1,193 research outputs found
Ryan (Birth, 1899-04-04)
No full textAddress: Elm St.1590/Pg.36/1899/M W/Cinti, Ohio/Cinti, Ohio/Dr. E.P. JosephOriginal record filed in drawer labeled 'Runk-Ryan'
Letter from Archbishop E.P. Roche to Hagan
No full textTypescript letter signed Archbishop E.P. Roche of Newfoundland, The Palace, St. John's (Canada), to Hagan, introducing the new student from the archdiocese, Mr. William Ryan
boreale
No full textHypericum boreale (Britton) E.P. Bicknellnorthern St. John's-wortmillepertuis boréalnear junction of Spring Street and Ryan Road, Florence (Northampton)pond margi
Robustness in the graph topology of a common adaptive controller
No full textFor any m-input, m-output, finite-dimensional, linear, minimum-phase plant P with first Markov parameter having spectrum in the open right-half complex plane, it is well known that the adaptive output feedback control C, given by u = -ky, k = ||y||2, yields a closed-loop system [P,C] for which the state converges to zero, the signal k converges to a finite limit, and all other signals are of class L2. It is first shown that these properties continue to hold in the presence of L2-input and L2-output disturbances. By establishing gain function stability of an appropriate closed-loop operator, it is proved that these properties also persist when the plant P is replaced by a stabilizable and detectable linear plant P1 within a sufficiently small neighbourhood of P in the graph topology, provided that the plant initial data and the L2 magnitude of the disturbances are sufficiently small. Example 9 of Georgiou & Smith (IEEE Trans. Autom. Control 42(9) 1200-1221, 1997) is revisited to which the above L2-robustness result applies. Unstable behaviour for large initial conditions and/or large L2 disturbances is shown, demonstrating that the bounds obtained from the L2 theory are qualitatively tight: this contrasts with the L∞-robustness analysis of Georgiou & Smith which is insufficiently tight to predict the stable behaviour for small initial conditions and zero disturbances
Approaching the diamond surface: first principles modelling the physics and chemistry of approaching radicals
No full textThe diamond surface plays a central role in much of the diamond research, and as such much of its properties are described and studied in great detail. There is a clear picture of the atomic scale structure of the different facets and their reconstructions. Also terminations with H, O, N and other atomic species as well as the incorporation of these elements has been modelled [1,2]. The electronic structure and the negative electron affinity mechanism is elucidated and so on. In contrast, however, the atomic scale models of diamond growth are much less developed, though progress is being made [3]. In these models the reaction barriers between stable and meta-stable intermediates are being calculated, providing insights into the kinetics of the surface. However, quantum mechanical models can provide much more insights than this. In this work, we simulated the approach of radical atoms and molecules towards the H-terminated diamond 001 surface. By allowing the model to equilibrate at every step, the physics and chemistry of the approach can be followed in minute detail. It allows us to indicate at which distance the surface and radical start interacting, and what that interaction entails. The charge evolution of the radical and the surface is followed by means of Hirshfeld-I charges, providing insights into charge transfer mechanisms. [4] Throughout the approach, the interaction can be followed through different physical and chemical concepts. Different types of bonding are identified as well as H-abstraction events and covalent bonding. In this work, our focus goes to C and P based radicals, showing them to behave very differently near the surface, providing insights into the requirements for improved P incorporation.The author name needs to be updated to include the middle names: Danny E.P. Vanpoucke, and linked to the correct personel account which incorrectly is missing the author middle names
Approaching the diamond surface: first principles modelling the physics and chemistry of approaching radicals
No full textThe diamond surface plays a central role in much of the diamond research, and as such much of its properties are described and studied in great detail. There is a clear picture of the atomic scale structure of the different facets and their reconstructions. Also terminations with H, O, N and other atomic species as well as the incorporation of these elements has been modelled [1,2]. The electronic structure and the negative electron affinity mechanism is elucidated and so on. In contrast, however, the atomic scale models of diamond growth are much less developed, though progress is being made [3]. In these models the reaction barriers between stable and meta-stable intermediates are being calculated, providing insights into the kinetics of the surface. However, quantum mechanical models can provide much more insights than this. In this work, we simulated the approach of radical atoms and molecules towards the H-terminated diamond 001 surface. By allowing the model to equilibrate at every step, the physics and chemistry of the approach can be followed in minute detail. It allows us to indicate at which distance the surface and radical start interacting, and what that interaction entails. The charge evolution of the radical and the surface is followed by means of Hirshfeld-I charges, providing insights into charge transfer mechanisms. [4] Throughout the approach, the interaction can be followed through different physical and chemical concepts. Different types of bonding are identified as well as H-abstraction events and covalent bonding. In this work, our focus goes to C and P based radicals, showing them to behave very differently near the surface, providing insights into the requirements for improved P incorporation.The author name needs to be updated to include the middle names: Danny E.P. Vanpoucke, and linked to the correct personel account which incorrectly is missing the author middle names
DFT-based Vibrational Spectra for THz-Spectroscopy and Defect Fingerprinting in Molecular Crystals and Solids.
