196,167 research outputs found
Entropy generation analysisfor the design optimizationof solid oxide fuel cells
No full textPurpose - The aim of this paper is to investigate performance improvements of a monolithic solid oxide fuel cell geometry through an entropy generation analysis. Design/methodology/approach - The analysis of entropy generation rates makes it possible to identify the phenomena that cause the main irreversibilities in the fuel cell, to understand their causes and to propose changes in the design and operation of the system. The various contributions to entropy generation are analyzed separately in order to identify which geometrical parameters should be considered as the independent variables in the optimization procedure. The local entropy generation rates are obtained through 3D numerical calculations, which account for the heat, mass, momentum, species and current transport. The system is then optimized in order to minimize the overall entropy generation and increase efficiency. Findings - In the optimized geometry, the power density is increased by about 10 per cent compared to typical designs. In addition, a 20 per cent reduction in the fuel cell volume can be achieved with less than a 1 per cent reduction in the power density with respect to the optimal design. Research limitations/implications - The physical model is based on a simple composition of the reactants, which also implies that no chemical reactions (water gas shift, methane steam reforming, etc.) take place in the fuel cell. Nevertheless, the entire procedure could be applied in the case of different gas compositions. Practical implications - Entropy generation analysis allows one to identify the geometrical parameters that are expected to play important roles in the optimization process and thus to reduce the free independent variables that have to be considered. This information may also be used for design improvement purposes. Originality/value - In this paper, entropy generation analysis is used for a multi-physics problem that involves various irreversible terms, with the double use of this physical quantity: as a guide to select the most relevant design geometrical quantities to be modified and as objective function to be minimized in the optimization proces
Sensitivity analysis applied to the multi-objective optimization of a MCFC hybrid plant
No full textIn this paper, the multi-objective optimization of a molten carbonate fuel cell (MCFC) based hybrid plant fueled with landfill gas is performed. System operation is significantly affected by off-design conditions. These are due to variations methane concentration occurring as the landfill depletes, performance degradations of the components, particularly the fuel cell, and ambient conditions. For these reasons, the objective functions are defined considering the plant lifetime. Some of the parameters affecting the results, as the voltage degradation, the cost of fuel cell, the methane concentration and the unit cost of landfill gas can be only estimated or forecasted and their actual values are uncertain. Therefore, the optimization is performed considering a sensitivity analysis in order to estimate the effects of possible variations on the Pareto front. The following free design variables are considered: pressure and temperature operation of the MCFC, turbine inlet temperature, fuel mass flow rate. In addition, the optimal configuration of the heat exchanger network is selected for each set of the design variabl
Numerical Analysis of a medium scale latent energy storage unit for district heating systems
No full textThe present paper describes the application of computational fluid-dynamics (CFD) to the design and characterization of a medium scale energy storage unit for district heating systems. The shell-and-tube LHTES unit contains a technical grade paraffin (RT100) as phase change material (PCM) and uses water as heat transfer fluid (HTF). The system has been designed to transfer heat from the district to the building heating networks. After an initial description of the LHTES unit and a wide literature overview on the subject, the paper discusses the need for thermal enhancement to improve the thermal conductivity of the PCM. A solution based on a paraffin-graphite composite with a 15% graphite volume fraction has been found to be well performing in this particular application. Several operating scenarios characterized by heat requests ranging between 130 kWand 400 kWhave been explored and the main outputs presented as function of Re and St numbers. The timewise variations of other significant quantities such as liquid fraction, sensible and latent energy content, HFT outlet temperature and heat fluxes have been also presented and discussed. A final discussion on the possible system configurations shows that in comparison to traditional water storage systems for district heating, LHTES systems provide, depending on the chose alternative, higher energy storage densitie
Design improvement of circular molten carbonate fuel cell stack through CFD Analysis
