24 research outputs found
Comparison of the hemodynamics and dynamics of fluid shift of Ringer's solution before surgery in children and adults
No full textSynthesis and Characterization of Stable Ruthenabenzenes Starting from HC⋮CCH(OH)C⋮CH
No full textTreatment of RuCl2(PPh3)3 with HC⋮CCH(OH)C⋮CH/PPh3 at room temperature produces the air-stable ruthenabenzene [Ru(CHC(PPh3)CHC(PPh3)CH)Cl2(PPh3)2]Cl (2) in good yield. The ruthenabenzene
2 can even be obtained from the one-pot reaction of RuCl3, PPh3, and HC⋮CCH(OH)C⋮CH in the
mixed solvent of ionic liquid and CH2Cl2 in higher yield. The ruthenabenzene 2 reacts with PMe3, PBu3,
tert-butyl isocyanide, 2,2‘-dipyridyl (bipy), and 2,2‘-dipyridyl/PMe3 to give new stable ruthenabenzenes
[Ru(CHC(PPh3)CHC(PPh3)CH)Cl2(PMe3)2]Cl (4), [Ru(CHC(PPh3)CHC(PPh3)CH)Cl2(PBu3)2]Cl (5), [Ru(CHC(PPh3)CHC(PPh3)CH)Cl(tBuNC)(PPh3)2]Cl2 (6), [Ru(CHC(PPh3)CHC(PPh3)CH)Cl(bipy)(PPh3)]Cl2
(7), and [Ru(CHC(PPh3)CHC(PPh3)CH)(bipy)(PMe3)2]Cl3 (8), respectively. Reaction of ruthenabenzene
2 with AgBF4 gives bisruthenabenzene [Ru(CHC(PPh3)CHC(PPh3)CH)(PPh3)]2(μ-Cl)3(BF4)3 (9). The
thermal decomposition reactions of ruthenabenzene 2 and 7 produce a stable Cp- ion derivative, [CHC(PPh3)CHC(PPh3)CH]Cl (10). 2, 4, 7, 8, 9, and 10 have been structurally characterized. 9 is the first
non-metal-coordinated bismetallabenzene. An electrochemical study shows that the metal centers in the
bisruthenabenzene 9 slightly interact with each other through the chloro bridges
Synthesis and Characterization of Stable Ruthenabenzenes Starting from HC⋮CCH(OH)C⋮CH
No full textTreatment of RuCl2(PPh3)3 with HC⋮CCH(OH)C⋮CH/PPh3 at room temperature produces the air-stable ruthenabenzene [Ru(CHC(PPh3)CHC(PPh3)CH)Cl2(PPh3)2]Cl (2) in good yield. The ruthenabenzene
2 can even be obtained from the one-pot reaction of RuCl3, PPh3, and HC⋮CCH(OH)C⋮CH in the
mixed solvent of ionic liquid and CH2Cl2 in higher yield. The ruthenabenzene 2 reacts with PMe3, PBu3,
tert-butyl isocyanide, 2,2‘-dipyridyl (bipy), and 2,2‘-dipyridyl/PMe3 to give new stable ruthenabenzenes
[Ru(CHC(PPh3)CHC(PPh3)CH)Cl2(PMe3)2]Cl (4), [Ru(CHC(PPh3)CHC(PPh3)CH)Cl2(PBu3)2]Cl (5), [Ru(CHC(PPh3)CHC(PPh3)CH)Cl(tBuNC)(PPh3)2]Cl2 (6), [Ru(CHC(PPh3)CHC(PPh3)CH)Cl(bipy)(PPh3)]Cl2
(7), and [Ru(CHC(PPh3)CHC(PPh3)CH)(bipy)(PMe3)2]Cl3 (8), respectively. Reaction of ruthenabenzene
2 with AgBF4 gives bisruthenabenzene [Ru(CHC(PPh3)CHC(PPh3)CH)(PPh3)]2(μ-Cl)3(BF4)3 (9). The
thermal decomposition reactions of ruthenabenzene 2 and 7 produce a stable Cp- ion derivative, [CHC(PPh3)CHC(PPh3)CH]Cl (10). 2, 4, 7, 8, 9, and 10 have been structurally characterized. 9 is the first
non-metal-coordinated bismetallabenzene. An electrochemical study shows that the metal centers in the
bisruthenabenzene 9 slightly interact with each other through the chloro bridges
Synthesis and Characterization of Stable Ruthenabenzenes Starting from HC⋮CCH(OH)C⋮CH
No full textTreatment of RuCl2(PPh3)3 with HC⋮CCH(OH)C⋮CH/PPh3 at room temperature produces the air-stable ruthenabenzene [Ru(CHC(PPh3)CHC(PPh3)CH)Cl2(PPh3)2]Cl (2) in good yield. The ruthenabenzene
2 can even be obtained from the one-pot reaction of RuCl3, PPh3, and HC⋮CCH(OH)C⋮CH in the
mixed solvent of ionic liquid and CH2Cl2 in higher yield. The ruthenabenzene 2 reacts with PMe3, PBu3,
