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Il credito fondiario delle Venezie nel Novecento
Ricostruzione nel tempo che fu suo di un importante istituto di credit
TYDOCK PHARMA s.r.l. Spin Off dell'Università di Modena e Reggio Emilia che ha come fine l'attività di ricerca e sviluppo nel settore delle biotech farmaceutiche.
Il taglio di Porto Viro: storia dell'impresa e delle sue implicazioni politiche
Miscellanea i saggi storici in onore professor Giovanni Zali
Dehydration process and transient channel deformations of slightly hydrated boron leucite: An “in situ” time-resolved synchrotron powder diffraction study
The step by step thermal dehydration process of slightly hydrated boron leucite K16[B16Si32O96],
was studied in situ by synchrotron radiation powder diffraction. A time-resolved experiment was
performed using a translating imaging plate system. Rietveld refinements were carried out on 41
consecutive powder patterns in the 25°C to 940°C temperature range. Results show that
temperature-induced transformations can be schematized into two main steps. In the 25-565°C
temperature range, the symmetry remained cubic I-43d and the unit cell parameter increased with
an increase in temperature. The migration of H2O molecules through the [111] channels during
dehydration determined an opening of the six-member ring apertures which was as wide as possible
and, at the same time, a narrowing in the eight-ring along [111]. This process was accomplished by
a twisting in the tetragonal prism, constituting a leucite framework, which led to an opposed tilting
in the tetrahedra connecting the prisms. Above 565°C, a continuous structural transformation led to a displacive polymorphic transition. Rietveld structure refinement of the unit cell parameters showed remarkable change, thus indicating an I-43d → Ia-3d change in symmetry. This was associated with a relaxation in the continuous structural distortions of the leucite framework and the T-O-T and O-T-O angles indicated the formation of more regular aperture
Caratteristiche degli olii essenziali di piante di Lavandula hybrida Reverchon “Grosso” coltivate in aree appenniniche
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