1,721,022 research outputs found

    Le massif du Gran Sasso. Abruzze, Italie centrale Synthèse hydrogéologique, par m. Petitta & M. Tallini, 2002

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    Nicod Jean. Le massif du Gran Sasso. Abruzze, Italie centrale Synthèse hydrogéologique, par m. Petitta & M. Tallini, 2002. In: Karstologia : revue de karstologie et de spéléologie physique, n°42, 2e semestre 2003. Les cavités glaciaires sous le regard des spéléologues. pp. 55-56

    Le massif du Gran Sasso. Abruzze, Italie centrale Synthèse hydrogéologique, par m. Petitta & M. Tallini, 2002

    No full text
    Nicod Jean. Le massif du Gran Sasso. Abruzze, Italie centrale Synthèse hydrogéologique, par m. Petitta & M. Tallini, 2002. In: Karstologia : revue de karstologie et de spéléologie physique, n°42, 2e semestre 2003. Les cavités glaciaires sous le regard des spéléologues. pp. 55-56

    Innovative methodology for quantitative and qualitative assessment of water resources in karst aquifers: a case study in southern Lazio region, central Italy

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    This paper outlines the results of a hydrogeological study carried on from July 2014 to November 2106 to assess quantitatively and qualitatively water resources (groundwater and surface water) emerging in the Upper Valley of the Aniene River (Latium Region, Central Italy). This work deals with the Environmental Monitoring Plan, related to the catchment project of the Pertuso Spring, which is going to be exploited to supply an important water network in the South part of Roma district. The study area is located in the Upper Valley of the Aniene River, in the outcrop of Triassic-Cenozoic carbonate rocks, and belong to an important karst aquifer. Pertuso Spring is the main outlet of this karst aquifer and is the one of the most important water resource in the southeast part of Latium Region, used for drinking, agriculture and hydroelectric supplies. This hydrogeological system is characterized by a strong local hydraulic connectivity between the Aniene River surface water and groundwater coming from the Pertuso Spring. First at all, in this study, in order to estimate the vulnerability degree of the karst aquifer feeding the Pertuso Spring, the COP method has been applied and vulnerability maps are proposed. Thus, with the aim of highlighting the karst features key-role in the unsaturated zone, a new vulnerability approach has been set up, starting from two discretization approaches. The aim of this work is to compare both results of the intrinsic vulnerability mapping, in order to evaluate which one is the most suitable for the study area. On the basis of the hydrogeochemical data and their interpretations for groundwater and surface water, monitored from July 2014 to November 2016, a hydrogeological study has been carried on to identify flowpaths and hydrogeochemical processes governing groundwater-surface water interactions in this region. To this end, discharge surveys were carried out on four monitoring sections along the Aniene River. The proposed conceptual model shows that the karst aquifer feeding the Pertuso Spring supplies the Aniene River, highlighting seasonal variability depending on the rainfall regime. The analysis of solute contents in the monitoring points has suggested the identification of the Magnesium ion as a conservative tracer in this specific system and, consequently, to the development an indirect method for the evaluation of karst spring discharge based on discharge measurements and water geochemical data. This method is based on the elaboration of surface water discharge measurements in relationship with Mg2+ concentration values, determined as for groundwater, coming from the Pertuso Spring, as for surface water samples, collected upstream and downstream the spring, along the Aniene River streamflow. This method has been validated by the comparison with discharge values obtained using the current meter method and by geochemical data. This study suggests that the application of the Magnesium ion as an environmental tracer may provide a means to evaluate discharge of the Pertuso Spring, as it came up to be a marker of the mixing of surface water and groundwater. On the other hand, the Magnesium ion concentration provides information for the identification of groundwater flow systems and the main hydrogeochemical processes affecting the composition of water within the karst aquifer feeding the Pertuso Spring

    Arsenic speciation in a contaminated coastal aquifer below a former fertilizer production plant

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    Inorganic arsenic has been widely used during the production cycle of fertilizers and pesticides and leakage into sub-soils and shallow groundwater has been reported in the recent literature (Root et al. 2009; Cancés et al. 2005). Despite of this, most of the scientific papers has been focused on natural arsenic mobilization and geochemical cycling in the subsurface (Hering J. G. and Kneebone 2002; Lin and Puls 2003). Thus, more studies are still needed to understand the mobilization/immobilization mechanisms of arsenic in highly contaminated sites. Since the arsenic mobilization is usually driven by redox processes, pH changes and ionic strength of the solutions (Smedley and Kinniburgh 2002), it is foremost important to study its behavior in coastal aquifers where all of these factors essentially coincide. In fact, like for the surface waters, the groundwater mixing zone can affect the biogeochemical cycling of metals and nutrients, which are sensitive to changes in salinity and redox potential (Slomp et al. 2004). The study site is a former fertilizer plant located near the shore line, in Italy. The overall groundwater geochemistry at the study site has been documented in a previous paper (Mastrocicco et al. 2011). Within this framework, a detailed characterization of arsenic in groundwater was performed to elucidate the mobilization/immobilization mechanisms actually occurring at the site

