1,721,041 research outputs found
Multiparameter Raman Lidar Measurements for the Characterization of a Dry Stratospheric Intrusion Event
No full textThe University of Basilicata Raman lidar system (BASIL) is operational in Potenza, Italy, and it is capable of performing high-resolution and accurate measurements of atmospheric temperature and water vapor based on the application of the rotational and vibrational Raman lidar techniques in the ultraviolet region. BASIL was recently involved in the 2005 International Lindenberg campaign for Assessment of Humidity and Cloud Profiling Systems and Its Impact on High-Resolution Modeling (LAUNCH 2005) experiment held from 12 September to 31 October 2005. A thorough description of the technical characteristics, measurement capabilities, and performances of BASIL is given in this paper. Measurements were continuously run between 1 and 3 October 2005, covering a dry stratospheric intrusion episode associated with a tropopause folding event. The measurements in this paper represent the first simultaneous Raman lidar measurements of atmospheric temperature, water vapor mixing ratio, and thus relative humidity reported for an extensive observation period (32 h). The use of water vapor to trace intruded stratospheric air allows the clear identification of a dry structure (similar to 1 km thick) originating in the stratosphere and descending in the free troposphere down to; 3 km. A similar feature is present in the temperature field, with lower temperature values detected within the dry-air tongue. Relative humidity measurements reveal values as small as 0.5%-1% within the intruded air. The stratospheric origin of the observed dry layer has been verified by the application of a Lagrangian trajectory model. The subsidence of the intruding heavy dry air may be responsible for the gravity wave activity observed beneath the dry layer. Lidar measurements have been compared with the output of both the fifth-generation Pennsylvania State University-National Center for Atmospheric Research (PSU-NCAR) Mesoscale Model (MM5) and the European Centre for Medium-Range Weather Forecasts (ECMWF) global model. Comparisons in terms of water vapor reveal the capability of MM5 to reproduce the dynamical structures associated with the stratospheric intrusion episode and to simulate the deep penetration into the troposphere of the dry intruded layer. Moreover, lidar measurements of potential temperature are compared with MM5 output, whereas potential vorticities from both the ECMWF model and MM5 are compared with estimates obtained combining MM5 model vorticity and lidar measurements of potential temperature
High levels of genetic variability and population differentiation in Gressittacantha terranova (Collembola, Hexapoda) from Victoria Land, Antarctica
No full textAllozyme electrophoresis was used to asses genetic variability and differentiation in 22 populations of Gressittacantha terranova Wise (Hexapoda, Collembola) from a coastal area of Victoria Land between the Mariner Glacier and the Nansen Ice Sheet. Allelic frequencies were determined at five enzyme loci: Phi, Pgm, Hk, Mpi and Mdh. Levels of variability, estimated as rates of heterozygosity, were higher than those calculated for the same loci in taxonomically related and non-related species of non-Antarctic Collembola. Thus, in spite of the ecological simplicity of Antarctic terrestrial ecosystems, G. terranova is characterized by high levels of genetic variability, and the 22 populations could be divided into three geographic groups, separated by the Aviator and Campbell glaciers. Genetic differentiation reflects the geographic arrangment of the populations, suggesting that the glaciers are effective barriers to gene flow, and that the patchy distribution of collembolan species in Antarctica has the potential to induce, in the long term, microspeciation processes. Interestingly, detectable genetic differentiation was observed between six populations collected at Edmonson Point, even though these are very close to each other, indicating the impact of geographic isolation even within short distances. The only exception to the congruence between genetic and geographic structuring was provided by the population of Apostrophe Island, for which a recent introduction with individuals coming from southern populations is suggested
How Reducing Fossil-Based Plastic Use Can Help the Overall Sustainability of Oyster Farming: The Case of the Gulf of La Spezia
