14 research outputs found
Badania nad strategiami zrównoważonego rozwoju dla kultury ludowej na obszarach wiejskich Chin: w oparciu o perspektywę doświadczania
No full textThis study explores sustainable development strategies for folk culture in rural China from the experiencing perspective, aiming to propose practical and context-specific pathways tailored to China's unique conditions. Rooted in rural communities, folk culture represents a significant component of Chinese cultural heritage and holds unique value across social, economic, and environmental dimensions, serving as a vital cultural resource for rural revitalization. However, as urban modernization progresses, folk culture faces challenges in transmission and innovation. By integrating the experiencing perspective with the inheritance and innovation of folk culture, and leveraging the rural revitalization strategy, this research examines sustainable development strategies and proposes multidimensional implementation pathways. These strategies include policy support, educational outreach, digital technology application, and integration with modern industries, promoting the continued transmission and development of folk culture in contemporary society.Niniejsze badanie analizuje strategie zrównoważonego rozwoju kultury ludowej na obszarach wiejskich Chin z perspektywy doświadczania, dążąc do zaproponowania praktycznych i kontekstowych ścieżek dostosowanych do unikalnych warunków Chin. Zakorzeniona w społecznościach wiejskich, kultura ludowa stanowi istotny element chińskiego dziedzictwa kulturowego i posiada wyjątkową wartość w wymiarze społecznym, ekonomicznym i środowiskowym, stanowiąc istotny zasób kulturowy dla rewitalizacji obszarów wiejskich. Jednak wraz z postępem modernizacji miast, kultura ludowa staje przed wyzwaniami w zakresie transmisji i innowacji. Integrując perspektywę doświadczenia z dziedzictwem i innowacyjnością kultury ludowej oraz wykorzystując strategię rewitalizacji obszarów wiejskich, niniejsze badanie analizuje strategie zrównoważonego rozwoju i proponuje wielowymiarowe ścieżki wdrażania. Strategie te obejmują wsparcie polityczne, działania edukacyjne, zastosowanie technologii cyfrowych oraz integrację z nowoczesnymi gałęziami przemysłu, promując ciągłą transmisję i rozwój kultury ludowej we współczesnym społeczeństwie
Effects of Cu2O morphology on the performance of CO self-sustained catalytic combustion
No full textSelf-sustained catalytic combustion is a sustainable approach to deal with exhaust gas with high concentration CO, and revealing its reaction process is necessary and challenging. Herein, cube (Cu2O-C), octahedron (Cu2O-O) and dodecahedron (Cu2O-D) exposing different crystal planes were used to explore the catalytic combustion mechanism. The catalytic combustion can be self-sustained on the Cu2O surface and the activities decrease in the order of Cu2O-O > Cu2O-D > Cu2O-C, contributing to the different exposing planes with (1 1 1), (1 1 0) and (1 0 0), respectively. In-situ DRIFTS results prove that the catalytic combustion of CO to CO2 on Cu2O is prone to follow the MvK mechanism. Comparing with Cu2O-D and Cu2O-C, the relatively open surface of Cu2O-O plane composed of unsaturated copper and oxygen atoms facilitates the CO adsorption on Cu (I) and the mobility of lattice oxygen, leading to the highest low temperature reducibility and catalytic activity
Study on the Dip Angle Effect of Asymmetric Deformation and Failure of the Gob-Side Coal–Rock Roadway in Gently Inclined Coal Seam
No full textIn order to reveal the influence law of coal seam dip angle on the stability of the surrounding rock of the gob-side coal–rock roadway in a gently inclined coal seam (GCRGICS), the deformation characteristics of the surrounding rock under four different coal seam dip angles of this kind of roadway were studied by field investigation, theoretical analysis and numerical simulation. The results showed that, with the increase of the coal seam dip angle, the amount of the roadway roof subsidence and the deformation of the upper and lower side arc triangle coal along the coal–rock interface increased, and the maximum deformation was 479 and 950 mm, respectively, and the maximum slip deformation area gradually shifted from the upper side arc triangle coal to the lower side arc triangle coal. The asymmetric deformation characteristics of the surrounding rock became more and more obvious. The asymmetric deformation rate of the GCRGICS showed a V-shaped variation relationship with the coal seam dip angle, when the coal seam dip angle was 10°, the asymmetric deformation rate was the minimum, only 1.1%. The plastic zone of the surrounding rock expanded with the increase of the coal seam dip angle, and the new extension range was mainly located in the roof area of the roadway
Robotic Grasping Detection Algorithm Based on 3D Vision Dual-Stream Encoding Strategy
No full textThe automatic generation of stable robotic grasping postures is crucial for the application of computer vision algorithms in real-world settings. This task becomes especially challenging in complex environments, where accurately identifying the geometric shapes and spatial relationships between objects is essential. To enhance the capture of object pose information in 3D visual scenes, we propose a planar robotic grasping detection algorithm named SU-Grasp, which simultaneously focuses on local regions and long-distance relationships. Built upon a U-shaped network, SU-Grasp introduces a novel dual-stream encoding strategy using the Swin Transformer combined with spatial semantic enhancement. Compared to existing baseline methods, our algorithm achieves superior performance across public datasets, simulation tests, and real-world scenarios, highlighting its robust understanding of complex spatial environments
