1,721,031 research outputs found
Combustion of n-C3-C6Linear Alcohols: An Experimental and Kinetic Modeling Study. Part II: Speciation Measurements in a Jet-Stirred Reactor, Ignition Delay Time Measurements in a Rapid Compression Machine, Model Validation, and Kinetic Analysis
Full text linkThis work presents new experimental data for n-C3-C6 alcohol, combustion (n-propanol, n-butanol, n-pentanol, n-hexanol). Speciation measurements have been carried out in a jet-stirred reactor (p = 107 kPa, T = 550-1100 K, φ = 0.5, 1.0, 2.0) for n-butanol, n-pentanol, and n-hexanol. Ignition delay times of ethanol, n-propanol, n-butanol, and n-pentanol/air mixtures were measured in a rapid compression machine at φ = 1.0, p = 10 and 30 bar, and T = 704-935 K. The kinetic subsets for alcohol pyrolysis and oxidation from the CRECK kinetic model have been systematically updated to describe the pyrolysis and high- and low-temperature oxidation of this series of fuels as described in Part I of this work (Pelucchi, M.; Namysl, S.; Ranzi, E. et al. Combustion of n-C3-C6 linear alcohol: an experimental and kinetic modeling study. Part I: reaction classes, rate rules, model lumping and validation. Submitted to Energy and Fuels, 2020). Part II describes in detail the facilities used for this systematic experimental investigation of n-C3-C6 alcohol combustion and presents a complete validation of the kinetic model by means of comparisons with the new data and measurements previously reported in the literature for both pyrolytic and oxidative conditions. Kinetic analyses such as rate of production and sensitivity analyses are used to highlight the governing reaction pathways and reasons for existing deviations, motivating possible further improvements in our chemistry mechanism
Going Beyond Counting First Authors in Author Co-citation Analysis
Full text linkThe present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation
counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings
are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that
only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into
account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed
A Predictive Physico-chemical Model of Biochar Oxidation
Full text linkPyrolysis of solid fuels forms a solid carbon-rich fuel, also called char, whose physico-chemical description is rather complex. Heterogeneous oxidation reactions take place during thermochemical conversion of char. The present work proposes a predictive detailed kinetic model, opening a new path for a deeper understanding of the char conversion process. This model considers porosity, surface area, density of surface sites, and their evolution along the conversion process. The chemical aspects of char oxidation are modeled assuming a carbonaceous bulk structure, surrounded by a variety of surface sites which represent the chemical functionalities typically present in such materials. The heterogeneous chemical reactions and their kinetic parameters are defined based on previous studies in the literature and by analogy to homogeneous gas-phase reactions of aromatic species. A mathematical framework is proposed to couple physical and chemical descriptions of the oxidation process. Although the proposed model benefits from experimental information, it is able to comprehensively describe the conversion rate of a broad range of carbonaceous materials such as carbon nanotubes, graphite, and chars only on the basis of their elemental composition. The proposed model represents a first step in exploring the explicit and coupled treatment given to the physical and chemical evolution of the fuel throughout its conversion, allowing us to consistently describe the particle evolution, opening a path for reliable models to manage the chemistry of char conversion
Variations on the Author
Full text link“Variations on the Author” discusses two of Eduardo Coutinho’s recent films (Um Dia na Vida, from 2010, and Últimas Conversas, posthumously released in 2015) and their contribution to the general question of documentary authorship. The director’s filmography is characterized by a consistent yet self-effacing form of authorial self-inscription: Coutinho often features as an interviewer that rather than express opinions propels discourses; an interviewer that is good at listening. This mode of self-inscription characterizes him as an author who is not expressive but who is nonetheless markedly present on the screen. In Um Dia na Vida, however, Coutinho is completely absent form the image, while Últimas Conversas, on the contrary, includes a confessional prologue that moves the director from the margins to the center of his films. This article examines the ways in which these works stand out in the filmography of a director who offers new insights into the notion of cinematic authorship
On the combustion and sooting behavior of standard and hydro-treated jet fuels: An experimental and modeling study on the compositional effects
