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Stabilization of unstable unsatured molecules in five-coordinate TBP complexes of Pt(II): enol, diol and dialdehyde derivatives
No full textProtection and stabilization of some unstable olefins has been effectively achieved by coordination in live-coordinate [PtClMe(2,9-Me-2-1,10-phenanthroline)(olefin)] complexes. These have been characterized by H-1-NMR spectroscopy and iu the case of [PtClMe(2,9-Me-2-1,10-phenanthroline)(Z-EtCH=CHOH)] by X-ray diffractometry. Chemoselective reactions have been accomplished on the complexes, some of them involving alcoholic or aldehydic functions of the unsaturated ligan
Organometallics in Water: Three-Coordinate [Pt0(N,N-chelate) (e2- olefin)] Complexes Containing New Chiral Ligands Based on a-D-Mannose
No full textStability and reactivity of the cis-{PtIIR(alkyne)} fragment (R= alkyl): an unprecedented rearrangement to form the {PtII(allyl)} moiety
No full textStabilization of unstable unsaturated molecules in five-coordinate TBP complexes of Pt(II): enol, diol and dialdehyde derivatives
No full textThe first class of square-planar platinum(II) complexes containing electron-poor alkenes. Rare insertion of an alkene into a Pt-alkyl bond
No full textThe first class of square-planar platinum(II) complexes containing electron-poor alkenes. Rare insertion of an alkene into a Pt-alkyl bond
No full textCOMPLESSI OLEFINICI DI PT(II) CONTENENTI UN LEGANTE MIMINO-AMMIDE: EVIDENZE NMR DI UN SIGNIFICATIVO CONTRIBUTO DI P-RETRODONAZIONE NEL LEGAME PT-OLEFINA
No full textNEUTRAL PT(II) COMPOUNDS SHOWING A CIS-ARRANGEMENT OF AN OLEFIN AND A HYDROCARBYL GROUP: EVIDENCES OF A SIGNIFICANT P-BACKDONATION IN THE METAL-OLEFIN BOND
No full textStability and reactivity of the cis-{PtIIR(alkyne)} fragment (R= alkyl): an unprecedented rearrangement to form the {PtII(allyl)} moiety
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