No full textOyster farming plays a crucial role in sustainable food production due to its high nutritional value and relatively low environmental impact. However, in a scenario of increasing production, it is necessary to consider the issue of plastic use as a limitation to be addressed. A life cycle assessment (LCA) was conducted on oyster farming in La Spezia (Italy) as a case study, utilizing 1 kg of packaged oysters as the functional unit. Fossil-based plastics and wooden packaging were identified as the primary environmental concerns. To analyze potential strategies for reducing the environmental impact of oyster farming, alternative scenarios were considered wherein fossil-based materials were replaced with bio-based materials. Specifically, this study examined the substitution of the current packaging, consisting of a wooden box and a polypropylene (PP) film, with a fully recyclable PP net. Additionally, polylactic acid (PLA), polyhydroxyalkanoates (PHAs), and bio-based polyethylene terephthalate (Bio-PET) were proposed as alternatives to virgin high-density polyethylene (HDPE) and PP for buoys, oyster bags, and boxes. Among the scenarios analyzed, the sole effective strategy to reduce the impact of plastics on the process is to replace them with PHA. In the other cases, the high energy consumption of their non-optimized production renders them disadvantageous options. However, the assessment must include the effects of degradation that traditional plastics can have in the marine environment, an aspect that potentially renders natural fibers more advantageous. The use of PP net packaging has demonstrated high efficacy in reducing impacts and provides a foundation for considering the need to combine sustainability and marketing with current legislation regarding food packaging
Δ1-Dehydrogenation and C20 Reduction of Cortisone and Hydrocortisone Catalyzed by Rhodococcus Strains
No full textPrednisone and prednisolone are steroids widely used as anti-inflammatory drugs. Development of the pharmaceutical industry is currently aimed at introducing biotechnological processes and replacing multiple-stage chemical syntheses. In this work we evaluated the ability of bacteria belonging to the Rhodococcus genus to biotransform substrates, such as cortisone and hydrocortisone, to obtain prednisone and prednisolone, respectively. These products are of great interest from a pharmaceutical point of view as they have higher anti-inflammatory activity than the starting substrates. After an initial lab-scale screening of 13 Rhodococcus strains, to select the highest producers of prednisone and prednisolone, we reported the 200 ml-batch scale-up to test the process efficiency and productivity of the most promising Rhodococcus strains. R. ruber, R. globerulus and R. coprophilus gave the Delta 1-dehydrogenation products of cortisone and hydrocortisone (prednisone and prednisolone) in variable amounts. In these biotransformations, the formation of products with the reduced carbonyl group in position C-20 of the lateral chain of the steroid nucleus was also observed (i.e., 20 beta-hydroxy-prednisone and 20 beta-hydroxy-prednisolone). The yields, the absence of collateral products, and in some cases the absence of starting products allow us to say that cortisone and hydrocortisone are partly degraded
Aspergillus oryzae grown on rice hulls used as an additive for pretreatment of starch-containing wastewater from the pulp and paper industry
No full textFrom an industrial point of view, the use of microorganisms as a wastewater bioremediation practice represents a sustainable and economic alternative for conventional treatments. In this work, we investigated the starch bioremediation of paper mill wastewater (PMW) with Aspergillus oryzae. This amylase-producing fungus was tested in submerged fermentation technology (SmF) and solidstate fermentation (SSF) on rice hulls. The tests were conducted to assay the concentration of the reducing sugars on paper mill wastewater. The bioremediation of starch in the wastewater was carried out by A. oryzae, which proved capable of growing in this complex media as well as expressing its amylase activity
Going Beyond Counting First Authors in Author Co-citation Analysis
Full text linkThe present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation
counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings
are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that
only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into
account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed
Temperature and water vapour measurements in the framework of the Network for the Detection of Atmospheric Composition Change (NDACC)
