313 research outputs found

    SPECTROSCOPY OF VIBRATIONALLY EXCITED STATES OF CCH

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    1. Y.-C. Hsu, J. J.-M. Lin, D. Papoušek, and J.-J. Tsai, J. Chem. Phys. 98, 6690(1993). 2. Y.-C. Hsu, Laser Techniques for State-Selected and State-to-State Chemistry II Proceedings of SPIE conference, 2124, 302(1994). 3. Y.-C. Hsu, Y.-J. Shiu and C.-M. Lin, J. Chem. Phys. (to be submitted).Author Institution: Academia Sinica, P. O. Box 23-166, Taipei 107, Taiwan, Republic of China.; National Taiwan University, Taipei 107, Republic of China.By laser-induced fluorescence (LIF), we previously detected 22 UV bands due to transitions from vibrationally excited states of CCH(X~2Σ+)CCH(\tilde{X}^{2}\Sigma^{+}) to B~2A.13\tilde{B}^{2}A.^{1-3} Five new bands of parallel-type transitions are rotationally analyzed. The LIF spectrum of the 35929, 36658 and 36821cm136821 cm^{-1} bands were obtained after photolysis at 193 nm of a supersonic beam of argon seeded with acetylene; two other bands at 38360 and 38452cm138452 cm^{-1}, assigned as SX~(0,20,0)S \leftarrow \tilde{X} (0,2^{0},0) and VX~(0,22,0)V \leftarrow \tilde{X} (0,2^{2},0), were recorded after photolysis at 193 nm of a mixture of acetylene and SF6SF_{6} at high pressure. States S and V represent K=0 and 2 stacks of a single vibrational level T, located at 39157.4126(51)cm139157.4126(51) cm^{-1}, of B~2A\tilde{B}^{2} A. Gating at the fluorescence lifetime enables us to separate weak bands of CCH from C2C_{2}. Methods of obtaining vibrationally cooled CCH will be discussed

    Leiopus (Carinopus) nigrofasciculosus Wallin, Kvamme & Lin, 2012, sp. nov.

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    Leiopus (Carinopus) nigrofasciculosus sp. nov. Figs. 13, 14, 31, 38, 52, 63, 77, 91. Type locality: China, S Shaanxi, Xi'an-Ningshan, Qinling Shan. Holotype: Male (body length 8.2 mm, width 2.7 mm), S. Shaanxi, Xi'an-Ningshan, Qinling Shan pass, 50 km S Xi'an, altitude 2000 m, 33 °08' N, 108 °08' E, 2000.06. 11, leg. J. Turna, CCH with identity = 1.124. Paratype: 1 female, SW Anhui, Yuexi Co., Miaodaoshan mountains, altitude 600–1300 m, 30 ° 48–50 ' N 116 °05' E, 1995.07.18– 20, leg. L & R. Businsky, CCH. 1 female, Anhui, Huangshan, 1977.07. 19, leg. Huang Ju, CAU.Published as part of Wallin, Henrik, Kvamme, Torstein & Lin, Meiying, 2012, A review of the genera Leiopus Audinet-Serville, 1835 and Acanthocinus, Dejean, 1821 (Coleoptera: Cerambycidae, Lamiinae, Acanthocinini) in Asia, with descriptions of six new species of Leiopus from China, pp. 1-36 in Zootaxa 3326 on page 12, DOI: 10.5281/zenodo.28120

    LASER SPECTROSCOPY OF CCH IN THE 3660039700cm136600-39700 cm^{-1} REGION

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    a^{a}Y.-C. Hsu, J. J.-M. Lin, D. Papousˉ\bar{s}ek, and J.-J. Tsai, J.Chem. Phys. 98, 6690(1993). b^{b} Y.-C. Hsu, Y.-J. Shiu, and C.-M. Lin, J. Chem. Phys. 103, 5919(1995).Author Institution: Institute of Atomic and Molecular Sciences; Department of ChemistryIn the 3660039700cm136600-39700 cm^{-1} range, eight new bands of CCH B2AX~2ΣB^{2}A^{\prime}\leftarrow \tilde{X}^{2}\Sigma transition were observed by laser-induced fluorescence. By rotational analysis, they have been assigned as transitions from low vibronic levels, X~(0,v2,v3)(v2=24\tilde{X}(0, v_{2}, v_{3}) (v_{2}=2-4 and v3=01v_{3}=0-1) of CCH to two vibrational levels (T, T+1221) of the B~\tilde{B} state. Most of these bands were difficult to be detected if a acetylene/argon or helium gas mixture was photolyzed to produce CCH. Due to population transfer, via collisions with SF6SF_{6}, from higher vibronic levels of CCH which were predominantly produced in the 193.3 nm photolysis of acetylene, spectral intensities of these bands were thus enhanced. Spectroscopic parameters of X~(0,20,0),X~(0,22,0),X~(0,22,1)\tilde{X}(0,2^{0}, 0),\tilde{X}(0,2^{2}, 0),\tilde{X}(0,2^{2},1) and B~(T+1221)\tilde{B}(T+1221) were obtained for the first time. Spectral lines of transition B~(T)X~(0,30,3,0)\tilde{B}(T)\leftarrow\tilde{X}(0, 3^{0,3}, 0) recorded in a supersonic beam were also included in a simultaneous fit, spectroscopic parameters of X~(0,30,3,0)\tilde{X}(0, 3^{0,3},0) were accordingly better determined in this work than our previous reports.a,breports.^{a,b} The vibronic energy levels X~(0,v2,v3)(v3=02)\tilde{X}(0, v_{2}, v_{3})(v_{3}=0-2) of CCH up to 5500cm15500 cm^{-1} were approximated as three anharmonic oscillators, where v2v_{2} is 401 cm. The anharmonicities and 911#### obtained from the fit will be given

