1,721,001 research outputs found
From aminosilanoles to homo- and heterocyclic SiOSiN-rings and cages
No full textAlkaline derivates of aminosilanoles are isolated as rings, cubanes and prisms. They react stepwisely with element halides to give four-, six-, and eight-membered ring molecules. The smallest two silicon atoms containing four-membered rings were forested in these reactions. Reactions and structures are discussed.Deutsche Forschungsgemeinschaft; Fonds der Chemischen Industri
SiF-NH-functional cyclodisilazane - Synthesis and reactivity
No full textDichlorosilanes with bulky substituents R(Me3C)SiCl2 react with liquid ammonia to give geminal silyldiamines [R(Me3C)Si(NH2)(2), 1: R = CH2Me, 2: R = CHMe2]. In the reaction of the monolithium derivatives of these compounds with halosilanes 1-amino-1.3-disilazanes are obtained [(NH2)(Me3C)RSi-NH-SiR1R2R3; 3: R = CMe3, R-1 = R-2 = R-3 = Me; 4: R = R-1 = CMe3, R-2 = R-3 = Me; 5: R-1 = R-2 = R-3 = CMe3, R-3 = H; 6: R = R-1 CMe3, R-2 = Me, R-3 = F; 7: R = CHMe2, R-1 = R-2 = R-3 = Me]. If monolithiated diamines are treated with trifluorosilanes cyclisation occurs to give (NH-Si(CMe3)(2)-NH-SiFR)cyclodisilazanes [R = N(SiMe3)(CMe3) (8); R = N(SiMe2CMe3)(2) (9)]. 50% of the educts are recovered. The spirocyclic compound 10 is isolated from the reaction of the dilithiated 1-amino-1.3-disilazane 3 with F3SiN(SiMe2CMe3)(2). NH-SiF-Functional cyclodisilazanes can be obtained in the reaction of the dilithium derivative of compound 4 with trifluorosilanes [(N(SiMe CMe3)-Si(CMe3)(2)-NH-SiFR), R = Ph (11); R = CMe3 (12)]. The lithium derivative of 12 crystallises with TMEDA as adduct 13. In the reaction of the lithiated compound 12 with Me3SiCl, LiCl elimination and substitution of the N-atom is observed (14). The treatment of 13 with PhCHO leads to a 1.3-diaza-5-oxa-2.4-disila-cyclohexane (15 a, b). Starting from lithiated 12 the methoxy-substituted cyclodisiloxane 16 is accessible in the reaction with MeOH. As result of its reactivity towards Me2SiF2 the fluorosilyl-substituted cyclodisilazane 17 is obtained. Crystal structures of 9-11 and 13 have been determined
SiF-NH-functional cyclodisilazane - Synthesis and reactivity
No full textDichlorosilanes with bulky substituents R(Me3C)SiCl2 react with liquid ammonia to give geminal silyldiamines [R(Me3C)Si(NH2)(2), 1: R = CH2Me, 2: R = CHMe2]. In the reaction of the monolithium derivatives of these compounds with halosilanes 1-amino-1.3-disilazanes are obtained [(NH2)(Me3C)RSi-NH-SiR1R2R3; 3: R = CMe3, R-1 = R-2 = R-3 = Me; 4: R = R-1 = CMe3, R-2 = R-3 = Me; 5: R-1 = R-2 = R-3 = CMe3, R-3 = H; 6: R = R-1 CMe3, R-2 = Me, R-3 = F; 7: R = CHMe2, R-1 = R-2 = R-3 = Me]. If monolithiated diamines are treated with trifluorosilanes cyclisation occurs to give (NH-Si(CMe3)(2)-NH-SiFR)cyclodisilazanes [R = N(SiMe3)(CMe3) (8); R = N(SiMe2CMe3)(2) (9)]. 50% of the educts are recovered. The spirocyclic compound 10 is isolated from the reaction of the dilithiated 1-amino-1.3-disilazane 3 with F3SiN(SiMe2CMe3)(2). NH-SiF-Functional cyclodisilazanes can be obtained in the reaction of the dilithium derivative of compound 4 with trifluorosilanes [(N(SiMe CMe3)-Si(CMe3)(2)-NH-SiFR), R = Ph (11); R = CMe3 (12)]. The lithium derivative of 12 crystallises with TMEDA as adduct 13. In the reaction of the lithiated compound 12 with Me3SiCl, LiCl elimination and substitution of the N-atom is observed (14). The treatment of 13 with PhCHO leads to a 1.3-diaza-5-oxa-2.4-disila-cyclohexane (15 a, b). Starting from lithiated 12 the methoxy-substituted cyclodisiloxane 16 is accessible in the reaction with MeOH. As result of its reactivity towards Me2SiF2 the fluorosilyl-substituted cyclodisilazane 17 is obtained. Crystal structures of 9-11 and 13 have been determined
Going Beyond Counting First Authors in Author Co-citation Analysis
Get PDFThe present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation
counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings
are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that
only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into
account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed
Variations on the Author
Get PDF“Variations on the Author” discusses two of Eduardo Coutinho’s recent films (Um Dia na Vida, from 2010, and Últimas Conversas, posthumously released in 2015) and their contribution to the general question of documentary authorship. The director’s filmography is characterized by a consistent yet self-effacing form of authorial self-inscription: Coutinho often features as an interviewer that rather than express opinions propels discourses; an interviewer that is good at listening. This mode of self-inscription characterizes him as an author who is not expressive but who is nonetheless markedly present on the screen. In Um Dia na Vida, however, Coutinho is completely absent form the image, while Últimas Conversas, on the contrary, includes a confessional prologue that moves the director from the margins to the center of his films. This article examines the ways in which these works stand out in the filmography of a director who offers new insights into the notion of cinematic authorship
Appropriate Similarity Measures for Author Cocitation Analysis
Get PDFWe provide a number of new insights into the methodological discussion about author cocitation analysis. We first argue that the use of the Pearson correlation for measuring the similarity between authors’ cocitation profiles is not very satisfactory. We then discuss what kind of similarity measures may be used as an alternative to the Pearson correlation. We consider three similarity measures in particular. One is the well-known cosine. The other two similarity measures have not been used before in the bibliometric literature. Finally, we show by means of an example that our findings have a high practical relevance.information science;Pearson correlation;cosine;similarity measure;author cocitation analysis
Dispelling the Myths Behind First-author Citation Counts
Get PDFWe conducted a full-scale evaluative citation analysis study of scholars in the XML research field to explore just how different from each other author rankings resulting from different citation counting methods actually are, and to demonstrate the capability of emerging data and tools on the Web in supporting more realistic citation counting methods. Our results contest some common arguments for the continued
use of first-author citation counts in the evaluation of scholars, such as high correlations between author rankings by first-author citation counts and other citation
counting methods, and high costs of using more realistic citation counting methods that are not well-supported by the ISI databases. It is argued that increasingly available digital full text research papers make it possible for citation analysis studies to go beyond what the ISI databases have directly supported and to employ more
sophisticated methods
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