Effects of precursor concentration on morphologies of Cu2O micro/nanocrystals and properties of CO self-sustained catalytic combustion
No full textThe self-sustained catalytic combustion is one of the most effective ways to remove high concentration CO at low temperature. In this paper, Cu2O micro/nanocrystals with different morphologies were successfully synthesized by changing the precursor concentration using liquid phase reduction method. The obtained Cu2O were characterized using SEM, XRD, XPS, H-2-TPR and O-2-TPD, and the relationship between the catalytic performance and morphology was analyzed based on CO-TPD-MS and activity evaluation results. It was found that high precursor concentration leads to more exposure of active crystal planes of Cu2O. Compared with Cu2O-1 exposing only (100) crystal planes, Cu2O-5, the precursor concentration of which is 5 times of Cu2O-1, exposes (100) and (110) crystal planes. Cu2O-9, with 9 times of precursor concentration of Cu2O-1, exposes (100), (110) and (1 1 1) crystal planes simultaneously. All the obtained Cu2O with different precursor concentrations can achieve self-sustained CO catalytic combustion, and the catalytic activity increases with increasing precursor concentration (Cu2O-1 < Cu2O-5 < Cu2O-9). The results prove that unsaturated coordination of Cu and O on the (1 1 1) and (1 1 0) planes can enhance the corresponding reducibility, adsorption and activation of gaseous oxygen, consequently promoting the CO oxidation to CO2 over Cu2O-9
Self-sustained combustion of CO with transient changes and reaction mechanism over CuCe0.75Zr0.25O delta powder for honeycomb ceramic catalyst
No full textA CuCe0.75Zr0.25O delta catalyst was prepared by the sol-gel method and successfully coated on honeycomb ceramic (HC) carrier. The activity of CuCe0.75Zr0.25O delta/HC was determined by the CO-TPO + FLIR, with the results performing that the critical condition for CO self-sustained combustion is 3 vol% CO + 3 vol% O-2/N-2 at 0.5 L/min. As the CO concentration increases from 1 vol% CO to 3 vol% CO, the induction process ( T-15) shifts to rapid ignition with a transient change for the CO oxidation reaction. The furnace temperature for CO self-sustained combustion decreases with increasing the CO and O-2 concentrations. Upon increasing the CO2 concentration, however, furnace temperature is needed to increase and realize CO complete conversion. The thermal stability test combined with SEM + EDX results indicate that the CuCe0.75Zr0.25O delta/HC retains an excellent thermal stability after a 200 h, and the high-temperature region remains at 225 +/- 1 degrees C during the CO self-combustion reaction. The activity of catalyst is reduced slightly after the 200 h test because of the carbon deposition on the catalyst surface, but such a slight deactivation can be eliminated by the air oxidation method. In situ IR results show a competitive adsorption of CO/O-2 and CO2 on the Cu-Ce active sites, indicating that the addition of gaseous CO2 performs an inhibition of CO oxidation. CO preferentially adsorbs linearly at Cu+ sites to form carbonyls that react with lattice oxygen to produce CO2 to release, which can be ascribed to M-K mechanism. The L-H mechanism is less important, which involves the relatively weak reaction of adsorbed CO and adsorbed oxygen on the Cu-Ce active sites to form carbonate species
Synthesis of Cu2O micro/nanocrystals for catalytic combustion of high-concentration CO: The crucial role of glucose
No full textCubic Cu2O micro/nanocrystals were successfully synthesized by liquid-phase reduction using copper salt of CuSO4 or CuCl2.2H2O, and glucose or ascorbic acid as reducing agent, respectively. The activity of the catalysts was evaluated by light-off curves of CO self-sustained catalytic combustion via temperature-programmed oxidation of CO (CO-TPO), with the results showing the activity of catalysts following the order of Cu2O-ClGLU > Cu2O-S-GLU > Cu2O-S-AA > Cu2O-Cl-AA, (Cl denotes CuCl2.2H2O, GLU denotes glucose, S denotes CuSO4 and AA denotes ascorbic acid, respectively), corresponding to the ignition temperature of 109 degrees C, 122 degrees C, 137 degrees C and 186 degrees C, respectively. The crystal structure, elemental valence, morphology and redox property of the prepared catalysts were analyzed by using various characterization techniques. Combined with in situ infrared spectrum, the CO self-sustained catalytic combustion over Cu2O catalysts mainly follows the Mars-van-Krevelen (M-v-K) mechanism: the adsorbed and activated CO reacts with lattice oxygen to yield CO2 and oxygen vacancy, and then the oxygen vacancy can be replenished by gaseous oxygen. Combined with catalytic performance of high-concentration CO, it is found that the catalysts prepared using glucose as reducing agent are more angular compared with ascorbic acid. The Cu2O-Cl-GLU synthesized with glucose and CuCl2.2H2O exhibits the best catalytic activity among all the catalysts tested, attributing to its more obvious edge and rough crystal surface. The unique structure of Cu2O-Cl-GLU leads to the high exposure rate and coordination unsaturation of atoms on the cubic Cu2O micro/nanocrystals that can improve the ability of activating gaseous O2 and low temperature reducibility, and consequently facilitating the catalytic activity
