1,720,979 research outputs found

    Elemental partitioning and site-occupancy in γ/γ′ forming Co–Ti–Mo and Co–Ti–Cr alloys

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    We report on the sub-nanometer scale characterization of Co-12Ti-4Mo and Co-12Ti-4Cr (at.%) model alloys. Atom probe tomography reveals that Co and Cr partition to gamma, whereas Ti and Mo to gamma'. Additions of Mo and Cr to the reference Co-12Ti system lead to strong increases in gamma' volume fraction by about 25% and 12%, respectively. Element-specific spatial distribution maps along the [001] direction of the L1(2)-ordered gamma' phase reveal that both Mo and Cr preferentially replace Ti on its sublattice. The remaining excess Ti is available for formation of additional gamma', resulting in enhanced gamma' volume fractions. (C) 2018 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

    Going Beyond Counting First Authors in Author Co-citation Analysis

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    The present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed

    Variations on the Author

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    “Variations on the Author” discusses two of Eduardo Coutinho’s recent films (Um Dia na Vida, from 2010, and Últimas Conversas, posthumously released in 2015) and their contribution to the general question of documentary authorship. The director’s filmography is characterized by a consistent yet self-effacing form of authorial self-inscription: Coutinho often features as an interviewer that rather than express opinions propels discourses; an interviewer that is good at listening. This mode of self-inscription characterizes him as an author who is not expressive but who is nonetheless markedly present on the screen. In Um Dia na Vida, however, Coutinho is completely absent form the image, while Últimas Conversas, on the contrary, includes a confessional prologue that moves the director from the margins to the center of his films. This article examines the ways in which these works stand out in the filmography of a director who offers new insights into the notion of cinematic authorship

    Appropriate Similarity Measures for Author Cocitation Analysis

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    We provide a number of new insights into the methodological discussion about author cocitation analysis. We first argue that the use of the Pearson correlation for measuring the similarity between authors’ cocitation profiles is not very satisfactory. We then discuss what kind of similarity measures may be used as an alternative to the Pearson correlation. We consider three similarity measures in particular. One is the well-known cosine. The other two similarity measures have not been used before in the bibliometric literature. Finally, we show by means of an example that our findings have a high practical relevance.information science;Pearson correlation;cosine;similarity measure;author cocitation analysis

    Improvement of High Temperature Strength of Al and Co Alloy by L12 Type Coherent Precipitates

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    The present work aims at developing a new class of high temperature alloys based on ordered intermetallic compound that forms coherently with the matrix during solid state transformation. The chosen intermetallics have L12 ordered structure, which is a derivative of fcc unit cell. Most popular example of this fcc derivative is Ni3Al that is critical in developing high strength at high temperatures (~900°C) in commercially successful Ni based superalloys. Similar ordered structures form either in stable or metastable form can act as a main strengthening constituent in Al and Co matrices. For example Al3Sc, Al3Zr, Al3Hf can be dispersed in fcc Al matrix that are stable at temperatures ~ 400°C due to very low diffusivity of transition metals (Sc, Zr, Hf etc.) in the matrix. However, due to low solid solubility of these transition metals, the obtained volume fraction of these precipitates in the matrix is not sufficient to provide adequate room temperature strength. In fcc Co matrix, stable Co3Ti phase with L12 ordered structure forms with cuboidal morphology. However, besides having lower melting point, the precipitates have large misfit that lowers thermal stability at high temperatures. Recently, addition of Al and W with a proper ratio in Co is reported to lead the formation of metastable Co3(Al,W) L12 ordered phase in fcc α-Co matrix. This provides significant strength at high temperatures (~ 900°C). The main drawback for these alloys is their high densities (9.6 to 10.5 gm.cm-3) due to the requirement of compulsory addition of W (~ 15 to 25 wt%) for stabilising the ordered phase. In the present work, these problems are overcome leading to the development of new class of Al and Co alloys. The thesis is organized in three parts. In the first part, the principles of strengthening that can be optimized to develop newer high temperature high strength alloys are reviewed. The ordered L12 structure, which is the mainstay of the current effort of new alloy development, is elaborated. In the second part we present the results of our effort to the development a new class of high strength high temperature Al alloys. A new approach has been adopted to get a microstructure that contains both high temperature stable and room temperature strengthening precipitates. This has been illustrated by two Al rich compositions, Al-2Cu-0.1Nb-0.15Zr and Al-2Cu-0.1Hf-0.15Zr (at% unless stated otherwise). Addition of Nb/Zr or Hf/Zr in Al alloys leads to the formation of high temperature stable L12 ordered spherical coherent precipitates in the fcc Al matrix. Cu addition gives room temperature strengthening θ’ and θ” precipitates. The arc melted alloys were chill cast (suction cast) in the form of 3 mm rods followed by a novel three stage heat treatment process, as shown below. In the case of Al-2Cu-0.1Nb-0.15Zr alloy, the chill cast structure consists of Cu rich phase at the boundaries along the α-Al dendrites while Zr and Nb partition inside the α-Al dendrites. Aging at 400°C leads to an increase in the hardness of the cast alloy due to the precipitation of coherent L12 ordered Al3(Zr,Nb) spherical precipitates (~5nm) in the α-Al dendrites. Zr strongly partitions to the L12 ordered precipitate relative to the matrix. Nb exhibits weak partitioning in the precipitate. Further solutionising was optimized at 535°C for 30 minutes such that the segregation of Cu in the chill cast samples can be eliminated. The WDS mapping shows that Cu dissolved uniformly in the α-matrix while the Zr/Nb enriched α-Al dendrites are still present. The L12 ordered precipitates are mostly found in these Zr/Nb enriched dendrites formed during solidification. The precipitates sizes are finer (~5 nm) in dendrites and larger in the interdendritic region. The Nb partitioning increases in the ordered L12 precipitates relative to the matrix after solutionising. On aging at 190°C, fine θ” precipitates nucleate on prior Al3(Zr,Nb) precipitates present in α-Al dendrites while the interdendritic regions contain coarser θ’ nucleated on larger size L12 precipitates. The θ”/θ’ are much finer and higher in number density for the quaternary alloy compared to binary Al-2Cu alloy subjected to conventional heat treatment. The quaternary alloy show higher peak hardness of 1500 ± 8 MPa after 5 hours of aging at 190°C compared to binary Al-2Cu alloy with peak hardness of 1260 ± 11 MPa

    Dispelling the Myths Behind First-author Citation Counts

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    We conducted a full-scale evaluative citation analysis study of scholars in the XML research field to explore just how different from each other author rankings resulting from different citation counting methods actually are, and to demonstrate the capability of emerging data and tools on the Web in supporting more realistic citation counting methods. Our results contest some common arguments for the continued use of first-author citation counts in the evaluation of scholars, such as high correlations between author rankings by first-author citation counts and other citation counting methods, and high costs of using more realistic citation counting methods that are not well-supported by the ISI databases. It is argued that increasingly available digital full text research papers make it possible for citation analysis studies to go beyond what the ISI databases have directly supported and to employ more sophisticated methods

    Author Index

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