    Density dependent transport modelling of Total Chlorinated Hydrocarbons to evaluate the remediation strategy in a Megasite

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    The calibrated tridimensional flow and transport model was a useful tool to assess the efficacy of the remediation strategy employed: the model showed that TCH were confined within the Megasite boundaries despite the presence of scattered residual DNAPL source zones. The shape of TCH plumes was primarily influenced by the saltwater wedge location, with the highest TCH concentrations located in the upper part of the aquifer near the shore line. To further improve TCH recovery and mitigate saltwater intrusion, shallow wells might be employed near the sea boundary

    Coastal aquifer contamination by arsenic and phosphorous from a fertilizer production plant

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    Inorganic arsenic has been widely used during the production cycle of fertilizers and pesticides and leakage into subsoils and shallow groundwater has been reported in the recent literature. Despite of this, most of the scientific papers have focused on natural arsenic mobilization and geochemical cycling in the subsurface. Since the arsenic mobilization is usually driven by redox processes, pH changes and ionic strength of the water, it is of foremost importance to study its behavior in coastal aquifers where all of these factors essentially coincide. The study site is a former fertilizer plant located near the shore line in Italy, where a pump and treat remediation scheme has been active since 2001. A detailed characterization of arsenic in groundwater was performed to elucidate the mobilization/immobilization mechanisms actually occurring at the site. It was found that most of the arsenic was entrapped in the sediments located near to the source zone, while phosphorous (mainly phosphate) migrated further downstream. A marked vertical reverse trend of EC and Eh was found within the aquifer: the elevated EC was due to the seawater wedge intrusion enhanced by pumping wells, while anoxic conditions were due to organic matter oxidation by sulphate provided by seawater. The arsenic speciation in groundwater showed the net predominance of As(III) except in the upper portion of the aquifer, where post-oxic condition occurred due to continuous oxygen exchange with the vadose zone. In the deeper portion of the aquifer the As(III) concentrations increased up to 900 μg/l, while As(V) remained stable. This feature was probably due to the elevated ionic strength of deep groundwater, which can displace weakly bonded oxianions from exchange sites and also by reducing conditions which promoted As(III) mobilization. Phosphate was present almost only in groundwater due to the reducing conditions of the aquifer. This characterization confirmed that two different mechanisms for arsenic fate were active: (i) the oxidation and consequent sequestration in the upper oxidized zone, near the water table, with a marked decrease of total arsenic in groundwater with respect to the aquifer bottom, where (ii) the reduced and salinized conditions gave rise to very high arsenic concentrations with As(III) as the main groundwater species

    Intrinsic vulnerability uncertainties due to climatic variability and soil permeability in the Fucino plain (IT)

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    Reactive nitrogen losses from agricultural activities are a global problem and its management requires an integrated interdisciplinary approach. Throughout the world, alluvial plains are usually the most impacted regions by nitrate pollution and especially by nitrate groundwater contamination. This study shows that climatic variability in this small alluvial plain affects LOS indices results less than ks uncertainties. The application of LOS indices showed its aptitude to adequately represent the intrinsic vulnerability to nitrogen and water losses in agricultural alluvial plains

    Bias between flowmeter measurements and numerical model in a contaminated coastal aquifer

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    During the characterization of the subsurface fluxes, the use of different techniques (geophysical, hydrological, hydrochemical) usually help to understand the processes taking place within the aquifer (Schürch & Buckley 2002). Generally, low-permeability, non-reactive, horizontal flow barriers (HFBs) are used to contain contaminants in aquifer and prevent further spreading of contaminants in groundwater. Grout curtains HFBs, which are the focus of this study, are supposed to be impermeable. Barriers are typically used in conjunction with interior and exterior extraction wells to help maximize containment inside the barrier and capture leakage outside the barrier (U.S. Environmental Protection Agency, 1996)

    Going Beyond Counting First Authors in Author Co-citation Analysis

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    The present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed
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