236 research outputs found

    The global food chain

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    Jonathon Porritt is Founder Director of Forum for the Future www.forumforthefuture.org.uk; Chairman of the UK Sustainable Development Commission www.sd-commission.org.uk; and author of Capitalism as if the World Matters (Earthscan, 2007)

    A conceptual review of interprofessional expertise in child safeguarding

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    It is increasingly accepted that practitioners across a range of professional fields must work together in order to promote children's welfare and protect them from harm. However, it has also become apparent that interprofessional working is a challenging area of practice that cannot simply be prescribed through protocols and procedures, nor acquired as a set of technical competences. This article develops the concept of interprofessional expertise in order to explain how practitioners become more proficient at working with others to manage complex child welfare issues. Key principles are outlined with reference to relevant theoretical frameworks, including models of skill acquisition. The article concludes by discussing some potential implications for future research and contemporary developments in child safeguarding practice

    Allylic C—H activation to access anti-1,3-amino alcohol motifs

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    1,3-Amino alcohols are common motifs in a variety of biologically active molecules including antivirals, antibiotics, antifungals, and various alkaloids. Due to their prevalence and utility as synthetic intermediates, a variety of methods have been developed to access these motifs in a diastereoselective fashion, which are outlined in detail herein. This thesis documents a novel approach to access anti-1,3-amino alcohols through an intramolecular palladium (II)/sulfoxide-oxazoline catalyzed C—H functionalization between a terminal olefin and an N-tosyl carbamate, generating anti-1,3-oxazinanones. These motifs can be further elaborated upon, making this method ideal for the late stage diversification of complex molecules and pharmaceuticals. This new method can be carried out in the presence of reactive functionality that is not well tolerated by existing methods.Submission published under a 24 month embargo labeled 'Closed Access', the embargo will last until 2020-05-01The student, Jonathon Young, accepted the attached license on 2018-04-25 at 09:29.The student, Jonathon Young, submitted this Thesis for approval on 2018-04-25 at 09:40.This Thesis was approved for publication on 2018-04-25 at 14:08.DSpace SAF Submission Ingestion Package generated from Vireo submission #12470 on 2018-08-31 at 17:30:26Made available in DSpace on 2018-09-04T20:47:30Z (GMT). No. of bitstreams: 2 YOUNG-THESIS-2018.pdf: 17381393 bytes, checksum: e7e97dc99ab1ce290a64d3a5a9836002 (MD5) LICENSE.txt: 4211 bytes, checksum: 6e0b64d3ab5cba30177cd6924932d927 (MD5) Previous issue date: 2018-04-25Embargo set by: Seth Robbins for item 107460 Lift date: 2020-09-04T20:47:38Z Reason: Author requested closed access (OA after 2yrs) in Vireo ETD systemEmbargo set by: Seth Robbins for item 107460 Lift date: 2020-09-04T20:50:11Z Reason: Author requested closed access (OA after 2yrs) in Vireo ETD systemLimited Restriction Lifted for Item 107460 on 2020-09-05T09:15:26Z

    Data and script for Van Berkel et al: Can starlings use a reliable cue of future food deprivation to adaptively modify foraging and fat reserves?

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    Supporting materials for: Can starlings use a reliable cue of future food deprivation to adaptively modify foraging and fat reserves? Menno van Berkela, Melissa Batesona, Daniel Nettlea and Jonathon Dunna* aCentre for Behaviour and Evolution & Institute of Neuroscience, Newcastle University, Newcastle, UK *Author for correspondence (email: [email protected]; telephone: (+44)7730015855; postal address: Institute of Neuroscience, Henry Wellcome Building, The Medical School, Framlington Place, Newcastle University, Newcastle upon Tyne, UK, NE2 4HH). R script and 3 .csv files.</p

