1,720,961 research outputs found
Liquid crystals : order, symmetry and dynamics
No full textEThOS - Electronic Theses Online ServiceGBUnited Kingdo
Poly(propyleneimine) liquid crystal codendrimers bearing laterally and terminally attached promesogenic groups
No full textThe synthesis, chemical characterization, and liquid crystalline behavior of two new series of poly(propyleneimine) (DAB) codendrimers are described. Both series were obtained by grafting onto the fourth-generation dendrimer (DAB-(NH2)(32)) various proportions of two types of promesogenic units: one of them laterally attached and the other terminally attached. Both series differ in the terminally attached promesogenic unit, being chiral in series 1 and achiral in series 2. X-ray diffraction studies show that these compounds exhibit nematic or lamellar mesophases. For intermediate proportions, the smectic C mesophase, which was not exhibited by the homodendrimers, appears. Thus, the evolution between a nematic and an orthogonal lamellar mesophase occurs through a tilted mesophase. The chiral centers in series I permit the appearance of chiral nematic (N*) and chiral smectic C (SmC*) mesophases, which are studied. Deuterium NMR experiments reveal that the nematic formed by one codendrimer is uniaxial and not the anticipated biaxial nematic
End-on and side-on nematic liquid crystal dendrimers
No full textA group of nematic materials based on poly(propyleneimine) dendrimers (PPI) containing two types of mesogenic subunits were synthesized. The presence of different types of mesogenic group, the topology of the attachment to the core (end-on and side-on), and the chemical nature of the linking connection to the PPI scaffold (imine or amide) were used to tailor the mesomorphic properties. The materials were characterized by a variety of techniques including H-1, C-13 NMR spectroscopy, GPC, MALDI-TOF MS, DSC, POM, and X-ray diffraction. The crystalline state, when it exists, was found to be suppressed for most of the materials once they had undergone the first transition to the isotropic phase. The majority of the compounds exhibited glass transitions near to or lower than room temperature and an accompanying wide temperature range mesophase. All of the side-on dendrimers synthesized exhibit a nematic mesophase whereas end-on dendrimers exhibit different mesophases depending on the length of the terminal chain of the mesogenic unit (nematic for n = 2, 4, 5). The H-2 NMR technique was used to investigate the symmetry of the nematic phase formed by the side-on dendrimers (G = 3). These studies revealed that the symmetry of the nematic phase is uniaxial. They also allow the investigation of the orientational order of the phase and the rate of field-induced director alignment
Going Beyond Counting First Authors in Author Co-citation Analysis
Full text linkThe present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation
counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings
are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that
only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into
account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed
Variations on the Author
Full text link“Variations on the Author” discusses two of Eduardo Coutinho’s recent films (Um Dia na Vida, from 2010, and Últimas Conversas, posthumously released in 2015) and their contribution to the general question of documentary authorship. The director’s filmography is characterized by a consistent yet self-effacing form of authorial self-inscription: Coutinho often features as an interviewer that rather than express opinions propels discourses; an interviewer that is good at listening. This mode of self-inscription characterizes him as an author who is not expressive but who is nonetheless markedly present on the screen. In Um Dia na Vida, however, Coutinho is completely absent form the image, while Últimas Conversas, on the contrary, includes a confessional prologue that moves the director from the margins to the center of his films. This article examines the ways in which these works stand out in the filmography of a director who offers new insights into the notion of cinematic authorship
Appropriate Similarity Measures for Author Cocitation Analysis
Full text linkWe provide a number of new insights into the methodological discussion about author cocitation analysis. We first argue that the use of the Pearson correlation for measuring the similarity between authors’ cocitation profiles is not very satisfactory. We then discuss what kind of similarity measures may be used as an alternative to the Pearson correlation. We consider three similarity measures in particular. One is the well-known cosine. The other two similarity measures have not been used before in the bibliometric literature. Finally, we show by means of an example that our findings have a high practical relevance.information science;Pearson correlation;cosine;similarity measure;author cocitation analysis
Dispelling the Myths Behind First-author Citation Counts
Full text linkWe conducted a full-scale evaluative citation analysis study of scholars in the XML research field to explore just how different from each other author rankings resulting from different citation counting methods actually are, and to demonstrate the capability of emerging data and tools on the Web in supporting more realistic citation counting methods. Our results contest some common arguments for the continued
use of first-author citation counts in the evaluation of scholars, such as high correlations between author rankings by first-author citation counts and other citation
counting methods, and high costs of using more realistic citation counting methods that are not well-supported by the ISI databases. It is argued that increasingly available digital full text research papers make it possible for citation analysis studies to go beyond what the ISI databases have directly supported and to employ more
sophisticated methods
koamabayili/VECTRON-author-checklist: VECTRON author checklist
No full textWe have done our best to complete the author checklist relating to the use of animals in the hut study. Note that the objective for the hut study was to evaluate the IRS treatment applications for residual efficacy against Anopheles mosquitoes, including the local An. coluzzii mosquito population. Cows were only used to attract mosquitoes into the huts and no tests were carried out directly on the cows. The author checklist is intended for use with studies where experiments are carried out on animals, which is why we have had such difficulty in completing this for the hut study, as many of the questions do not relate to how the cows were used
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