mestrado) - Universidade Federal do Paraná, Setor de Ciencias Exatas, Programa de Pós-Graduação em Química. Defesa: Curitiba, 25/03/2011Inclui bibliografiaResumo: Dentro da Quimica, os compostos de coordenacao tem encontrado grande campo de atuacao, principalmente por oferecerem caracteristicas unicas, aliadas a flexibilidade de estados de oxidacao e estabilidade dos ions metalicos, na obtencao de materiais com diversas propriedades eletronicas, opticas, magneticas e biologicas. Os cianometalato-complexos, os quais possuem o cianeto como ligante-ponte, sao os mais investigados dentre as estruturas supramoleculares baseadas em interacoes metalicas. Com a finalidade de preparar compostos polinucleares, os ligantes macrociclicos sao interessantes porque bloqueiam as posicoes equatoriais, viabilizando interacoes apenas na regiao axial, possibilitando, assim, a obtencao de fios moleculares. Neste sentido, justifica-se o uso do ligante binuclear macrociclico tetraiminodifenolico (tidf) como bloco construtor. Foram preparados, com a finalidade de obtencao de complexos polinucleares, dois complexos macrociclicos binucleares [Cu2(tidf)(ClO4)2(H2O)2] e [Co2(tidf)(ClO4)2(H2O)2], sendo este ultimo inedito na literatura. Utilizando estes dois complexos, juntamente com cianometalatos diversos, foram obtidos tres complexos ineditos, [{Cu2(tidf)(OH2)}2(ƒÊ-CN)2{Fe(CN)4}] E12H2O, [Cu2(tidf)(H2O)2][Fe(CN)5NO] EH2O e [Cu2(tidf)(H2O)2][Ni(CN)4], o primeiro pentanuclear e os seguintes trinucleares. Os tres complexos sao produtos das reacoes do complexo [Cu2(tidf)(ClO4)2(H2O)2] com os cianometalatos K4[Fe(CN)6] E3H2O, K4[Ni(CN)4] e Na2[Fe(CN)5NO].2H2O. O complexo pentanuclear apresenta o ligante cianeto como ponte entre os centros de cobre(II) e ferro(II). Ja os complexos trinucleares, apresentam os ligantes cianeto interagindo com moleculas de agua por ligacao de hidrogenio, formando estruturas supramoleculares em que a comunicacao entre o complexo macrociclico e o cianometalato e mediada por esse tipo de interacao. Todos os complexos obtidos formaram cristais susceptiveis a difracao de raios X. Alem disso, todos os complexos obtidos, alem dos seus precursores, foram caracterizados por tecnicas de Espectroscopia na regiao do UV-Visivel e Infravermelho, Ressonancia Paramagnetica Eletronica e Ressonancia Magnetica Nuclear, Espectroeletroquimica e Voltametria Ciclica, Analise Elementar e Medidas de Magnetismo Molecular. Os valores de constante de acoplamento magnetico, J, mostraram uma forte interacao intermetalica entre os centros atraves da ponte fenolato. Esta interacao e forte o suficiente para mascarar efeitos magneticos derivados da interacao entre os metais atraves da ponte cianeto. As propriedades espectrais correlacionaram-se com as distorcoes estruturais exibidas pelos dados cristalograficos e os resultados foram racionalizados com base na teoria de campo cristalino.Abstract: In chemistry coordination compounds have been intensively studied because they offer unique features, combined with the flexibility of metal ions and stability of oxidation states, to obtain materials with different electronic, optical, magnetic and biological properties. The cianometalato-complexes, which have the cyanide as bridging ligand, are among the most investigated supramolecular structures based on interactions between metal ions. In order to prepare polynuclear compounds, macrocyclic ligands are interesting because they block the equatorial positions, and favor axial substitution, thus enabling the achievement of molecular wires. In this sense, we have used binucleant macrocyclic ligand tetraiminodifenolico (tidf) as a building block. Two binuclear complexes [Cu2(tidf)(ClO4)2(H2O)2] and [Co2(tidf)(ClO4)2(H2O)2] were prepared, the latter being unique in the literature. Using these two complexes, along with several cyanide-metal complexes three new complexes were prepared, [{Cu2(tidf)(OH2)}2(ƒÊ-CN)2{Fe(CN)4}].12H2O, [Cu2(tidf)(H2O)2][Fe(CN)5NO] EH2O and [Cu2(tidf)(H2O)2][Ni(CN)4]. The first one is pentanuclear and the others are trinuclear. The three complexes are products of the reactions of the complex [Cu2(tidf)(ClO4)2(H2O)2] with the cianometalatos K4[Fe(CN)6].3H2O, K4[Ni(CN)4] and Na2[Fe(CN)5NO].2H2O. The pentanuclear complex features the cyanide ligand as a bridge between the centers of copper(II) and iron(II). The crystal structure of both trinuclear complexes showed hydrogen bonding between water molecules and the cyanides to form supramolecular architetures. All complexes, and their precursors, were characterized by Spectroscopy in the UV-Visible and Infrared, Electronic Paramagnetic Resonance and Nuclear Magnetic Resonance, Spectroelectrochemistry and Cyclic Voltammetry, Elemental Analysis and Measures of Molecular Magnetism. Calculated magnetic coupling constant, J, is consistent with a strong intermetallic communication through the phenolate bridge, a phenomenon strong enough to mask any other relevant magnetic property. UV-vis data were interpreted based on crystal field theory and the energy of the transitions were correlated with structural distortions of the compounds
Going Beyond Counting First Authors in Author Co-citation Analysis
Get PDFThe present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation
counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings
are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that
only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into
account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed
Variations on the Author
Get PDF“Variations on the Author” discusses two of Eduardo Coutinho’s recent films (Um Dia na Vida, from 2010, and Últimas Conversas, posthumously released in 2015) and their contribution to the general question of documentary authorship. The director’s filmography is characterized by a consistent yet self-effacing form of authorial self-inscription: Coutinho often features as an interviewer that rather than express opinions propels discourses; an interviewer that is good at listening. This mode of self-inscription characterizes him as an author who is not expressive but who is nonetheless markedly present on the screen. In Um Dia na Vida, however, Coutinho is completely absent form the image, while Últimas Conversas, on the contrary, includes a confessional prologue that moves the director from the margins to the center of his films. This article examines the ways in which these works stand out in the filmography of a director who offers new insights into the notion of cinematic authorship
