1,721,702 research outputs found
Comparison of Three Isoelectronic Multiple-Well Reaction Systems: OH + CH<sub>2</sub>O, OH + CH<sub>2</sub>CH<sub>2</sub>, and OH + CH<sub>2</sub>NH
No full textMethylenimine
(CH<sub>2</sub>NH) has been predicted to be a product
of the atmospheric photo-oxidation of methylamine, but its atmospheric
reactions have not been measured. In this paper, we report potential
energy surfaces (PESs) and rate constants for OH + CH<sub>2</sub>NH
and its isoelectronic analogues OH + CH<sub>2</sub>O and OH + CH<sub>2</sub>CH<sub>2</sub>, which are more fully understood. The PESs
were computed using the BHandHLYP/aug-cc-pVTZ and CCSD(T)/aug-cc-pVTZ
levels of theory. Canonical variational transition state theory and
Rice–Ramsperger–Kassel–Marcus and master equation
modeling were used to calculate temperature- and pressure-dependent
rate constants, with particular emphasis on the OH + reactant entrance
channels and the effects of prereactive complexes. The computed results
are in reasonable agreement with experimental data where they can
be compared and also with the results of previous theoretical calculations.
The results show that to some extent OH radicals both add to the carbon
center double bond in CH<sub>2</sub>NH and abstract methylene hydrogen
atoms, as in the OH + CH<sub>2</sub>O and OH + CH<sub>2</sub>CH<sub>2</sub> reactions, respectively, but the dominant pathway is abstraction
of the hydrogen from N–H. The computed rate constants are suitable
for both atmospheric and combustion modeling
Going Beyond Counting First Authors in Author Co-citation Analysis
Full text linkThe present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation
counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings
are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that
only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into
account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed
Variations on the Author
Full text link“Variations on the Author” discusses two of Eduardo Coutinho’s recent films (Um Dia na Vida, from 2010, and Últimas Conversas, posthumously released in 2015) and their contribution to the general question of documentary authorship. The director’s filmography is characterized by a consistent yet self-effacing form of authorial self-inscription: Coutinho often features as an interviewer that rather than express opinions propels discourses; an interviewer that is good at listening. This mode of self-inscription characterizes him as an author who is not expressive but who is nonetheless markedly present on the screen. In Um Dia na Vida, however, Coutinho is completely absent form the image, while Últimas Conversas, on the contrary, includes a confessional prologue that moves the director from the margins to the center of his films. This article examines the ways in which these works stand out in the filmography of a director who offers new insights into the notion of cinematic authorship
Appropriate Similarity Measures for Author Cocitation Analysis
Full text linkWe provide a number of new insights into the methodological discussion about author cocitation analysis. We first argue that the use of the Pearson correlation for measuring the similarity between authors’ cocitation profiles is not very satisfactory. We then discuss what kind of similarity measures may be used as an alternative to the Pearson correlation. We consider three similarity measures in particular. One is the well-known cosine. The other two similarity measures have not been used before in the bibliometric literature. Finally, we show by means of an example that our findings have a high practical relevance.information science;Pearson correlation;cosine;similarity measure;author cocitation analysis
Dispelling the Myths Behind First-author Citation Counts
Full text linkWe conducted a full-scale evaluative citation analysis study of scholars in the XML research field to explore just how different from each other author rankings resulting from different citation counting methods actually are, and to demonstrate the capability of emerging data and tools on the Web in supporting more realistic citation counting methods. Our results contest some common arguments for the continued
use of first-author citation counts in the evaluation of scholars, such as high correlations between author rankings by first-author citation counts and other citation
counting methods, and high costs of using more realistic citation counting methods that are not well-supported by the ISI databases. It is argued that increasingly available digital full text research papers make it possible for citation analysis studies to go beyond what the ISI databases have directly supported and to employ more
sophisticated methods
koamabayili/VECTRON-author-checklist: VECTRON author checklist
No full textWe have done our best to complete the author checklist relating to the use of animals in the hut study. Note that the objective for the hut study was to evaluate the IRS treatment applications for residual efficacy against Anopheles mosquitoes, including the local An. coluzzii mosquito population. Cows were only used to attract mosquitoes into the huts and no tests were carried out directly on the cows. The author checklist is intended for use with studies where experiments are carried out on animals, which is why we have had such difficulty in completing this for the hut study, as many of the questions do not relate to how the cows were used
DataSheet1_Feasibility on equivalence ratio measurement via OH*, CH*, and C2* chemiluminescence and study of soot emissions in co-flow non-premixed DME/C1–C2 hydrocarbon flames.PDF
No full textThe effects of dimethyl ether (DME) addition to methane and ethylene fuels on the combustion characteristics of heat release, soot emissions, and flame temperature were investigated experimentally and numerically in a non-premixed laminar flame configuration. The flame-heat release soot-volume fraction was measured experimentally using CH*, OH*, and C2* chemiluminescence and planar two-color soot pyrometry, respectively. The CH*, OH*, and C2* were used to locate flame-heat release regions as well as to investigate the soot signal’s effect on their measurements. The ratios of the chemiluminescence pairs (OH*/CH* and OH*/C2*) were studied for the feasibility of map local equivalence ratios. Numerical calculations across a full range of DME mixing ratios were performed through 1D laminar flame simulations implemented with a detailed mechanism to provide an indication of the flame structures and profiles of key species including OH*, OH, CH*, CH, CH3, C3H3, C2H2, heat release rate (HRR), and flame temperature. An existing developed soot model was used in a 2D computational study to investigate its validity for modeling soot for DME (oxygenated fuel)/C2H4/N2 flames. Parametric studies have been carried out on some key parameters in the soot model to find optimum values that can be used in future studies. Although soot radiation intensities increased at a small amount (25%vol) of DME addition in the DME/methane flames, the soot pyrometry results showed a reduced soot volume fraction with an increased DME mixture ratio in both DME/methane and DME/ethylene flames studied, agreeing with the key conclusion of 1D numerical results. The flame HRR decreases with the increasing addition of DME to methane and ethylene flames and correlates with the trend of OH* and CH* profiles. The 1D simulation showed a non-monotonic correlation between OH*/CH* ratios and equivalence ratios, implying a limited use of OH*/CH* for the equivalence ratio measurement in non-premixed flames with DME additions.</p
- …
