1,721,026 research outputs found
Determination and evaluation by HPLC and mass spectrometry of isothiazolinone derivatives as antimicrobial agents in cosmetics
No full textSurface chemistry study of RuO2/IrO2/TiO2 mixed-oxide electrodes
No full textDSA metal oxide electrodes such as the RuO2/IrO2/TiO2 mixed system are widely studied for their excellent electrocatalytic activity. In order to understand their catalytic properties, the comprehension of the surface chemistry involved during electrochemical treatments is crucial. With this aim,
RuO2/IrO2/TiO2 mixed-oxide electrodes having various noble metal contents were studied by means of secondary ion mass spectrometry (SIMS). In particular, cathodic and anodic polarization and O2 evolution reactions were carried out to test the electrode behaviour and SIMS analyses were performed after all these treatments. In this way, surface changes induced by electrochemical treatments and depending on electrode composition were widely investigated by SIMS, revealing, for
example, the presence of hydration or preferential dissolution phenomena induced by electrochemical processing
Examination of RuO2 single-crystal surfaces: charge storage mechanism in H2SO4 aqueous solution
No full textSystematic voltammetric and impedance studies of RuO2 ‘as-grown’ single crystals were carried out using the (101), (110) and
(002) faces in 0.5 mol dm-3 sulphuric acid solution and applying the hanging electrolyte meniscus technique. The crystal surfaces,
prepared by the vapor transfer technique at high temperature, show well-defined XRD patterns. The dependence of the
voltammetric characteristics on potential scan rate modulations was investigated. The charge storage mechanism was examined in
the following cases for differences: (i) in the anodic surface charge qa* and the atomic distribution of ideal surfaces, (ii) between the total anodic charge qa*tot and the anodic charge associated with the electrochemical process qa** due to the redox couple in the solid state. A systematically higher charge for the (101) face in the same potential range represents a probe for the crystal face specificity of the redox process
Going Beyond Counting First Authors in Author Co-citation Analysis
Full text linkThe present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation
counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings
are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that
only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into
account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed
Adsorption of n-pentanol from KPF6 aqueous solution on the (100) and (110) faces of Ag single crystal electrodes
No full textThe potential dependence of the adsorption of n-pentanol (NP) on the (100) and (110) faces of Ag single crystal electrodes from
aqueous KPF6 solutions has been studied at 10 mV/s potential scan rate by measuring the impedance both at constant
frequency ( f ) and by sweeping f from 11 kHz to 0.1 Hz. The adsorption of NP has been found to be strongly dependent on
crystal orientation. The results have been compared with those obtained on Ag(111) with the same kind of single crystal
preparation, as well as with Ag(100) electrolytically grown in a Teflon capillary [A. Popov, O. Velev, T. Vitanov, J. Electroanal.
Chem. 256 (1988) 405]
Variations on the Author
Full text link“Variations on the Author” discusses two of Eduardo Coutinho’s recent films (Um Dia na Vida, from 2010, and Últimas Conversas, posthumously released in 2015) and their contribution to the general question of documentary authorship. The director’s filmography is characterized by a consistent yet self-effacing form of authorial self-inscription: Coutinho often features as an interviewer that rather than express opinions propels discourses; an interviewer that is good at listening. This mode of self-inscription characterizes him as an author who is not expressive but who is nonetheless markedly present on the screen. In Um Dia na Vida, however, Coutinho is completely absent form the image, while Últimas Conversas, on the contrary, includes a confessional prologue that moves the director from the margins to the center of his films. This article examines the ways in which these works stand out in the filmography of a director who offers new insights into the notion of cinematic authorship
Appropriate Similarity Measures for Author Cocitation Analysis
Full text linkWe provide a number of new insights into the methodological discussion about author cocitation analysis. We first argue that the use of the Pearson correlation for measuring the similarity between authors’ cocitation profiles is not very satisfactory. We then discuss what kind of similarity measures may be used as an alternative to the Pearson correlation. We consider three similarity measures in particular. One is the well-known cosine. The other two similarity measures have not been used before in the bibliometric literature. Finally, we show by means of an example that our findings have a high practical relevance.information science;Pearson correlation;cosine;similarity measure;author cocitation analysis
Dispelling the Myths Behind First-author Citation Counts
Full text linkWe conducted a full-scale evaluative citation analysis study of scholars in the XML research field to explore just how different from each other author rankings resulting from different citation counting methods actually are, and to demonstrate the capability of emerging data and tools on the Web in supporting more realistic citation counting methods. Our results contest some common arguments for the continued
use of first-author citation counts in the evaluation of scholars, such as high correlations between author rankings by first-author citation counts and other citation
counting methods, and high costs of using more realistic citation counting methods that are not well-supported by the ISI databases. It is argued that increasingly available digital full text research papers make it possible for citation analysis studies to go beyond what the ISI databases have directly supported and to employ more
sophisticated methods
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