Full text linkThe BASIL Raman lidar system entered the International Network for the Detection of Atmospheric Composition Change (NDACC) in 2012. Since then, measurements have been carried out routinely on a weekly basis. This paper reports specific measurement results from this effort, with a dedicated focus on temperature and water vapour profile measurements. The main objective of this research effort is to provide a characterisation of the system performance. The results illustrated in this publication demonstrate the ability of BASIL to perform measurements of the temperature profile up to 50 km and of the water vapour mixing ratio profile up to 15 km, when considering an integration time of 2 h and a vertical resolution of 150-600 m; the mean measurement accuracy, determined based on comparisons with simultaneous and co-located radiosondes, is 0.1 K (for the temperature profile) and 0.1 g kg-1 (for the water vapour mixing ratio profile) up to the upper troposphere. The relative humidity profiling capability up to the tropopause is also demonstrated by combining simultaneous temperature and water vapour profile measurements. Raman lidar measurements are compared with measurements from additional instruments, such as radiosondes and satellite sensors (IASI and AIRS), as well as with model reanalyses data (ECMWF and ECMWF-ERA). We focused our attention on six case studies collected during the first 2 years of system operation (November 2013-October 2015). Comparisons between BASIL and the different sensor/model data in terms of the water vapour mixing ratio indicate biases in the altitudinal interval between 2 and 15 km that are always within ±1 g kg-1 (or ±50 %), with minimum values being observed in the comparison between BASIL and radiosonde measurements (±20 % up to 15 km). Results also indicate a vertically averaged mean mutual bias of -0.026 g kg-1 (or -3.8 %), 0.263 g kg-1 (or 30.0 %), 0.361 g kg-1 (or 23.5 %), -0.297 g kg-1 (or -25 %) and -0.296 g kg-1 (or -29.6 %) when comparing BASIL with radiosondes, IASI, AIRS, ECMWF and ECMWF-ERA respectively. The vertically averaged mean absolute mutual biases are somewhat higher, i.e. 0.05 g kg-1(or 16.7 %), 0.39 g kg-1 (or 23.0 %), 0.57 g kg-1 (or 23.5 %), 0.32 g kg-1 (or 29.6 %) and 0.52 g kg-1 (or 53.3 %), when comparing BASIL with radiosondes, IASI, AIRS, ECMWF and ECMWF-ERA respectively. The comparisons in terms of temperature measurements indicate mutual biases in the altitudinal interval between 3 and 30 km that are always within ±3 K, with minimum values being observed in the comparison between BASIL and radiosonde measurements (±2 K within this same altitudinal interval). Results also reveal mutual biases within ±3 K up to 50 km for most sensor/model pairs. Furthermore, a vertically averaged mean mutual bias of -0.03, 0.21, 1.95, 0.14 and 0.43 K is found between BASIL and the radiosondes, IASI, AIRS, ECMWF and ECMWF-ERA respectively. The vertically averaged absolute mean mutual biases between BASIL and the radiosondes, IASI, AIRS, ECMWF and ECMWF-ERA are 1.28, 1.30, 3.50, 1.76 and 1.63 K respectively. Based on the available dataset and benefiting from the fact that the BASIL Raman lidar could be compared with all other sensor/model data, it was possible to estimate the overall bias of all sensors/datasets: -0.04 g kg-1 ĝ• 0.19 K, 0.20 g kg-1 ĝ• 0.22 K, -0.31 g kg-1 ĝ• -0.02 K, -0.40 g kg-1 ĝ• -1.76 K, 0.25 g kg-1 ĝ• 0.04 K and 0.25 g kg-1 ĝ• -0.24 K for the water vapour mixing ratio/temperature profile measurements carried out by BASIL, the radiosondes, IASI, AIRS, ECMWF and ECMWF-ERA respectively.
Bio‐delignification of green waste (Gw) in co‐digestion with the organic fraction of municipal solid waste (ofmsw) to enhance biogas production
No full textThe organic fraction of municipal solid waste (OFMSW) is recognized as a suitable sub-strate for the anaerobic digestion (AD) process and is currently considered a mature technology. A promising strategy to enhance biogas yield and productivity is the co‐digestion of OFMSW with other organic biomass, such as green waste (GW), a mixture of leaves, grass, and woody materials originated from private yards and public greenspace management. The main limitation to the use of GW for biogas production is the high percentage of the lignocellulosic fraction, which makes necessary a pretreatment of delignification to dissolve the recalcitrant structure. In this study, a new strategy of sustainable bio‐delignification using the white‐rot fungi Bjerkandera adusta (BA) in comparison with other chemical pretreatments were investigated. Untreated and treated GW were, re-spectively, submitted to anaerobic co‐digestion with OFMSW. AD processes were carried out in a lab‐scale plant for 30 days in thermophilic conditions (55 °C). Biogas cumulative production was increased by about 100% in the case of treated GW compared with that of just OFMSW, from 145 to 289 Nm3 CH4/ton SV, and productivity almost doubled from 145 to 283 Nm3/ton FM * day. The measured average methane content values in the cumulative biogas were 55% from OFMSW and 54% from GW. Moreover, over 95% of the biogas was produced in 20 days, showing the potential opportunity to reduce the AD time
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