1,720,955 research outputs found
Self-assembly behaviour of hetero-nuclear Janus dumbbells
No full textWe investigate the fluid structure and self-assembly of a system of Janus dumbbells by means of aggregation-volume-bias Monte Carlo simulations and Simulated Annealing techniques. In our approach, Janus dumbbells model asymmetric colloidal particles constituted by two tangent (touching) spheres (labelled as h and s) of different sizes and interaction properties: specifically, the h spheres interact with all other spheres belonging to different dumbbells via hard-sphere potentials, whereas two s spheres interact via a square-well potential. By introducing a parameter α ∈ [0,2] that controls the size ratio between the h and s spheres, we are able to investigate the overall phase behaviour of Janus dumbbells as a function of α. In a previous paper (O'Toole et al., Soft Matter, 2017, 13, 803) we focused on the region where the s sphere is larger than the h sphere (α > 1), documenting the presence of a variety of phase behaviours. Here we investigate a different regime of size ratios, predominantly where the hard sphere is larger than (or comparable to) the attractive one. Under these conditions, we observe the onset of many different self-assembled super-structures. Depending on the specific value of α we document the presence of spherical clusters (micelles) progressively evolving into more exotic structures including platelets, filaments, networks and percolating fluids, sponge structures and lamellar phases. We find no evidence of a gas–liquid phase separation for α ≤ 1.1, since under these conditions it is pre-empted by the development of self-assembled phases
Phase-behaviour of Janus Dumbbell Liquids and Assemblies by Monte Carlo Techniques
Full text linkThis thesis summarises a theoretical investigation into the phase behaviour of model ‘Janus’ dumbbell systems composed of two tangent beads, one possessing a hard-core potential and the other a square-well. The relationship between shape and interaction anisotropy is explored via varying the particle properties over two orthogonal pathways. We elucidate the effects of varying interaction and shape anisotropy on the fluid properties of these particles. A parameter, α is developed to control the size ratio between the interaction sites. The model allows particles to be tuned over the full range of diameter ratios. Variegated phase behaviour is observed with varying α. Gas-liquid critical phenomena is observed, in general, for the more isotropic particle descriptions where the particle possesses an attractive tail. As the interaction profile becomes more anisotropic the system properties change drastically. Phase diagrams are computed via collation of gas-liquid phase separation data, calculated via Successive Umbrella Sampling with histogram re-weighting, along with Simulated Annealing simulations in the Canonical ensemble, both of which employ an implementation of the Aggregation-Volume-Bias Monte Carlo intra-box swap move algorithm. Self-assembled phases are observed to perturb gas-liquid critical phenomena, where the critical point becomes metastable to bilayer structures before the Janus limit (α = 1). Bilayer structures in this region are observed to tolerate significant curvature until the two interaction sites are equal in size (α = 1) where only flat lamellar structures are found. Where the attractive site is smaller than the repulsive site, the systems are observed to display up to seven structurally differentiable behaviours controlled by α and the state-point, including: a monomer gas, micelles, platelets, strips, strip networks, sponges, and lamellar structures. Arguments are developed to account for this variation from first principles
Going Beyond Counting First Authors in Author Co-citation Analysis
Full text linkThe present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation
counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings
are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that
only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into
account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed
Variations on the Author
Full text link“Variations on the Author” discusses two of Eduardo Coutinho’s recent films (Um Dia na Vida, from 2010, and Últimas Conversas, posthumously released in 2015) and their contribution to the general question of documentary authorship. The director’s filmography is characterized by a consistent yet self-effacing form of authorial self-inscription: Coutinho often features as an interviewer that rather than express opinions propels discourses; an interviewer that is good at listening. This mode of self-inscription characterizes him as an author who is not expressive but who is nonetheless markedly present on the screen. In Um Dia na Vida, however, Coutinho is completely absent form the image, while Últimas Conversas, on the contrary, includes a confessional prologue that moves the director from the margins to the center of his films. This article examines the ways in which these works stand out in the filmography of a director who offers new insights into the notion of cinematic authorship
Appropriate Similarity Measures for Author Cocitation Analysis
Full text linkWe provide a number of new insights into the methodological discussion about author cocitation analysis. We first argue that the use of the Pearson correlation for measuring the similarity between authors’ cocitation profiles is not very satisfactory. We then discuss what kind of similarity measures may be used as an alternative to the Pearson correlation. We consider three similarity measures in particular. One is the well-known cosine. The other two similarity measures have not been used before in the bibliometric literature. Finally, we show by means of an example that our findings have a high practical relevance.information science;Pearson correlation;cosine;similarity measure;author cocitation analysis
Dispelling the Myths Behind First-author Citation Counts
Full text linkWe conducted a full-scale evaluative citation analysis study of scholars in the XML research field to explore just how different from each other author rankings resulting from different citation counting methods actually are, and to demonstrate the capability of emerging data and tools on the Web in supporting more realistic citation counting methods. Our results contest some common arguments for the continued
use of first-author citation counts in the evaluation of scholars, such as high correlations between author rankings by first-author citation counts and other citation
counting methods, and high costs of using more realistic citation counting methods that are not well-supported by the ISI databases. It is argued that increasingly available digital full text research papers make it possible for citation analysis studies to go beyond what the ISI databases have directly supported and to employ more
sophisticated methods
koamabayili/VECTRON-author-checklist: VECTRON author checklist
No full textWe have done our best to complete the author checklist relating to the use of animals in the hut study. Note that the objective for the hut study was to evaluate the IRS treatment applications for residual efficacy against Anopheles mosquitoes, including the local An. coluzzii mosquito population. Cows were only used to attract mosquitoes into the huts and no tests were carried out directly on the cows. The author checklist is intended for use with studies where experiments are carried out on animals, which is why we have had such difficulty in completing this for the hut study, as many of the questions do not relate to how the cows were used
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