1,720,999 research outputs found
Supported Metal Nanoparticles for Catalytic and Enrivonmental Applications
No full textTHE FABRICATION OF STABLE SUPPORTED METAL NANOPARTICLES SUITABLE FOR HETEROGENEOUS CATALYSIS OR
ENVIRONMENTAL APPLICATIONS, TO PREVENT NANOPARTICLES AGGREGATION AND TO FACILITATE CATALYST RECYCLING, IS THE
GOAL OF OUR RESEARCH GROUP OF THIS LAST DECADE. THIS PAPER PRESENT CONVENIENT, STRAIGHTFORWARD, EASY METHODS
TO OBTAIN POLYETHYLENEIMINE FUNCTIONALIZED SILICA BEADS, ORGANOSILANE-COATED INDIUM TIN OXIDES OR HYDROPHILIC
NUCLEPORE TRACK-ETCHED POLYCARBONATE MEMBRANES (PC) FUNCTIONALIZED WITH GOLD OR SILVER NANOPARTICLE
Organic transformations catalyzed by gold nanoaparticles supported on functionalized silica
No full textRecently, we presented the preparation, without any need of additional reducing and/or stabilizing
agents, of a variety of stable silica-supported gold nanoparticles (AuNPs) by using as the only
reactants an aqueous solution of chloroauric acid (HAuCl4) and different functionalized-silica
supports. We started using commercial polyethyleneimine-functionalized silica bead and we
went on preparing silica nanoparticles with alkynyl carbamate moieties.
We now present the results of our recent work with supported AuNPs, which has been focused on
the synthesis of a material with the right features for the application as catalyst in a continuous flow
system. Indeed, flow chemistry is recognized by the Green Chemistry Institute (GCI) as a key area
for research activities in the aim of developing sustainable manufacturing.
The silica-supported AuNPs have been prepared by the simple grafting of commercial available
silica with the alkyne terminated organosilane [3-(2-propynylcarbamate)propyl]triethoxysilane
(PPTEOS), followed by the addition of HAuCl4 to obtain the in situ formation of the target AuNPsanchored
systems. The resulting material (Au/SiO2@Yne) has been characterized with various
techniques, such as atomic absorption spectroscopy (AAS), transmission electron microscopy
(TEM) and thermogravimetric analysis (TGA). Afterwards, Au/SiO2@Yne has been employed as
heterogeneous catalyst in the oxidation of alcohols to their corresponding carbonyl compounds. The
reaction conditions have been chosen with particular attention to the green aspect, therefore the
oxidation have been carried out using a mixture of tert-butanol and water as solvent and hydrogen
peroxide as the oxidant agent
Going Beyond Counting First Authors in Author Co-citation Analysis
Get PDFThe present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation
counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings
are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that
only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into
account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed
Variations on the Author
Get PDF“Variations on the Author” discusses two of Eduardo Coutinho’s recent films (Um Dia na Vida, from 2010, and Últimas Conversas, posthumously released in 2015) and their contribution to the general question of documentary authorship. The director’s filmography is characterized by a consistent yet self-effacing form of authorial self-inscription: Coutinho often features as an interviewer that rather than express opinions propels discourses; an interviewer that is good at listening. This mode of self-inscription characterizes him as an author who is not expressive but who is nonetheless markedly present on the screen. In Um Dia na Vida, however, Coutinho is completely absent form the image, while Últimas Conversas, on the contrary, includes a confessional prologue that moves the director from the margins to the center of his films. This article examines the ways in which these works stand out in the filmography of a director who offers new insights into the notion of cinematic authorship
Appropriate Similarity Measures for Author Cocitation Analysis
Get PDFWe provide a number of new insights into the methodological discussion about author cocitation analysis. We first argue that the use of the Pearson correlation for measuring the similarity between authors’ cocitation profiles is not very satisfactory. We then discuss what kind of similarity measures may be used as an alternative to the Pearson correlation. We consider three similarity measures in particular. One is the well-known cosine. The other two similarity measures have not been used before in the bibliometric literature. Finally, we show by means of an example that our findings have a high practical relevance.information science;Pearson correlation;cosine;similarity measure;author cocitation analysis
Dispelling the Myths Behind First-author Citation Counts
Get PDFWe conducted a full-scale evaluative citation analysis study of scholars in the XML research field to explore just how different from each other author rankings resulting from different citation counting methods actually are, and to demonstrate the capability of emerging data and tools on the Web in supporting more realistic citation counting methods. Our results contest some common arguments for the continued
use of first-author citation counts in the evaluation of scholars, such as high correlations between author rankings by first-author citation counts and other citation
counting methods, and high costs of using more realistic citation counting methods that are not well-supported by the ISI databases. It is argued that increasingly available digital full text research papers make it possible for citation analysis studies to go beyond what the ISI databases have directly supported and to employ more
sophisticated methods
koamabayili/VECTRON-author-checklist: VECTRON author checklist
No full textWe have done our best to complete the author checklist relating to the use of animals in the hut study. Note that the objective for the hut study was to evaluate the IRS treatment applications for residual efficacy against Anopheles mosquitoes, including the local An. coluzzii mosquito population. Cows were only used to attract mosquitoes into the huts and no tests were carried out directly on the cows. The author checklist is intended for use with studies where experiments are carried out on animals, which is why we have had such difficulty in completing this for the hut study, as many of the questions do not relate to how the cows were used
Author-wise bibliometric analysis based on entropy.
No full textAuthor-wise bibliometric analysis based on entropy.</p
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