1,720,956 research outputs found
Computational studies of complex fluid phases and polymeric membranes based on ionic liquid crystals
Full text linkThe study of complex fluid phases is pursued with the aid of computer simulations. Starting from n-alkanes and ending on polymeric matrix the microscopical quantities are evaluated and compared to the experimental evidences by mean of different approaches. The targets of this work are membranes based on ionic liquid crystals which are employed in the production of clean water from seawater
The structuring effect of the alkyl domains on the polar network of ionic liquid mixtures: a molecular dynamics study
Full text linkBy using molecular dynamics simulations, we investigate the structural and dynamic properties of mixtures of 1,3-dimethylimidazolium bis(trifluoromethanesulfonyl)imide, [C(1)C(1)im][Tf2N] and 1-dodecyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide, [C(12)C(1)im][Tf2N] (also C-1 and C-12 in short). Such mixtures feature an imidazolium bistriflimide salt with a very short alkyl chain, not giving rise to any nano-segregation as a pure component, with another one with a longer alkyl chain that exhibits a substantial nano-segregation as a pure liquid. As the mole fraction of the long-chain component C-12 is increased, the so-called pre-peak of the structure factor S(q), occurring in the region 1-3 nm(-1), shows a shift to higher values of the wavevector q, mirroring a decrease of the corresponding correlation length. Moreover, the intensity of the pre-peak strongly increases with the C-12 concentration. These results are in very good agreement with experimental X-ray scattering data in the literature. On the other hand, the diffusion of the ions is found to exhibit a simple behaviour consistent with the increased viscosity of the mixture, and these results are also in good agreement with NMR experimental data from the literature. The simulation results are rationalized as caused by a structuring effect, similar to the hydrophobic effect, of the alkyl domains of the C-12 component dissolved in the "solvent" represented by the C-1 cation, the Tf2N- anion and the C-12 cation head. In short, the exclusion of the alkyl chains from the polar network, a process mostly governed by electrostatic interactions, favours the formation of hydrophobic domains, which in turn exert a structuring effect on the ions of the polar domains, favouring a stronger ionic interaction. This is finally reflected in a shorter correlation length and a higher intensity of the pre-peak of the structure factor S(q) as the C-12 mole fraction is increased. At variance with the microscopic structure, the diffusion of all three types of ions is not strongly influenced by the nano-segregation and is essentially dependent on the viscosity of the mixture
Going Beyond Counting First Authors in Author Co-citation Analysis
Full text linkThe present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation
counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings
are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that
only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into
account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed
Variations on the Author
Full text link“Variations on the Author” discusses two of Eduardo Coutinho’s recent films (Um Dia na Vida, from 2010, and Últimas Conversas, posthumously released in 2015) and their contribution to the general question of documentary authorship. The director’s filmography is characterized by a consistent yet self-effacing form of authorial self-inscription: Coutinho often features as an interviewer that rather than express opinions propels discourses; an interviewer that is good at listening. This mode of self-inscription characterizes him as an author who is not expressive but who is nonetheless markedly present on the screen. In Um Dia na Vida, however, Coutinho is completely absent form the image, while Últimas Conversas, on the contrary, includes a confessional prologue that moves the director from the margins to the center of his films. This article examines the ways in which these works stand out in the filmography of a director who offers new insights into the notion of cinematic authorship
Appropriate Similarity Measures for Author Cocitation Analysis
Full text linkWe provide a number of new insights into the methodological discussion about author cocitation analysis. We first argue that the use of the Pearson correlation for measuring the similarity between authors’ cocitation profiles is not very satisfactory. We then discuss what kind of similarity measures may be used as an alternative to the Pearson correlation. We consider three similarity measures in particular. One is the well-known cosine. The other two similarity measures have not been used before in the bibliometric literature. Finally, we show by means of an example that our findings have a high practical relevance.information science;Pearson correlation;cosine;similarity measure;author cocitation analysis
Dispelling the Myths Behind First-author Citation Counts
Full text linkWe conducted a full-scale evaluative citation analysis study of scholars in the XML research field to explore just how different from each other author rankings resulting from different citation counting methods actually are, and to demonstrate the capability of emerging data and tools on the Web in supporting more realistic citation counting methods. Our results contest some common arguments for the continued
use of first-author citation counts in the evaluation of scholars, such as high correlations between author rankings by first-author citation counts and other citation
counting methods, and high costs of using more realistic citation counting methods that are not well-supported by the ISI databases. It is argued that increasingly available digital full text research papers make it possible for citation analysis studies to go beyond what the ISI databases have directly supported and to employ more
sophisticated methods
koamabayili/VECTRON-author-checklist: VECTRON author checklist
No full textWe have done our best to complete the author checklist relating to the use of animals in the hut study. Note that the objective for the hut study was to evaluate the IRS treatment applications for residual efficacy against Anopheles mosquitoes, including the local An. coluzzii mosquito population. Cows were only used to attract mosquitoes into the huts and no tests were carried out directly on the cows. The author checklist is intended for use with studies where experiments are carried out on animals, which is why we have had such difficulty in completing this for the hut study, as many of the questions do not relate to how the cows were used
Author-wise bibliometric analysis based on entropy.
No full textAuthor-wise bibliometric analysis based on entropy.</p
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