tert-butyl isocyanide, 2,2‘-dipyridyl (bipy), and 2,2‘-dipyridyl/PMe3 to give new stable ruthenabenzenes
[Ru(CHC(PPh3)CHC(PPh3)CH)Cl2(PMe3)2]Cl (4), [Ru(CHC(PPh3)CHC(PPh3)CH)Cl2(PBu3)2]Cl (5), [Ru(CHC(PPh3)CHC(PPh3)CH)Cl(tBuNC)(PPh3)2]Cl2 (6), [Ru(CHC(PPh3)CHC(PPh3)CH)Cl(bipy)(PPh3)]Cl2
(7), and [Ru(CHC(PPh3)CHC(PPh3)CH)(bipy)(PMe3)2]Cl3 (8), respectively. Reaction of ruthenabenzene
2 with AgBF4 gives bisruthenabenzene [Ru(CHC(PPh3)CHC(PPh3)CH)(PPh3)]2(μ-Cl)3(BF4)3 (9). The
thermal decomposition reactions of ruthenabenzene 2 and 7 produce a stable Cp- ion derivative, [CHC(PPh3)CHC(PPh3)CH]Cl (10). 2, 4, 7, 8, 9, and 10 have been structurally characterized. 9 is the first
non-metal-coordinated bismetallabenzene. An electrochemical study shows that the metal centers in the
bisruthenabenzene 9 slightly interact with each other through the chloro bridges
Synthesis and Characterization of Stable Ruthenabenzenes Starting from HC⋮CCH(OH)C⋮CH
No full textTreatment of RuCl2(PPh3)3 with HC⋮CCH(OH)C⋮CH/PPh3 at room temperature produces the air-stable ruthenabenzene [Ru(CHC(PPh3)CHC(PPh3)CH)Cl2(PPh3)2]Cl (2) in good yield. The ruthenabenzene
2 can even be obtained from the one-pot reaction of RuCl3, PPh3, and HC⋮CCH(OH)C⋮CH in the
mixed solvent of ionic liquid and CH2Cl2 in higher yield. The ruthenabenzene 2 reacts with PMe3, PBu3,
tert-butyl isocyanide, 2,2‘-dipyridyl (bipy), and 2,2‘-dipyridyl/PMe3 to give new stable ruthenabenzenes
[Ru(CHC(PPh3)CHC(PPh3)CH)Cl2(PMe3)2]Cl (4), [Ru(CHC(PPh3)CHC(PPh3)CH)Cl2(PBu3)2]Cl (5), [Ru(CHC(PPh3)CHC(PPh3)CH)Cl(tBuNC)(PPh3)2]Cl2 (6), [Ru(CHC(PPh3)CHC(PPh3)CH)Cl(bipy)(PPh3)]Cl2
(7), and [Ru(CHC(PPh3)CHC(PPh3)CH)(bipy)(PMe3)2]Cl3 (8), respectively. Reaction of ruthenabenzene
2 with AgBF4 gives bisruthenabenzene [Ru(CHC(PPh3)CHC(PPh3)CH)(PPh3)]2(μ-Cl)3(BF4)3 (9). The
thermal decomposition reactions of ruthenabenzene 2 and 7 produce a stable Cp- ion derivative, [CHC(PPh3)CHC(PPh3)CH]Cl (10). 2, 4, 7, 8, 9, and 10 have been structurally characterized. 9 is the first
non-metal-coordinated bismetallabenzene. An electrochemical study shows that the metal centers in the
bisruthenabenzene 9 slightly interact with each other through the chloro bridges
Synthesis and characterization of stable ruthenabenzenes starting from HCCCH(OH)CCH
No full textTreatment of RuCl2(PPh3)(3) with HCCCH(OH)CCH/PPh3 at room temperature produces the air-stable ruthenabenzene [Ru(CHC(PPh3)CHC(PPh3)CH)Cl-2(PPh3)(2)]Cl (2) in good yield. The ruthenabenzene 2 can even be obtained from the one-pot reaction of RuCl3, PPh3, and HCCCH(OH)CCH in the mixed solvent of ionic liquid and CH2Cl2 in higher yield. The ruthenabenzene 2 reacts with PMe3, PBu3, tert-butyl isocyanide, 2,2'-dipyridyl (bipy), and 2,2'-dipyridyl/PMe3 to give new stable ruthenabenzenes [Ru(CHC(PPh3)CHC(PPh3)CH)Cl-2(PMe3)(2)]Cl (4), [Ru(CHC(PPh3)CHC(PPh3)CH)Cl-2(PBu3)(2)]Cl (5), [Ru(CHC(PPh3)CHC(PPh3)CH)Cl((BuNC)-Bu-t)(PPh3)(2)]Cl-2 (6), [Ru(CHC(PPh3)CHC(PPh3)CH)Cl(bipy)(PPh3)]Cl-2 (7), and [Ru(CHC(PPh3)CHC(PPh3)CH)(bipy)(PMe3)(2)]Cl-3 (8), respectively. Reaction of ruthenabenzene 2 with AgBF4 gives bisruthenabenzene [Ru(CHC(PPh3)CHC(PPh3)CH)(PPh3)](2)(mu-Cl)(3)(BF4)(3) (9). The thermal decomposition reactions of ruthenabenzene 2 and 7 produce a stable Cp- ion derivative, [CHC(PPh3)CHC(PPh3)CH]Cl (10). 2, 4, 7, 8, 9, and 10 have been structurally characterized. 9 is the first non-metal-coordinated bismetallabenzene. An electrochemical study shows that the metal centers in the bisruthenabenzene 9 slightly interact with each other through the chloro bridges
