1,720,952 research outputs found
Multiphase Flow Modelling of Electrochemical Systems: an analytical approach
The primary objective of this work is to provide new analytical models to support the theoretical understanding of multiphase flows in various electrochemical systems. Most of the previous works in this field use either experiments or numerical simulations to understand the hydrodynamics of the multiphase flows. In this thesis, various new analytical models are derived for different cell configurations such as PEM diffusion layer, flow-through electrolysers, parallel plate electrolyzers and zero-gap electrolysers. New design equations are provided that can be readily used as a first estimate for a new electrochemical cell. The novelty of this work lies in providing new analytical approaches to develop a theoretical understanding of electrochemical cells
Going Beyond Counting First Authors in Author Co-citation Analysis
The present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation
counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings
are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that
only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into
account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed
Variations on the Author
“Variations on the Author” discusses two of Eduardo Coutinho’s recent films (Um Dia na Vida, from 2010, and Últimas Conversas, posthumously released in 2015) and their contribution to the general question of documentary authorship. The director’s filmography is characterized by a consistent yet self-effacing form of authorial self-inscription: Coutinho often features as an interviewer that rather than express opinions propels discourses; an interviewer that is good at listening. This mode of self-inscription characterizes him as an author who is not expressive but who is nonetheless markedly present on the screen. In Um Dia na Vida, however, Coutinho is completely absent form the image, while Últimas Conversas, on the contrary, includes a confessional prologue that moves the director from the margins to the center of his films. This article examines the ways in which these works stand out in the filmography of a director who offers new insights into the notion of cinematic authorship
Appropriate Similarity Measures for Author Cocitation Analysis
We provide a number of new insights into the methodological discussion about author cocitation analysis. We first argue that the use of the Pearson correlation for measuring the similarity between authors’ cocitation profiles is not very satisfactory. We then discuss what kind of similarity measures may be used as an alternative to the Pearson correlation. We consider three similarity measures in particular. One is the well-known cosine. The other two similarity measures have not been used before in the bibliometric literature. Finally, we show by means of an example that our findings have a high practical relevance.information science;Pearson correlation;cosine;similarity measure;author cocitation analysis
Dispelling the Myths Behind First-author Citation Counts
We conducted a full-scale evaluative citation analysis study of scholars in the XML research field to explore just how different from each other author rankings resulting from different citation counting methods actually are, and to demonstrate the capability of emerging data and tools on the Web in supporting more realistic citation counting methods. Our results contest some common arguments for the continued
use of first-author citation counts in the evaluation of scholars, such as high correlations between author rankings by first-author citation counts and other citation
counting methods, and high costs of using more realistic citation counting methods that are not well-supported by the ISI databases. It is argued that increasingly available digital full text research papers make it possible for citation analysis studies to go beyond what the ISI databases have directly supported and to employ more
sophisticated methods
An Analytical Model for Liquid and Gas Diffusion Layers in Electrolyzers and Fuel Cells
The diffusion layer is a crucial part of most fuel cells and electrolyzers. We analytically solve a simplified set of visco-capillary equations for the gas and liquid saturation profiles inside such layers. Contrary to existing numerical simulations, this approach allows us to obtain general scaling relations. We derive simple explicit equations for the limiting current density associated with reactant starvation, flooding, and membrane dehydration, including the effect of fluid properties, contact angle, tortuosity, and the pore size distribution. This is the first explicit, extensive and thorough analytical modeling framework for the two-phase transport in an electrochemical cell that provides useful insights into the performance characteristics of the diffusion layer. A more even pore size distribution generally allows higher currents. Explicit expressions for the inimmum pore size and maximum layer thickness show that modern diffusion layers are typically well-designed.Energy Technolog
An analytical multiphase flow model for parallel plate electrolyzers
Membraneless parallel-plate electrolyzers use electrolyte flow to avoid product crossover. Using a mixture model neglecting inertia, and assuming an exponential gas fraction profile, we derive approximate analytical expressions for the velocity profile and pressure drop for thin plumes. We verify these expressions using numerical solutions obtained with COMSOL and validate them using experimental data from the literature. We find that the wall gas fraction increases rapidly at small heights, but becomes fairly constant at larger heights. These expressions serve as a guiding framework for designing a membraneless parallel-plate electrolyzer by quantifying the maximum possible height. We find that buoyancy driven membraneless parallel-plate electrolyzers with a 3 mm gap can be designed with a maximum height of around 7.6 cm at 1000 A/m2 for operation with 98% product purity at atmospheric pressure. For a forced flow at Re=1000, the same electrolyzer can be made around 17.6 cm tall at 1000 A/m2. These limits can be further improved with smaller bubbles or higher pressure.Energy Technolog
koamabayili/VECTRON-author-checklist: VECTRON author checklist
We have done our best to complete the author checklist relating to the use of animals in the hut study. Note that the objective for the hut study was to evaluate the IRS treatment applications for residual efficacy against Anopheles mosquitoes, including the local An. coluzzii mosquito population. Cows were only used to attract mosquitoes into the huts and no tests were carried out directly on the cows. The author checklist is intended for use with studies where experiments are carried out on animals, which is why we have had such difficulty in completing this for the hut study, as many of the questions do not relate to how the cows were used
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