Appropriate Similarity Measures for Author Cocitation Analysis
Get PDFWe provide a number of new insights into the methodological discussion about author cocitation analysis. We first argue that the use of the Pearson correlation for measuring the similarity between authors’ cocitation profiles is not very satisfactory. We then discuss what kind of similarity measures may be used as an alternative to the Pearson correlation. We consider three similarity measures in particular. One is the well-known cosine. The other two similarity measures have not been used before in the bibliometric literature. Finally, we show by means of an example that our findings have a high practical relevance.information science;Pearson correlation;cosine;similarity measure;author cocitation analysis
Dispelling the Myths Behind First-author Citation Counts
Get PDFWe conducted a full-scale evaluative citation analysis study of scholars in the XML research field to explore just how different from each other author rankings resulting from different citation counting methods actually are, and to demonstrate the capability of emerging data and tools on the Web in supporting more realistic citation counting methods. Our results contest some common arguments for the continued
use of first-author citation counts in the evaluation of scholars, such as high correlations between author rankings by first-author citation counts and other citation
counting methods, and high costs of using more realistic citation counting methods that are not well-supported by the ISI databases. It is argued that increasingly available digital full text research papers make it possible for citation analysis studies to go beyond what the ISI databases have directly supported and to employ more
sophisticated methods
koamabayili/VECTRON-author-checklist: VECTRON author checklist
No full textWe have done our best to complete the author checklist relating to the use of animals in the hut study. Note that the objective for the hut study was to evaluate the IRS treatment applications for residual efficacy against Anopheles mosquitoes, including the local An. coluzzii mosquito population. Cows were only used to attract mosquitoes into the huts and no tests were carried out directly on the cows. The author checklist is intended for use with studies where experiments are carried out on animals, which is why we have had such difficulty in completing this for the hut study, as many of the questions do not relate to how the cows were used
Author-wise bibliometric analysis based on entropy.
No full textAuthor-wise bibliometric analysis based on entropy.</p
Author Under Sail The Imagination of Jack London, 1893-1902
No full textIn Author Under Sail, Jay Williams offers the first complete literary biography of Jack London as a professional writer engaged in the labor of writing. It examines the authorial imagination in London's work, the use of imagination in both his fiction and nonfiction, and the ways he defined imagination in the creative process in his business dealings with his publishers, editors, and agents. In this first volume of a two-volume biography, Williams traverses the years 1893 to 1902, from London's "Story of a Typhoon" to The People of the Abyss. The Jack London who emerges in the pages of Author Under Sail is a writer whose partnership with publishers, most notably his productive alliance with George Brett of Macmillan, was one of the most formative in American literary history. London pioneered many author models during the heyday of realism and naturalism, blurring the boundaries of these popular genres by focusing on absorption and theatricality and the representation of the seen and unseen. London created an impassioned, sincere, and extremely personal realism unlike that of other American writers of the time. Author Under Sail is a literary tour de force that reveals the full range of London as writer, creative citizen, and entrepreneur at the same time it sheds light on the maverick side of machine-age literature.Intro -- Title Page -- Copyright Page -- Dedication -- Contents -- Acknowledgments -- Introduction -- 1. Spirit Truth -- 2. From Absorption to Theatricality and Back Again -- 3. "I Will Build a New Present" -- 4. Sons as Authors -- 5. Fathers as Publishers -- 6. The Daughter as Author -- 7. Lovers as Authors -- 8. At Sea with the Family -- 9. Yellow News, Yellow Stories -- 10. The Return Home -- Notes -- Bibliography -- Index -- About Jay WilliamsIn Author Under Sail, Jay Williams offers the first complete literary biography of Jack London as a professional writer engaged in the labor of writing. It examines the authorial imagination in London's work, the use of imagination in both his fiction and nonfiction, and the ways he defined imagination in the creative process in his business dealings with his publishers, editors, and agents. In this first volume of a two-volume biography, Williams traverses the years 1893 to 1902, from London's "Story of a Typhoon" to The People of the Abyss. The Jack London who emerges in the pages of Author Under Sail is a writer whose partnership with publishers, most notably his productive alliance with George Brett of Macmillan, was one of the most formative in American literary history. London pioneered many author models during the heyday of realism and naturalism, blurring the boundaries of these popular genres by focusing on absorption and theatricality and the representation of the seen and unseen. London created an impassioned, sincere, and extremely personal realism unlike that of other American writers of the time. Author Under Sail is a literary tour de force that reveals the full range of London as writer, creative citizen, and entrepreneur at the same time it sheds light on the maverick side of machine-age literature.Description based on publisher supplied metadata and other sources.Electronic reproduction. Ann Arbor, Michigan : ProQuest Ebook Central, YYYY. Available via World Wide Web. Access may be limited to ProQuest Ebook Central affiliated libraries
- …