No full textMolten carbonate fuel cell (MCFC) is a promising technology for distributed power generation. The core of an MCFC power generation unit is the stack, where various fuel cells are connected together in series and parallel in order to obtain the desired voltage and power. Stack geometry and configuration are major engineering topics, as inhomogeneous temperature or mass fractions cause inefficient performances of the fuel cells, as efficiency and power smaller than the expected and shorter lifetime. A detailed model is a useful tool to improve stack performances, through design improvements. In this paper, a 3D model of a stack composed of 15 circular MCFC, considering heat, mass and current transfer as well as chemical and electrochemical reactions is presented. The model validation is conducted using some preliminary experimental data obtained for an MCFC stack developed in the Fabbricazioni Nucleari laboratories. These results are examined in order to improve the stack configuration. It is shown that power density may be increased of about 20% through double side feeding. In addition, the average temperature gradients in the axial direction are reduced of more than 70%. Significant reductions in the temperature gradients, especially in transversal direction, can be achieved by adjusting the mass flow rate of cathodic gas supplied to the various cell
Leave 2nd generation behind: cost effective solutions for small-to-large scale DH networks
No full textDue “M” al Nord: Montanelli e Malaparte in Finlandia
No full textIndro Montanelli (1909–2001) and Curzio Malaparte (1898–1957) were in Finland during World War II, the former as a witness (and envoy) of the “winter war” fought against the Soviet Union by Finland (which had won independence from Russia in 1917), the latter in the years of the “war of continuation”, when hostilities between the two countries continued in the more complex picture of the second phase of the conflict, that is, after Germany had attacked the Soviet Union. Most of their correspondence and annotations, collected in volume, immediately became, for many readers, the representation of an unequal clash between the small but well-prepared army of Finland (David) and the populous ranks of the Red Army (Goliath). In this article, Antonio Sciacovelli highlights, on the basis of his analysis of their writings, how their images of the Finns, the environment and the particular situation of those years were conveyed to Italian readers, in the
“story” of the war events
Melting of PCM in a thermal energy storage unit: Numerical investigation and effect of nanoparticle enhancement
No full textThe present paper describes the analysis of the melting process in a single vertical shell-and-tube latent heat thermal energy storage (LHTES), unit and it is directed at understanding the thermal performance of the system. The study is realized using a computational fluid-dynamic (CFD) model that takes into account of the phase-change phenomenon by means of the enthalpy method. Fluid flow is fully resolved in the liquid phase-change material (PCM) in order to elucidate the role of natural convection. The unsteady evolution of the melting front and the velocity and temperature fields is detailed. Temperature profiles are analyzed and compared with experimental data available in the literature. Other relevant quantities are also monitored, including energy stored and heat flux exchanged between PCM and HTF. The results demonstrate that natural convection within PCM and inlet HTF temperature significantly affects the phase-change process. Thermal enhancement through the dispersion of highly conductive nanoparticles in the base PCM is considered in the second part of the paper. Thermal behavior of the LHTES unit charged with nano-enhanced PCM is numerically analyzed and compared with the original system configuration. Due to increase of thermal conductivity, augmented thermal performance is observed: melting time is reduced of 15% when nano-enhanced PCM with particle volume fraction of 4% is adopted. Similar improvements of the heat transfer rate are also detecte
Gli obblighi degli Stati parti della Dichiarazione sulla eliminazione della violenza contro le donne e l’effettività degli strumenti repressivi previsti nel diritto internazionale
No full textHarmonization of units and reference intervals of plasma proteins: State of the art from an External Quality Assessment Scheme
No full textThe need to harmonize laboratory information is particularly intense in the field of plasma proteins, considering their clinical impact and relevance in monitoring diseases. We evaluated units and reference intervals (RIs) utilized by participants of the External Quality Assessment Scheme (EQAS) for plasma proteins of the Centre of Biomedical Research. Moreover, we evaluated inter-laboratory analytical variability from 2001 to 2017. The census of participants' units employed in 2017 showed that for albumin (ALB), ~66% of laboratories still used dL instead of L, and for most other proteins, ~70% still expressed the results in mg/dL. Laboratories primarily used the RIs reported in the packaging inserts of their analytical systems, but for each protein, there was a wide variability of RIs, also among laboratories using the same analytical method. Mean CVs% of the 13 certified proteins in the last five EQA cycles ranged from 3.8% of haptoglobin (HPT) to 12.4% of α1-antitrypsin (AAT) and decreased from 2001 to 2017 for most of them, in particular for C3, ALB, α2-macroglobulin (A2M), HPT and transferrin (TRF). In the face of a reduction in inter-laboratory variability for a lot of proteins, there has not been a substantial change in the units and in the RIs used by the participants. To change old habits is difficult and requires coordination and collaboration. The EQAS plays an important role in the assessment and monitoring of all elements that contribute to the formulation of laboratory information and may be useful to contribute to their harmonization
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