1,720,956 research outputs found
Mechanical behaviour and diffusion of gas during neutron irradiation of actinides in ceramic inert matrices
No full textFission of actinides from nuclear waste in inert matrices (materials without uranium) can reduce the period in time that nuclear waste is more radiotoxic than uranium ore that is the rock from which ordinary reactor fuel is made. A pioneering study is performed with the inert matrices: MgO, MgAl2O4, Y3Al5O12, Y2O3 and CeO2-x. These inert matrices contain inclusions of actinide-oxides with a diameter of about 200 μm. UO2 is used as a phase of actinides to simulate the implantation of fission products in inert matrix fuels. After neutron irradiation, inter-particle fracture was present in fuels with matrices that do not form a solid solution with UO2. These cracks are caused by swelling of the actinide phase and insufficient creep of the matrix. The diffusion length of fission gases is significantly reduced by inter-particle fracture and thereby fission gas releases till 50% were measured. This inter-particle fracture may be prevented when inert matrix fuels are fabricated with porous actinide inclusions embedded in inert matrices that are polluted by actinides. The amount of helium generated during neutron irradiation of a few actinides from nuclear waste can be far larger than the amount of fission gases. Parameters and diffusion mechanisms to simulate diffusion of helium in MgAl2O4 were derived by thermal evolution of He concentration profiles, atomistic calculations and numerical analysis using original definitions of diffusion coefficients for inert gas in materials with defects for single crystal as well as polycrystal media. This study shows that, amongst others, the material degradation of MgAl2O4, caused by the generated amount of defects and He during irradiation conditions, is acceptable. But the pioneering study with UO2 as a phase of actinides, shows that the solid state swelling by fission products in MgAl2O4 is about ten times larger than this swelling in 238UO2 that is the matrix in fuel for commercial reactors. The commercial feasibility of reduction of actinides from nuclear waste, by neutron irradiation in inert matrices, requires more research.Interfaculty Reactor Institut
Kinetics of selenite interactions with Boom Clay: adsorption-reduction interplay
Get PDFX-ray diffractograms of separated clay-size, silt-size and total Boom Clay material are available as supplementary information. Also provided are: particle size distributions of all materials, extra information on XANES and EXAFS results, and Se concentrations through time for experiments with standard clay minerals and figures of the sensitivity analysis of the kinetic model
Transport of Ions Through Clays of the Peize and Waalre Formation
No full textHigh-level waste can be radiotoxic for thousands of years and should be carefully handled to prevent accidents. The research for geological disposal of radioactive waste focuses on the construction and durability of a geologic disposal facility in Dutch clays or salts. One of the challenges is assessing these host rocks’ capability to retard radionuclides and prevent them from entering the biosphere. This research focuses on disposal in clay. Because of clay’s low permeability, water movements are slow, and radionuclides transport is expected to occur predominantly by diffusion. The Peize and Waalre formations, situated on the interface between brackish and salt groundwater, serve as a natural analogue for targeted deeper, poorly indurated host rocks. The known disparity in chlorine levels between the aquifers adjacent to these clays qualify these formations for NaCl-tracer research. A cutting sampling study determined the conductivity of these clays’ porewater. Combining this with a one-dimensional modelling study, the saline history of this formation has been simulated. NaCl gradients were demonstrated at different drilling locations. The most manifested gradient is attempted to fit in the one-dimensional model. The model results suggest that this gradient originates from adjacent aquifer salinity, the clays’ physical properties and the difference in hydraulic head. The observed salinity discrepancy between aquifers and ion concentration gradient in the firstWaalre Clay confirm the assumption that the member can be a natural analogue. Uncertainty on the continuity of the total system prohibits concluding that diffusion-dominated transport in Dutch poorly indurated clays can be assumed. The best fitting scenario this research found fitting the empirical Waalre clay salinity curve is combined transport by diffusion and advection. The finding of diffusion-advection transport implies that the Waalre clay shows more complexity than initially expected.Applied Earth Science
Going Beyond Counting First Authors in Author Co-citation Analysis
Get PDFThe present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation
counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings
are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that
only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into
account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed
Variations on the Author
Get PDF“Variations on the Author” discusses two of Eduardo Coutinho’s recent films (Um Dia na Vida, from 2010, and Últimas Conversas, posthumously released in 2015) and their contribution to the general question of documentary authorship. The director’s filmography is characterized by a consistent yet self-effacing form of authorial self-inscription: Coutinho often features as an interviewer that rather than express opinions propels discourses; an interviewer that is good at listening. This mode of self-inscription characterizes him as an author who is not expressive but who is nonetheless markedly present on the screen. In Um Dia na Vida, however, Coutinho is completely absent form the image, while Últimas Conversas, on the contrary, includes a confessional prologue that moves the director from the margins to the center of his films. This article examines the ways in which these works stand out in the filmography of a director who offers new insights into the notion of cinematic authorship
Appropriate Similarity Measures for Author Cocitation Analysis
Get PDFWe provide a number of new insights into the methodological discussion about author cocitation analysis. We first argue that the use of the Pearson correlation for measuring the similarity between authors’ cocitation profiles is not very satisfactory. We then discuss what kind of similarity measures may be used as an alternative to the Pearson correlation. We consider three similarity measures in particular. One is the well-known cosine. The other two similarity measures have not been used before in the bibliometric literature. Finally, we show by means of an example that our findings have a high practical relevance.information science;Pearson correlation;cosine;similarity measure;author cocitation analysis
Dispelling the Myths Behind First-author Citation Counts
Get PDFWe conducted a full-scale evaluative citation analysis study of scholars in the XML research field to explore just how different from each other author rankings resulting from different citation counting methods actually are, and to demonstrate the capability of emerging data and tools on the Web in supporting more realistic citation counting methods. Our results contest some common arguments for the continued
use of first-author citation counts in the evaluation of scholars, such as high correlations between author rankings by first-author citation counts and other citation
counting methods, and high costs of using more realistic citation counting methods that are not well-supported by the ISI databases. It is argued that increasingly available digital full text research papers make it possible for citation analysis studies to go beyond what the ISI databases have directly supported and to employ more
sophisticated methods
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