1,720,966 research outputs found
REACTIVITY OF HYDROXO, HYDROPEROXO AND PEROXO PLATINUM(II) DERIVATIVES TOWARDS CARBON OXIDES
No full textThe reaction of the complexes Pt(PPh3)2(OOH)X (HX=succinimide (I), phthalimide (II), PhOH (III), ρ{variant}-MeC6H4OH (IV)) and Pt(PPh3)2(OH)X (HX= succinimide (V), phthalimide (VI)) with CO and CO2 have been studied. In order to clarify some reaction pathways, the reactivity of Pt[O2C(O)O](PPh3)2 (VII) and of Pt[O2CMe2O](PPh3)2 (VIII) with succinimide and phthalimide has also been investigated. 17O NMR and IR spectra of some of these compounds and of Pt[OC(O)O](PPh3)2 (IX) have been recorded
Going Beyond Counting First Authors in Author Co-citation Analysis
Get PDFThe present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation
counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings
are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that
only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into
account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed
Substituent Effect on One-Bond 13C-13C NMR Coupling Constants between the Carbonyl Carbon and C1 in Methyl Benzoates. Is there a Dependence on Pi greca-Bond-Order Changes?
No full text17O vs 13C NMR Chemical Shifts as Effective Indicators of p-Electron-Density Distribution in Hindered Methyl Benzoates
No full textSubstituent effects on one-bond 13C-13C NMR coupling constants between the carbonyl carbon and C1 in methyl benzoates. Is there a dependence on pi-bond-order changes?
No full text17O vs 13C NMR chemical shifts as effective indicators of π-electron-density distribution in hindered methyl benzoates
No full text17O NMR Substituent Chemical Shift (SCS) values on the carbonyl and methoxy oxygens in methyl 2,6-dimethyl-4-X-benzoates 2’ have been measured in acetonitrile-d and compared with those of the 2,6-unsubstituted methyl 4-X-benzoates 2, the former exhibiting very little sensitivity to the effect of 4-substituents and not appearing to be related to π-electron density changes in such sterically hindered systems.
Conversely 13C NMR SCS values of the methoxy carbon of the ester function in either 2 and 2’, although modest in size, exhibit a very good dual substituent parameter (DSP) correlation with the polar and resonance effect of 4-substituents and are therefore effective indicators of local π electron densities.
Moreover, 13C NMR SCS values of the methoxy carbon of 2’ exhibit an excellent linear correlation with those of 2,6-unsubstituted benzoates 2. Once more this agrees with our previous conclusion that the resonance interaction between the aromatic ring and the ester group is essentially related to a π-polarization effect, not involving charge-transfer between the two moieties and therefore not sensitive to steric hindrance to their coplanarity
Variations on the Author
Get PDF“Variations on the Author” discusses two of Eduardo Coutinho’s recent films (Um Dia na Vida, from 2010, and Últimas Conversas, posthumously released in 2015) and their contribution to the general question of documentary authorship. The director’s filmography is characterized by a consistent yet self-effacing form of authorial self-inscription: Coutinho often features as an interviewer that rather than express opinions propels discourses; an interviewer that is good at listening. This mode of self-inscription characterizes him as an author who is not expressive but who is nonetheless markedly present on the screen. In Um Dia na Vida, however, Coutinho is completely absent form the image, while Últimas Conversas, on the contrary, includes a confessional prologue that moves the director from the margins to the center of his films. This article examines the ways in which these works stand out in the filmography of a director who offers new insights into the notion of cinematic authorship
Appropriate Similarity Measures for Author Cocitation Analysis
Get PDFWe provide a number of new insights into the methodological discussion about author cocitation analysis. We first argue that the use of the Pearson correlation for measuring the similarity between authors’ cocitation profiles is not very satisfactory. We then discuss what kind of similarity measures may be used as an alternative to the Pearson correlation. We consider three similarity measures in particular. One is the well-known cosine. The other two similarity measures have not been used before in the bibliometric literature. Finally, we show by means of an example that our findings have a high practical relevance.information science;Pearson correlation;cosine;similarity measure;author cocitation analysis
Dispelling the Myths Behind First-author Citation Counts
Get PDFWe conducted a full-scale evaluative citation analysis study of scholars in the XML research field to explore just how different from each other author rankings resulting from different citation counting methods actually are, and to demonstrate the capability of emerging data and tools on the Web in supporting more realistic citation counting methods. Our results contest some common arguments for the continued
use of first-author citation counts in the evaluation of scholars, such as high correlations between author rankings by first-author citation counts and other citation
counting methods, and high costs of using more realistic citation counting methods that are not well-supported by the ISI databases. It is argued that increasingly available digital full text research papers make it possible for citation analysis studies to go beyond what the ISI databases have directly supported and to employ more
sophisticated methods
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