1,721,030 research outputs found
Role of Facets and Morphologies of Different Bismuth-Based Materials for CO2 Reduction to Fuels
Carbon dioxide (CO2) emission has been a global concern over the past few decades due to the increase in the demand of energy, a major source of which is fossil fuels. To mitigate the emission issues, as well as to find a solution for the energy needs, an ample load of research has been carried out over the past few years in CO2 reduction by catalysis. Bismuth, being an active catalyst both photocatalytically and electrocatalytically, is an interesting material that can be formed into oxides, sulphides, oxyhalides, etc. Numerous works have been published based on bismuth-based materials as active catalysts for the reduction of CO2. However, a proper understanding of the behavior of the active facets and the dependence of morphology of the different bismuth-based catalysts is an interesting notion. In this review, various bismuth-based materials will be discussed regarding their activity and charge transfer properties, based on the active facets present in them. With regard to the available literature, a summarization, including photocatalysis, electrocatalysis as well as photoelectrocatalysis, will be detailed, considering various materials with different facets and morphologies. Product selectivity, varying on morphological difference, will also be realized photoelectrochemically
Recent advances in transition metal sulfide-based electrocatalysts and photocatalysts for nitrogen fixation
Ammonia production through electrocatalytic and photocatalytic N2 fixation approaches has attracted a huge interest as a sustainable and clean route owing to the use of renewable energy to drive the processes. However, these approaches do not fulfil the industrial requirement because of the poor catalytic activity and efficiency of the catalysts. Therefore, rationally designed and highly efficient catalysts are urgently needed. Transition metal sulfide-based catalysts have gained great research interest as promising materials to catalyze artificial ammonia synthesis due to their structural similarity to the active site of the natural nitrogenase. This review gives some insights into the recent progress on the developments of transition metal sulfide-based electrocatalysts and photocatalysts for nitrogen fixation to ammonia under ambient conditions. A prospect on the future develop-ment on the rational design of efficient metal sulfide-based catalysts for artificial N2 fixation is also discussed
Going Beyond Counting First Authors in Author Co-citation Analysis
The present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation
counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings
are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that
only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into
account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed
Variations on the Author
“Variations on the Author” discusses two of Eduardo Coutinho’s recent films (Um Dia na Vida, from 2010, and Últimas Conversas, posthumously released in 2015) and their contribution to the general question of documentary authorship. The director’s filmography is characterized by a consistent yet self-effacing form of authorial self-inscription: Coutinho often features as an interviewer that rather than express opinions propels discourses; an interviewer that is good at listening. This mode of self-inscription characterizes him as an author who is not expressive but who is nonetheless markedly present on the screen. In Um Dia na Vida, however, Coutinho is completely absent form the image, while Últimas Conversas, on the contrary, includes a confessional prologue that moves the director from the margins to the center of his films. This article examines the ways in which these works stand out in the filmography of a director who offers new insights into the notion of cinematic authorship
Appropriate Similarity Measures for Author Cocitation Analysis
We provide a number of new insights into the methodological discussion about author cocitation analysis. We first argue that the use of the Pearson correlation for measuring the similarity between authors’ cocitation profiles is not very satisfactory. We then discuss what kind of similarity measures may be used as an alternative to the Pearson correlation. We consider three similarity measures in particular. One is the well-known cosine. The other two similarity measures have not been used before in the bibliometric literature. Finally, we show by means of an example that our findings have a high practical relevance.information science;Pearson correlation;cosine;similarity measure;author cocitation analysis
Syngas production by short contact time catalytic partial oxidation of methane (Chapter 4)
Dispelling the Myths Behind First-author Citation Counts
We conducted a full-scale evaluative citation analysis study of scholars in the XML research field to explore just how different from each other author rankings resulting from different citation counting methods actually are, and to demonstrate the capability of emerging data and tools on the Web in supporting more realistic citation counting methods. Our results contest some common arguments for the continued
use of first-author citation counts in the evaluation of scholars, such as high correlations between author rankings by first-author citation counts and other citation
counting methods, and high costs of using more realistic citation counting methods that are not well-supported by the ISI databases. It is argued that increasingly available digital full text research papers make it possible for citation analysis studies to go beyond what the ISI databases have directly supported and to employ more
sophisticated methods
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