1,720,968 research outputs found

    Flash Photolysis Study of 3-Methylisoxazolo[5,4-b]pyridine

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    The photoreactivity of the title compound has been examined in MeOH, PriOH, MeCN, and MeCN/as-dimethylhydrazine solutions. A ketenimine and a spiroazirine intermediate account for the final products as well as for the transients observed in the flash photolysis experiments. It is also found that acid catalysis plays an important role in the reaction of spiroazirine to oxazolopyridine. © 1990 American Chemical Society

    Energy pooling collision cross-section measurements in Indium: the In(6S1/2) + In(6S1/2) In(n P) + In(5P3/2) process

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    The quantitative investigation of the energy pooling collision (EPC) process between resonantly laser excited In atoms is reported. The process is studied in a laser induced fluorescence (LIF) experiment where the nP populations, with n=11, 10 and 9, are monitored. The population mechanism for these levels is verified via a temporal analysis of the fluorescence signals. This is possible in In due to the strongly reduced self trapping of the resonant radiation. The cross section for energy pooling collision to these nP levels has been derived by considering the Rydberg character of these levels

    Going Beyond Counting First Authors in Author Co-citation Analysis

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    The present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed

    Variations on the Author

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    “Variations on the Author” discusses two of Eduardo Coutinho’s recent films (Um Dia na Vida, from 2010, and Últimas Conversas, posthumously released in 2015) and their contribution to the general question of documentary authorship. The director’s filmography is characterized by a consistent yet self-effacing form of authorial self-inscription: Coutinho often features as an interviewer that rather than express opinions propels discourses; an interviewer that is good at listening. This mode of self-inscription characterizes him as an author who is not expressive but who is nonetheless markedly present on the screen. In Um Dia na Vida, however, Coutinho is completely absent form the image, while Últimas Conversas, on the contrary, includes a confessional prologue that moves the director from the margins to the center of his films. This article examines the ways in which these works stand out in the filmography of a director who offers new insights into the notion of cinematic authorship

    An efficient photo-atom source

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    We show that it is possible to obtain a very efficient photo-atom source, whose atom flux is regulated by light. The atom release is due to the recently observed light-induced atom desorption effect from silane coated cells. We report the results obtained at room temperature with rubidium in a double body cell coated with (poly)dimethyl-siloxane. This kind of photo-atom source can be immediately extended to other alkali atoms, namely sodium, potassium and cesium. Possible applications are discussed

    Appropriate Similarity Measures for Author Cocitation Analysis

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    We provide a number of new insights into the methodological discussion about author cocitation analysis. We first argue that the use of the Pearson correlation for measuring the similarity between authors’ cocitation profiles is not very satisfactory. We then discuss what kind of similarity measures may be used as an alternative to the Pearson correlation. We consider three similarity measures in particular. One is the well-known cosine. The other two similarity measures have not been used before in the bibliometric literature. Finally, we show by means of an example that our findings have a high practical relevance.information science;Pearson correlation;cosine;similarity measure;author cocitation analysis

    Dispelling the Myths Behind First-author Citation Counts

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    We conducted a full-scale evaluative citation analysis study of scholars in the XML research field to explore just how different from each other author rankings resulting from different citation counting methods actually are, and to demonstrate the capability of emerging data and tools on the Web in supporting more realistic citation counting methods. Our results contest some common arguments for the continued use of first-author citation counts in the evaluation of scholars, such as high correlations between author rankings by first-author citation counts and other citation counting methods, and high costs of using more realistic citation counting methods that are not well-supported by the ISI databases. It is argued that increasingly available digital full text research papers make it possible for citation analysis studies to go beyond what the ISI databases have directly supported and to employ more sophisticated methods

    Author Index

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