Physical Similarity Simulation of Deformation and Failure Characteristics of Coal-Rock Rise under the Influence of Repeated Mining in Close Distance Coal Seams
No full textAiming at the problem that it is difficult to achieve accurate laying of model and precise excavation of roadways in special surrounding rock structure roadway according to conventional physical similarity simulation, which reduces the reliability of experimental results. An accurate laying of model and precise excavation of roadway method, named “labeling positioning and drawing line, presetting roadway model” (LPDLPRM), was proposed. The physical similarity simulation of deformation and failure characteristics of surrounding rock of coal-rock rise, under the influence of repeated mining in close distance coal seams, was carried out based on the method and infrared detection. The results show that the coal-rock rise in close distance coal seams was affected by repeated mining disturbances, and the surrounding rock of coal-rock rise was characterized by obvious asymmetric deformation, specific for the stress and strain near the coal pillar were higher than that of other parts, and cracks near the coal pillar were denser than other parts; when the coal seam is mined in which the coal-rock rise is located, the stress concentration of the surrounding rock near the rise was weakened by mining pressure relief in the upper coal seam; the stress concentration of the surrounding rock near the rise increases when the coal and the lower coal seam are mined, and the stress on the right side (coal pillar side) near the coal-rock rise was the most concentrated. Therefore, it is important to take measures to strengthen support near the coal pillar and to control asymmetric deformation when the coal-rock rise is influenced by repeated mining
Tracking the Impact of Koch-Carbonylated Organics During the Zeolite ZSM-5 Catalyzed Methanol-to-Hydrocarbons Process
No full textA methanol-based economy offers an efficient solution to current energy transition challenges, where the zeolite-catalyzed methanol-to-hydrocarbons (MTH) process would be a key enabler in yielding synthetic fuels/chemicals from renewable sources. Despite its original discovery over half a century ago over the zeolite ZSM-5, the practical application of this process in a CO2-neutral scenario has faced several obstacles. One prominent challenge has been the intricate mechanistic complexities inherent in the MTH process over the zeolite ZSM-5, impeding its widespread adoption. This work takes a significant step forward by providing critical insights that bridge the gap in our understanding of the MTH process. It accomplishes this by connecting the (Koch-carbonylation-led) direct and dual cycle mechanisms, which operate during the early and steady-state phases of MTH catalysis, respectively. To unravel these mechanistic intricacies, we have performed catalytic and operando (i.e., UV-Vis coupled with an online mass spectrometer) and solid-state NMR spectroscopic-based investigations on the MTH process, involving co-feeding methanol and acetone (cf. a key Koch-carbonylated species), including selective isotope-labeling studies. Our iterative research approach revealed that (Koch-)carbonyl group selectively promotes the side-chain mechanism within the arene cycle of the dual cycle mechanism, impacting the preferential formation of BTX fraction (i.e., benzene-toluene-xylene) primarily.This project has been financially supported by the National Natural Science Foundation of China (NSFC) (Grant No. 22350610243, 22050410276), the Fundamental Research Funds for the Central Universities (Grant No.: 2042023kf0126) (China), King Abdullah University of Science and Technology (Saudi Arabia), the start-up research grant from Wuhan University (China), the China Postdoctoral Science Foundation (2021M702515/2022T150493)
Investigation of the Bearing Characteristics of Bolts on a Coal–Rock Combined Anchor Body under Different Pull-Out Rates
No full textIn order to reveal the influence of the pull-out rate on the load-bearing properties of the coal–rock combined anchor body, the mechanical properties and failure characteristics of a coal–rock combined anchor body under different pull-out rates (10, 20, 30, 40, 50 mm/min) were studied using the pull-out test and theoretical analysis. The results show that the bearing capacity of the bolt on the coal–rock combined anchor body improves under a dynamic load, but the load-bearing properties of the coal–rock combined anchor body are different from those of the full rock (coal) anchor body. With the increase in the pull-out rate, the maximum pull-out load of the bolt on the coal–rock combined anchor body increases first, then decreases, and finally tends to be stable. Under the condition of a low drawing rate, the bearing capacity of the coal–rock combined anchor system can be greatly improved, but when the pull-out rate exceeds 20 mm/min, the bearing capacity of the anchor system is reduced. The debonding process of the anchoring section of the coal–rock combined anchor body gradually expands from the beginning section of the anchor to the bottom of the borehole. The coal–rock combined anchor body undergoes time differential development of cracks, and the failure of the coal and rock mass occurs at different times. Its failure process can be divided into three stages: (1) the coal anchor and rock anchor act together; (2) the rock anchor acts alone; and (3) the coal anchor and rock anchor have residual action
