1,720,995 research outputs found
Direct evidence for the participation of band-tails and excited-state tunnelling in the luminescence of irradiated feldspars
The significance and extent of band-tail states in the luminescence and dosimetry properties of natural aluminosilicates (feldspars) is investigated by means of studies using low temperature (10 K) irradiation and optically stimulated luminescence (OSL) stimulation spectroscopy, and thermoluminescence (TL) in the range 10–200 K, made in comparison with high temperature (300 K) irradiation and photo-transferred OSL and TL investigations undertaken at low temperature. These measurements allow mappings of the band-tails to be made; they are found to be ?0.4 eV in extent in the typical materials studied. Furthermore, by populating charge trapping centres at high temperature (300 K) and monitoring the OSL stimulation spectra at temperatures in the range 10–300 K, clear evidence is presented for the presence of both thermally activated and non-thermally activated OSL processes; it is argued that the former result from thermally activated hopping through the band-tail states, whilst the latter are due to tunnelling processes, either from the excited state of the OSL centres or through the tail states. The spectral measurements are supported by analysis of the temporal dependence of the OSL signals, which correspond to either tunnelling or general order kinetic decay processes.RRR/Radiation, Radionuclides and ReactorsApplied Science
Micro-imaging synchrotron-laser interactions in wide band-gap luminescent materials
Applied Science
Going Beyond Counting First Authors in Author Co-citation Analysis
The present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation
counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings
are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that
only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into
account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed
The influence of crystal structure on the excitation and emission spectra of OSL in alkali and plagioclase feldspars
Thermal quenching of luminescence processes in feldspars
The technique of optically stimulated luminescence has important uses in the dose evaluation of irradiated feldspars. The luminescence process involves the eviction of electrons from donor traps, charge transfer through the conduction band, and recombination at acceptor sites; each of these processes is, in general, thermally dependent, and leads either to enhancement or quenching of the luminescence with increasing temperature. Previous studies have measured the combined thermal activation characteristics of all three processes, and show a strong dependence on stimulation energy. In this article, an initial attempt is made to isolate only the recombination part of the luminescence cycle, and determine its thermal characteristics separately. A Variety of luminescence transitions are examined in a range of both alkali and plagioclase feldspars; three distinct emission types are identified, which display very different behaviour. The first involves the internal transitions of common transition metal ions. The second is typical of centres not displaying excited states within the band gap that are likely to arise from direct recombination between the conduction band and the ground state of the defect. The third category is the most difficult to analyse since it involves irreversible changes in the luminescence characteristics with increasing temperature; we consider these to be due to thermally-induced destruction or creation of luminescence centres. Most of the alkali and plagioclase feldspars studied showed such an effect, to a greater or lesser extent, and the process complicates analysis of the reversible sensitivity changes
Variations on the Author
“Variations on the Author” discusses two of Eduardo Coutinho’s recent films (Um Dia na Vida, from 2010, and Últimas Conversas, posthumously released in 2015) and their contribution to the general question of documentary authorship. The director’s filmography is characterized by a consistent yet self-effacing form of authorial self-inscription: Coutinho often features as an interviewer that rather than express opinions propels discourses; an interviewer that is good at listening. This mode of self-inscription characterizes him as an author who is not expressive but who is nonetheless markedly present on the screen. In Um Dia na Vida, however, Coutinho is completely absent form the image, while Últimas Conversas, on the contrary, includes a confessional prologue that moves the director from the margins to the center of his films. This article examines the ways in which these works stand out in the filmography of a director who offers new insights into the notion of cinematic authorship
An optically stimulated luminescence study of flint related to radiation dosimetry
This article describes the essential features of photo-stimulated luminescence in flint. The emission is shown to be complex, arising from a number of different aspects of the material. Under constant illumination, dose-dependent time-decaying anti-Stokes signals are superimposed on dose-independent, time-stable emission that is both Stokes and anti-Stokes shifted in energy. It is argued that the dose-dependent signals arise from the crystalline quartz phase of the material, whereas the dose independent signals originate from an amorphous-like phase of SiO2. The microcrystallinity of the material leads to contrasting behaviour when compared with bulk crystalline quartz
Carrier recombination processes and divalent lanthanide spectroscopy in YPO4:Ce3+;L3+ (L=Sm,Dy,Tm)
We studied charge carrier trapping, detrapping, and recombination phenomena in Ce3+ doped YPO4, codoped with Sm3+, Dy3+, or Tm3+. Ce ions trap the holes and Sm, Dy, and Tm trap electrons created during x-ray irradiation. By means of red to infrared stimulation, the trapped electrons can be back transferred to Ce leading to shorter wavelength Ce3+?5d-4f luminescence. Excitation spectra for this recombination luminescence were recorded from 10 K to room temperature. It provides information on the excited state energies of divalent Sm, Dy, and Tm with respect to the lanthanide ground state energy and with respect to the mobility edge energy of YPO4. From the temperature dependence, insight is obtained on the carrier recombination pathways. We will identify temperature independent tunneling recombination, recombination by thermal excitation to the conduction band, and phonon-assisted delocalization of electrons from impurity states within the conduction band.QN/Quantum NanoscienceApplied Science
Appropriate Similarity Measures for Author Cocitation Analysis
We provide a number of new insights into the methodological discussion about author cocitation analysis. We first argue that the use of the Pearson correlation for measuring the similarity between authors’ cocitation profiles is not very satisfactory. We then discuss what kind of similarity measures may be used as an alternative to the Pearson correlation. We consider three similarity measures in particular. One is the well-known cosine. The other two similarity measures have not been used before in the bibliometric literature. Finally, we show by means of an example that our findings have a high practical relevance.information science;Pearson correlation;cosine;similarity measure;author cocitation analysis
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