1,721,041 research outputs found
La perequazione regionale
Il lavoro illustra criticamente il meccanismo di finanziamento e perequazione previsto per le Regioni dalla legge delega sul federalsimo fiscale di recente approvata in Italia. Il lavoro fa parte di una raccolta di contributi che costitusce il primo commento organico fin qui pubblicato sulla riforma del federalismo fiscale
Synthesis of C-glycosyl Compounds by the Wittig-Iodocyclization Procedure. Differences from Mercuriocyclization.
A novel case of 1,3-asymmetric induction in rhodium-catalyzed hydroformylation of an allylic double bond using perbenzylated C-glucosides as chiral directors,
1-(20,30,40,60-Tetra-O-benzyl-a-D-glucopyranosyl)-2-propene 1a and 1-(20,30,40,60-tetra-O-benzyl-b-D-glucopyranosyl)-2-
propene 1b were hydroformylated at different temperatures affording linear and branched aldehydes in either a 1:1 or 2:1 regioisomeric
ratio, depending on the stereochemistryof the starting substrate. The diastereoisomeric ratio of the branched isomer depended
on the reaction temperature as well as the alkene structure, the highest value (85:15) being obtained in the case of hydroformylation
of the a-isomer at 0 °C
Facile Conversion of 2,3,4,5-Tetra-O-benzyl-D-glucopyranose into 1,3,4,5-Tetra-O-benzyl-L-sorbopyranose.
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