    MEMS Harsh Environment Sensors for Earth and Space Exploration

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    abstract: Harsh environments have conditions that make collecting scientific data difficult with existing commercial-off-the-shelf technology. Micro Electro Mechanical Systems (MEMS) technology is ideally suited for harsh environment characterization and operation due to the wide range of materials available and an incredible array of different sensing techniques while providing small device size, low power consumption, and robustness. There were two main objectives of the research conducted. The first objective was to design, fabricate, and test novel sensors that measure the amount of exposure to ionizing radiation for a wide range of applications including characterization of harsh environments. Two types of MEMS ionizing radiation dosimeters were developed. The first sensor was a passive radiation-sensitive capacitor-antenna design. The antenna's emitted frequency of peak-intensity changed as exposure time to radiation increased. The second sensor was a film bulk acoustic-wave resonator, whose resonant frequency decreased with increasing ionizing radiation exposure time. The second objective was to develop MEMS sensor systems that could be deployed to gather scientific data and to use that data to address the following research question: do temperature and/or conductivity predict the appearance of photosynthetic organisms in hot springs. To this end, temperature and electrical conductivity sensor arrays were designed and fabricated based on mature MEMS technology. Electronic circuits and the software interface to the electronics were developed for field data collection. The sensor arrays utilized in the hot springs yielded results that support the hypothesis that temperature plays a key role in determining where the photosynthetic organisms occur. Additionally, a cold-film fluidic flow sensor was developed, which is suitable for near-boiling temperature measurement. Future research should focus on (1) developing a MEMS pH sensor array with integrated temperature, conductivity, and flow sensors to provide multi-dimensional data for scientific study and (2) finding solutions to biofouling and self-calibration, which affects sensor performance over long-term deployment.Dissertation/ThesisPh.D. Engineering 201

    MEMS harsh environment sensor array-enabled hot spring mapping

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    We report the design and application of MEMS temperature and electrical conductivity sensor arrays for studying the harsh environments of hot springs. Centimeter-scale measurements were necessary to measure geochemical gradients across photosynthetic bacteria transition zones. Platinum, Parylene-C, and fused silica were critical materials used in fabrication. More than 700 temperature and 90 conductivity measurements were taken in the mixing zone where two geochemically different hot spring channels converged and the data show that the temperature gradients play an important role in determining where photosynthetic organisms appear. Additionally, a novel technique was developed for studying conservative parameters at centimeter spatial scales.</p

    Historical legacies, competition and dispersal control patterns of invasion by a non-native grass, Microstegium vimineum Trin. (A. Camus)

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    Biological invasions can be controlled by a number of factors, and the importance of these factors for individual species can change depending on the spatial scale under consideration. Furthermore, the long-term legacies of past land use may be among the major factors structuring contemporary communities. This study was designed to merge these two lines of thought by observing the processes influencing invasion success of an exotic grass species, Microstegium vimineum. Plots within twenty hardwood forest stands of different ages (40 years old to [greater than] 100 years) were surveyed in central New Jersey for the presence and abundance of this species, and the data was analyzed using simple, multiple linear and logistic regressions, as well as regression trees. At the stand scale, M. vimineum abundance was influenced by age, slope, shrub cover and forest connectivity, with far more predictable responses in younger stands than in old. On the plot scale, forest age and prior use were again the dominant influences on abundance of the invasive. Invasion in old forests was most promoted by thinner canopy cover, while younger stands were most influenced by soil type and distance to forest edge. Further studies along dispersal corridors (streams and trails) in these stands consistently showed more invasion in younger stands than older, but also found the intensity of invasion to be higher along such corridors than through areas without them. Observation of isolated patches confirmed that seed dispersal is mostly short-range without dispersal conduits, with most seeds germinating less than a meter from their parent patch boundaries. Finally, an experimental study of the role of understory shrub cover and litter depth on seed germination and seedling growth showed that shade from shrubs strongly limits survival and growth. Seeds also need to be in contact with mineral soil to establish, but otherwise litter depth does not influence growth. These studies demonstrate that the establishment and spread of this invasive species is affected by complex hierarchies of factors that differ in stands with different land use histories. Land managers can use these differences to design targeted control programs that are more effective and stand-specific.Ph.D.Includes bibliographical references (p. 148-159)
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