86,530 research outputs found
Armed Forces and the International Court of Justice: The Relevance of International Humanitarian law and Human Rights Law to the Conduct of Military Operations
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Measuring agreement between judgements in the ophthalmoscopic evaluation in mild-moderate hypertension
No full textVariations on the Author
No full text“Variations on the Author” discusses two of Eduardo Coutinho’s recent films (Um Dia na Vida, from 2010, and Últimas Conversas, posthumously released in 2015) and their contribution to the general question of documentary authorship. The director’s filmography is characterized by a consistent yet self-effacing form of authorial self-inscription: Coutinho often features as an interviewer that rather than express opinions propels discourses; an interviewer that is good at listening. This mode of self-inscription characterizes him as an author who is not expressive but who is nonetheless markedly present on the screen. In Um Dia na Vida, however, Coutinho is completely absent form the image, while Últimas Conversas, on the contrary, includes a confessional prologue that moves the director from the margins to the center of his films. This article examines the ways in which these works stand out in the filmography of a director who offers new insights into the notion of cinematic authorship
Chemistry of some model compounds related to fluorinated polymers
No full textThe work described in this thesis is concerned with three areas which are the generation of stable carbocations from saturated model compounds related to poly- vinylidenefluoride, the development of synthetic routes to fluoro-organo-phosphazenes with intention of obtaining some potential additives for perfluoropolyether fluids operating at elevated temperatures, and pericyclic reactions involving fluorinated olefins.1. We reported that some remarkable conjugated cations, and di-cations (4a) are obtained by reaction of hydrofluorocarbon precursors (4) with an excess of antimony pentafluoride. Cations (4a) bear the fluorine atoms at the charged sites, which of course, leads to stabilisation of the systems We investigated the effect of both re-hybridisation and charge on (^13)C, (^19)F, (^1)H n.m.r. chemical shifts and we applied the empirical criterion of (^13)C chemical shifts additivity to these systems to confirm the structure of some carbo-mono-cations and.-di- cations.2. The mechanism of displacement reactions in halophosphazenes was rationalised by reacting the systems in study with selected nucleophiles in competition reactions. Some fluoro-organo-phosphazenes were synthesised using halophosphazenes as starting materials. Different methodologies were used and their effectiveness was limited by the reactivity of the halophosphazenes towards the fluoroalkylating agents. The methodologies used include nucleophilic displacement of the halogen with fluorinated alcohols (R(_F)CH(_2)OH), and perfluoroalkylating agents (eg.: CF(_3)SiMe(_3)); perfluoroalkylation of organo-phosphazene using hexafluoropropene under gamma ray irradiation. Potential stabilising agents for perfluoropolyether fluids were synthesised and their effectiveness was tested.3. Some pericyclic reactions of heptafluorobut-2-ene and hexafluorobut-2-ene with dienes have been studied in an attempt to synthesise a series of benzenoid and heteroaromatic compounds containing two trifluoromethyl groups in high yields
[Newspaper Clipping: Author Claims Evidence of Second JFK Assassin #1]
No full textNewspaper article titled "Author Claims Evidence of Second JFK Assassin." The article states that author Richard J. Whalen concluded "that there is circumstantial evidence to support the theory of a second assassin in the shooting of President John F. Kennedy.
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