No full textSpectroscopic techniques based on atomic vibrations provide a powerful tool for the
atomic scale characterization of solids. Unfortunately, the translation of their spectra into
atomistic structures tends to be an inverse-problem, as a structural model is required to
assign the observed spectral peaks. This is further complicated by the fact that the exact
position of the latter is sensitive to the precise underlying atomic structure. This results
in the need for very accurate models.
With the steady growth of computational resources, the calculation of vibrational spectra
for extended and periodic systems has become more attainable at the level of quantum
mechanical calculations. In this work, we first present the example of the THz vibrational
spectrum of lactose-monohydrate (LM), and use our results to identify the spectral lines
of the observed spectra of different phases, obtained experimentally by heating the LM
sample.1 The accompanying water loss induces two phase transitions. According to our
results, all phases, including the starting high purity commercial sample, are mixtures of
different phases. We discuss the impact of both structural—such as water content and
orientation— and methodological—such as Pulay stresses, periodic boundaries, and
supercell sizes—aspects on the calculated spectra, and show that DFT-based spectra
under periodic boundaries can be matched with experimental data.
The importance of an extended periodic system for obtaining an accurate vibrational
spectrum is also shown in studying defects in diamond. However, here, we show that the
qualitative picture of the defect character of each atom in the system is independent of
the system size, allowing for small periodic cells to determine the relevant defect atoms
at much reduced computational cost.2 Defects tend to be very localized, resulting in
atomic modes.3 Therefore, an often-used strategy for selecting the contributing atoms
considers only their relative position with regard to the defect center. Using the atomprojected
vibrational spectrum, we present a quantitative method for determining the
defect character of each atom in the system, allowing for a rational incremental
improvement of the defect spectrum. This method is then applied on several simple
defects in diamond.Author : Danny E.P. Vanpoucke
Author name needs to be updated to include middle names, and correctly linked to the uhasselt personel databas
DFT-based Vibrational Spectra for THz-Spectroscopy and Defect Fingerprinting in Molecular Crystals and Solids.
No full textSpectroscopic techniques based on atomic vibrations provide a powerful tool for the
atomic scale characterization of solids. Unfortunately, the translation of their spectra into
atomistic structures tends to be an inverse-problem, as a structural model is required to
assign the observed spectral peaks. This is further complicated by the fact that the exact
position of the latter is sensitive to the precise underlying atomic structure. This results
in the need for very accurate models.
With the steady growth of computational resources, the calculation of vibrational spectra
for extended and periodic systems has become more attainable at the level of quantum
mechanical calculations. In this work, we first present the example of the THz vibrational
spectrum of lactose-monohydrate (LM), and use our results to identify the spectral lines
of the observed spectra of different phases, obtained experimentally by heating the LM
sample.1 The accompanying water loss induces two phase transitions. According to our
results, all phases, including the starting high purity commercial sample, are mixtures of
different phases. We discuss the impact of both structural—such as water content and
orientation— and methodological—such as Pulay stresses, periodic boundaries, and
supercell sizes—aspects on the calculated spectra, and show that DFT-based spectra
under periodic boundaries can be matched with experimental data.
The importance of an extended periodic system for obtaining an accurate vibrational
spectrum is also shown in studying defects in diamond. However, here, we show that the
qualitative picture of the defect character of each atom in the system is independent of
the system size, allowing for small periodic cells to determine the relevant defect atoms
at much reduced computational cost.2 Defects tend to be very localized, resulting in
atomic modes.3 Therefore, an often-used strategy for selecting the contributing atoms
considers only their relative position with regard to the defect center. Using the atomprojected
vibrational spectrum, we present a quantitative method for determining the
defect character of each atom in the system, allowing for a rational incremental
improvement of the defect spectrum. This method is then applied on several simple
defects in diamond.Author : Danny E.P. Vanpoucke
Author name needs to be updated to include middle names, and correctly linked to the uhasselt personel databas
April 15, 1905 Page one Ludlow's big mill ready to operate Orel did not have wounded aboard
No full textThompson, Albert E.; Iles, L.L.; Swan, R.A.; Schram, John; Clise, H.L.; Ryan, John E.; Whiting, E.P.; Drew, Ed; Halverson, Albert
Buddhism in Theosophical Interpretation of E.P. Blavatskaya: «Philosophic Invention» Problem
No full textThe subject matter of the paper is a most interesting philosophic phenomenon- theosophy which received a considerable emphasis at the end of the nineteenth and the beginning of the twentieth century and greatly influenced viewpoints of the majority of philosophers, writers, musicians and artists. The key point of the article is the author's approach to the problem of close connection between E.P. Blavatskaya's theory and Buddhism. Diverse viewpoints of both famous Russian religious philosophers and buddhologists of that time as well as modern Russian esoteric investigators and scientific papers of E.P. Blavatskaya have been studied.
The famous Russian neo-Kantian philosopher I.I. Lapshin study «Philosophy of Inventing and Invention in Philosophy: Introduction to the History of Philosophy» being inside the scope of her basic investigations, the author comes to the conclusion that theosophy is the original form of «philosophic invention» based on the specific usage of various philosophic and religious ideas of Neo-Platonism, Christian mysticism, cabbalistic theories' symbols as well as Buddhism from the point of view of their esoteric content
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