Full text linkIn a context of growing level of environmental awareness, emission from aviation are the subject of increasing scrutiny. This situation poses important challenges because, due to safety, practical and economic factors, aero-transportation technologies are not likely to undergo rapid paradigm shifts. An area where important innovations are being introduced is fuel technology: fuels from alternative processes, potentially from renewable sources, offer the opportunity of limiting the carbon footprint of transportation, moreover, a better control on fuel quality can contribute to reducing emissions. Hydro-treating of oil based fuels can reduce their sulfur and aromatic content promoting a cleaner combustion. In order to better understand the impact of hydro-treating on emissions of PAHs and soot from jet fuels, new speciation data covering oxidation intermediates and soot precursors were measured in a flow reactor for a standard jet fuel and its hydro-treated counterpart. Using a detailed kinetic mechanism and complex surrogate blends mimicking the composition of the real fuels, the speciation data from the flow reactor were simulated. Additionally, soot formation trends were calculated and compared with previously published data. Using the kinetic model, which is based on mechanistic principles, it was possible to separate the relative contribution of different processes and, for the fuel blends of interest, the role played by specific components in the PAHs and soot formation. The results obtained provide useful information towards more effective fuel formulation strategies and fuel blends modeling
Theoretical study of sensitive reactions in phenol decomposition
Full text linkThe reactivity of phenol is of utmost importance in combustion systems. In fact, phenol is the simplest phenolic compound, abundant in bio-oils derived from biomass fast pyrolysis and therefore included as a reference component in bio-oil surrogate mixtures. Phenol is also relevant to the mechanism of oxidation of benzene, a building block in the growth of polycyclic aromatic hydrocarbons (PAHs), precursors of soot formation. Hence, in a modular and hierarchical approach to combustion chemistry, the knowledge of the pyrolysis and combustion kinetics of phenol is essential to characterize the reactivity and the combustion properties of bio-oils and mono aromatic hydrocarbons (MAHs), as well as to improve the understanding of PAHs and soot formation. Although the reaction pathways of phenol decomposition are well defined in the literature, the rate constants still require more accurate assessment, and a validation of the reaction mechanism of phenol pyrolysis against the full set of experimental data available is still missing. In this work, we compute with the ab initio transition state theory based master equation (AI-TST-ME) method the rate constants of the main reaction pathways of phenol decomposition, also relevant to benzene oxidation. In particular, we investigate phenol molecular decomposition to C5H6 + CO and its competition with the O-H bond fission and H-atom abstraction reactions by H to form the phenoxy radical (C6H5O). We also investigate the successive decomposition of C6H5O to C5H5 + CO and the H-atom abstraction reaction on C5H6 by H, which plays a pivotal role in controlling the H concentration in phenol pyrolysis and combustion. The calculated rate constants are found to be in good agreement with experimental values. The CRECK kinetic model is updated with the new rate constants and validated against the available experimental data of phenol pyrolysis providing, to our knowledge, the first comprehensive validation of phenol decomposition kinetics. However, discrepancies are still present in the profiles of products formed from secondary reactivity. Our analysis suggests that further investigation of the reactivity of C5H6 is required, providing guidelines for a more accurate characterization of the decomposition to smaller species
Appropriate Similarity Measures for Author Cocitation Analysis
Full text linkWe provide a number of new insights into the methodological discussion about author cocitation analysis. We first argue that the use of the Pearson correlation for measuring the similarity between authors’ cocitation profiles is not very satisfactory. We then discuss what kind of similarity measures may be used as an alternative to the Pearson correlation. We consider three similarity measures in particular. One is the well-known cosine. The other two similarity measures have not been used before in the bibliometric literature. Finally, we show by means of an example that our findings have a high practical relevance.information science;Pearson correlation;cosine;similarity measure;author cocitation analysis
Dimethyl ether oxidation analyzed in a given flow reactor: Experimental and modeling uncertainties
