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    Application of different thermal analysis techniques to characterize oxidized olive oils

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    The deep changes caused by oxidation on virgin olive oil (VOO), which is a high-quality product, not subjected to ameliorative refining, make this phenomenon one of the most studied. Among the techniques used to study oxidation in olive oil, thermal analysis (TA) provides useful information about the thermal behavior of the samples as affected by oxidation. Thermogravimetry (TG), measuring the changes in the sample mass, can monitor the kinetics of oil mass loss in decomposition processes or oxidation and has been found particularly useful, especially when operating simultaneously with Differential Thermal Analysis (DTA) or Differential Scanning Calorimetry (DSC). The DSC thermal curves of olive oil, both on cooling and heating, has been found to be largely influenced by the oxidative status of the samples and different statistical approaches have been successfully proposed to correlate the thermal parameters with the conventional chemical indicators of oxidation. DSC can be also used to study the kinetics of phase transition phenomena as affected by oxidation. This review provides an exhaustive survey about the application of the thermoanalytical techniques on this topic proposing them as as a fast and green alternative to conventional chemical methods

    Chestnut flour addition in commercial gluten-free bread: A shelf-life study

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    Two commercial gluten-free mixtures (F1gf, and F2gf) were enriched with 20 g/100 g and 10 g/100 g of chestnut flour, respectively, to produce technologically and nutritionally improved breads (M1C, M2C) to be compared to gluten-free breads (M1 and M2). Physicochemical (proximate composition, colour, texture, crumb grain characteristics) and nutritional (antioxidant capacity, in vitro digestion) indices were monitored during three days storage. The addition of chestnut flour led to colour browning, lower bulk volume with larger crumb holes and faster staling resulting from crumb cohesiveness and resilience decrease. M2C presented harder crumb and smaller holes compared to M1C, probably due to the lupine proteins in M2C. During storage, the crust hardness decreased (M1C) or increased (M2C) depending on mixture components, as consequence of different water migration. Higher antioxidant activity was observed for both the enriched breads while no variations resulted in starch digestibility. Finally, only breads with 20 g/100 g of enrichment showed a significant increase in total as well as soluble and insoluble fibres

    Sourdough Fermentation and Chestnut Flour in Gluten-free Bread: a shelf-life evaluation

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    The effect of sourdough fermentation combined with chestnut flour was investigated for improving technological and nutritional quality of gluten-free bread during 5 day shelf life by means of chemicophysical and nutritional properties. Sourdough fermentation by itself and with chestnut flour reduced volume of loaves and heterogeneity in crumb grain. Sourdough technology allowed increasing crumb moisture content with no significant variations during shelf-life. Chestnut flour darkened crumb and crust while no effects on colour were observed for sourdough. Sourdough and/or chestnut flour addition caused a significant increase in crumb hardness at time 0 while a significant reduction of staling was observed only at 5 days, even if a decrease in amylopectin fusion enthalpy was observed. The percentage of hydrolysed starch during in vitro digestion was significantly reduced by sourdough fermentation with a presumable lower glycaemic index
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