200,686 research outputs found

    Fabio Quaranta

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    profilo del fashion designer italiano Fabio Quarant

    La Wally. Ebben? nè andrò : Aria / Catalani, comp. Lasciali dir, tu m'ami : Melodia / Quaranta, comp ; Salomea Krusceniski, S [acc p]

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    Titre uniforme : Catalani, Alfredo (1854-1893). Compositeur. [La Wally]. ExtraitTitre uniforme : Quaranta, Francesco (1848-1897). Compositeur. [Lasciali dir, tu m' ami]Comprend : La Wally / Catalani, comp ; Lasciali dir, tu m'ami / Quaranta, compContient une table des matière

    The chemistry of N-CO2 bonds: synthesis of carbamic acids and their derivatives, isocyanates, and ureas

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    The chapter provides an updated account of the research activity concerning the utilization of carbon dioxide in the synthesis of carbamates, isocyanates, and ureas

    La Sala dei Quaranta

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    Dal Portogallo al Bosforo: quaranta personaggi illustri della cultura, della scienza, della politica, testimoni della secolare capacità che l’Università di Padova ebbe – dal Duecento in avanti – di attrarre scolari da ogni dove. Il Volume sintetizza la loro storia personale (F. Piovan) e ricostruisce tempi e modi della decisione di collocare i loro ritratti (eseguiti da Gian Giacomo Dal Forno) nella Sala dei Quaranta, durante i lavori di riqualificazione del Bo, presieduti e coordinati da Carlo Anti e Gio Ponti, fra anni Trenta e Quaranta del Novecento (M. Nezzo)

    “Carbomethoxylating reactivity of methyl phenyl carbonate towards aromatic amines in the presence of Group 3 metal (Sc, La) triflate catalysts”

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    Methyl phenyl carbonate (MPC) has been investigated as a carbomethoxylating agent of aromatic amines in the presence of group 3 metal (Sc or La) triflate catalysts. Under mild conditions (363 K), both Sc(OTf)3 and La(OTf)3 (OTf = O3SCF3) can promote the carbamation of aniline and a few industrially relevant aromatic diamines, such as 4,4-methylenedianiline (MDA) and 2,4-diaminotoluene (TDA), with MPC. Carbamate yield and selectivity are markedly affected by the experimental conditions (temperature, reaction medium, nature of the metal center). Sc(OTf)3 is a more effective and selective carbamation catalyst than La(OTf)3. Ad hoc experiments have shown that, in the presence of the M(OTf)3 (M = Sc, La) catalysts, MPC is not only more reactive but also a more selective carbomethoxylating agent than dimethyl carbonate (DMC)
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