Full text linkStagni A, Schmitt S, Pelucchi M, Frassoldati A, Kohse-Höinghaus K, Faravelli T. Dimethyl ether oxidation analyzed in a given flow reactor: Experimental and modeling uncertainties. Combustion and Flame . 2022;240: 111998.Dimethyl ether (DME), a widely studied alternative fuel, is known to exhibit complex low- and high-temperature oxidation chemistry. It is also the smallest molecule in the families of symmetric ethers and oxymethylene ethers that receive attention as renewable fuels. Thanks to several studies performed in facilities such as shock tubes, jet-stirred reactors and flames, it can be assumed that the DME oxidation is well understood. However, DME oxidation in flow reactors has been addressed comparatively rarely, although this configuration presents an interesting system with influences of both kinetics and fluid dynamics on the reaction behavior. To examine the interplay of both influences and potential uncertainties resulting from such effects, DME oxidation was experimentally investigated over an extended range of conditions in a flow reactor equipped with mass-spectrometric analysis. Quantitative species profiles were obtained at near-atmospheric pressure in a temperature range of 40 0-110 0 K for three equivalence ratios phi (0.8, 1.0 and 1.2), and three flow rates at each stoichiometry. These nine different cases were first analyzed using a detailed chemical reaction mechanism with a Plug-Flow Reactor (PFR) model. In-depth examination of experimental and reaction model uncertainties led to updates in the reaction mechanism that were performed on the basis of most recent, reliable kinetic information. In spite of the good agreement of the PFR model with the experimental data at selected conditions, especially in the low temperature regime, substantial deviations in the reactivity and associated species profiles were noted in several cases, particularly for lean conditions at low flow rates and intermediate temperatures around and above 700 K. A two-dimensional (2D) computational fluid dynamics (CFD) model was therefore employed to characterize the reactive flow conditions more accurately. Significant contributions of fluid dynamics effects were observed in the cases that presented the most severe deviations, and overall good agreement within experimental uncertainty was obtained for the nine cases with the 2D simulations. With the aid of a mathematical curve matching procedure using a variety of recent, established kinetic mechanisms, it could be convincingly demonstrated under the current conditions that improvements in predictive modeling capability in the sensitive test cases were not a question of improved kinetics but were mainly achieved by considering the two-dimensional reactive flow. As a consequence, the present investigation can serve to alert the community to the potential major influences that might be neglected if standard PFR models are used to predict fuel oxidation without detailed analysis whether the conditions are suited to that approach. (c) 2022 The Combustion Institute. Published by Elsevier Inc. All rights reserved
Theoretical kinetics of HO2 + C5H5: A missing piece in cyclopentadienyl radical oxidation reactions
No full textThe resonantly-stabilized cyclopentadienyl radical (C5H5) is a key species in the combustion and molecular growth kinetics of mono and poly-aromatic hydrocarbons (M/PAHs). At intermediate-to-low temperatures, the C5H5 reaction with the hydroperoxyl radical (HO2) strongly impacts the competition between oxidation to smaller products and growth to PAHs, precursors of soot. However, literature estimates for the HO2 + C5H5 reaction rate are inaccurate and inconsistent with recent theoretical calculations, thus generating discrepancies in global combustion kinetic models. In this work, we perform state-of-the-art theoretical calculations for the HO2 + C5H5 reaction including variable reaction coordinate transition state theory for barrierless channels, accurate thermochemistry, and multi-well master equation (ME) simulations. Contrary to previous studies, we predict that OH + 1,3-C5H5O is the main reaction channel. The new rate constants are introduced in two literature kinetic models exploiting our recently developed ME based lumping methodology and used to perform kinetic simulations of experimental data of MAHs oxidation. It is found that the resonantly-stabilized 1,3-C5H5O radical is the main C5H5O isomer, accumulating in relevant concentration in the system, and that the adopted lumping procedure is fully consistent with results obtained with detailed kinetics. The reactivity of C5H5O with OH and O-2 radicals is included in the kinetic mechanisms based on analogy rules. As a result, C5H5O mostly reacts with O-2 producing smaller C-3/C-4 species and large amounts of C5H4O, suggesting that further investigations of the reactivity of both C5H5O and C5H4O with oxygenated radicals is necessary. Overall, this work presents new reliable rate constants for the HO2 + C5H5 reaction and provides indications for future investigations of relevant reactions in the sub-mechanisms of cyclopentadiene and MAH oxidation
- …