Synthesis and Characterization of Stable Ruthenabenzenes Starting from HC⋮CCH(OH)C⋮CH
No full textTreatment of RuCl2(PPh3)3 with HC⋮CCH(OH)C⋮CH/PPh3 at room temperature produces the air-stable ruthenabenzene [Ru(CHC(PPh3)CHC(PPh3)CH)Cl2(PPh3)2]Cl (2) in good yield. The ruthenabenzene
2 can even be obtained from the one-pot reaction of RuCl3, PPh3, and HC⋮CCH(OH)C⋮CH in the
mixed solvent of ionic liquid and CH2Cl2 in higher yield. The ruthenabenzene 2 reacts with PMe3, PBu3,
tert-butyl isocyanide, 2,2‘-dipyridyl (bipy), and 2,2‘-dipyridyl/PMe3 to give new stable ruthenabenzenes
[Ru(CHC(PPh3)CHC(PPh3)CH)Cl2(PMe3)2]Cl (4), [Ru(CHC(PPh3)CHC(PPh3)CH)Cl2(PBu3)2]Cl (5), [Ru(CHC(PPh3)CHC(PPh3)CH)Cl(tBuNC)(PPh3)2]Cl2 (6), [Ru(CHC(PPh3)CHC(PPh3)CH)Cl(bipy)(PPh3)]Cl2
(7), and [Ru(CHC(PPh3)CHC(PPh3)CH)(bipy)(PMe3)2]Cl3 (8), respectively. Reaction of ruthenabenzene
2 with AgBF4 gives bisruthenabenzene [Ru(CHC(PPh3)CHC(PPh3)CH)(PPh3)]2(μ-Cl)3(BF4)3 (9). The
thermal decomposition reactions of ruthenabenzene 2 and 7 produce a stable Cp- ion derivative, [CHC(PPh3)CHC(PPh3)CH]Cl (10). 2, 4, 7, 8, 9, and 10 have been structurally characterized. 9 is the first
non-metal-coordinated bismetallabenzene. An electrochemical study shows that the metal centers in the
bisruthenabenzene 9 slightly interact with each other through the chloro bridges
Synthesis and Characterization of Stable Ruthenabenzenes Starting from HC⋮CCH(OH)C⋮CH
No full textTreatment of RuCl2(PPh3)3 with HC⋮CCH(OH)C⋮CH/PPh3 at room temperature produces the air-stable ruthenabenzene [Ru(CHC(PPh3)CHC(PPh3)CH)Cl2(PPh3)2]Cl (2) in good yield. The ruthenabenzene
2 can even be obtained from the one-pot reaction of RuCl3, PPh3, and HC⋮CCH(OH)C⋮CH in the
mixed solvent of ionic liquid and CH2Cl2 in higher yield. The ruthenabenzene 2 reacts with PMe3, PBu3,
tert-butyl isocyanide, 2,2‘-dipyridyl (bipy), and 2,2‘-dipyridyl/PMe3 to give new stable ruthenabenzenes
[Ru(CHC(PPh3)CHC(PPh3)CH)Cl2(PMe3)2]Cl (4), [Ru(CHC(PPh3)CHC(PPh3)CH)Cl2(PBu3)2]Cl (5), [Ru(CHC(PPh3)CHC(PPh3)CH)Cl(tBuNC)(PPh3)2]Cl2 (6), [Ru(CHC(PPh3)CHC(PPh3)CH)Cl(bipy)(PPh3)]Cl2
(7), and [Ru(CHC(PPh3)CHC(PPh3)CH)(bipy)(PMe3)2]Cl3 (8), respectively. Reaction of ruthenabenzene
2 with AgBF4 gives bisruthenabenzene [Ru(CHC(PPh3)CHC(PPh3)CH)(PPh3)]2(μ-Cl)3(BF4)3 (9). The
thermal decomposition reactions of ruthenabenzene 2 and 7 produce a stable Cp- ion derivative, [CHC(PPh3)CHC(PPh3)CH]Cl (10). 2, 4, 7, 8, 9, and 10 have been structurally characterized. 9 is the first
non-metal-coordinated bismetallabenzene. An electrochemical study shows that the metal centers in the
bisruthenabenzene 9 slightly interact with each other through the chloro bridges
Schematic drawing of the time-line in the study.
No full textSchematic drawing of the time-line in the study.</p
The curve-fitting procedure.
No full textA: The measured plasma dilution over time in all sheep, regardless of vasoactive drug. B: The plasma dilution predicted from the base model (four parameters only) without consideration of covariates (drug effects), and C: The plasma dilution predicted from the final model with covariate effects.</p