    NEGATIVE ANHARMONICITIES OF THE BENDING VIBRATION OF CCH AND THE TRANS-BENDING VIBRATION OF THE ACETYLENE CATION

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    1. E. Hirota, Chem. Rev. 92, 141 (1992). 2. Y.-C. Hsu, J. J.-M. Lin, D. Papoušek, and J. -J. Tsai, J. Chem. Phys. 98, 6690 (1993).Author Institution: Academia Sinica, P. O. Box 23-166, Taipei, 107, Taiwan Republic of China; National Taiwan University, Taipei, 107, Republic of China.The levels of the bending vibration (ν2=111)(\nu_{2} = 1-11) of CCH(X~2Σ+)CCH (\tilde{X}^{2}\Sigma^{+}) were determined by UV laser-induced fluorescence of the products of photolysis of acetylene at 193 nm. Large negative anharmonicity was found in the lowest five levels of the bending vibration. As the number of bending quanta increases, the anharmonicity decreases considerably. Levels ν4=05\nu_{4} = 0-5 of the trans-bending motion of the acetylene cation (X~2Πu)(\tilde{X}^{2}\Pi_{u}), isoelectronic with CCH1CCH_{1} and its deuterated isotopomer have been determined by 1 + 1 PFI-ZEKE spectroscopy via a single rovibronic level of A~1Au\tilde{A}^{1} A_{u} as an intermediate. Spectral analysis shows that negative anharmonicity was also present in the latter case. Large negative anharmonicity of CCH is attributed to vibronic interaction1interaction^{1} between A~2Π\tilde{A}^{2}\Pi and X~2Σ+\tilde{X}^{2}\Sigma^{+} as well as vibration-rotational interaction among the vibrational levels of the X~\tilde{X} state.2state.^{2}. The potential-energy curve of the bending vibration of CCH (X~)(\tilde{X}) and that of the trans-bending vibration of C2H2C_{2}H_{2} calculated by an ab initio method will be presented to show that negative anharmonicities of these molecules may be due to the flatness of the (zero-order) potential-energy curves. The Renner-Teller effect of the trans-bending vibration of the acetylene cation will be discussed

    Leiopus (Carinopus) ocellatus Wallin, Kvamme & Lin, 2012, sp. nov.

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    Leiopus (Carinopus) ocellatus sp. nov. Figs. 11, 12, 30, 37, 51, 62, 76, 90. Type locality: China, Shaanxi, Qinling Shan, Xunyangba. Holotype: Male (length 7.6 mm, width 2.6 mm), C-China, Shaanxi, Qinling Shan, 6 km E of Xunyangba, altitude 1000–1300 m, 2000.05.23–06.13, leg. C. Holzschuh, CCH with identity = 1.123. Paratypes: 3 females, C-China, Shaanxi, Qinling Shan, 6 km E of Xunyangba, altitude 1000–1300 m, 2000.05.23–06.13, leg. C. Holzschuh, CCH; 1 female, Shaanxi, Ningshan, Huoditang, altitude 1580 m, 1998.08. 22, IZAS, IOZ (E) 1858417; 1 female, Shaanxi, Ningshan, Huodigou, altitude 1580–2000 m, 1998.08. 18, leg. Yuan Decheng, IZAS, IOZ (E) 1858418. 1 male, Shaanxi, Shiquan, 1960.06.0 3, IZAS, IOZ (E) 1859440.Published as part of Wallin, Henrik, Kvamme, Torstein & Lin, Meiying, 2012, A review of the genera Leiopus Audinet-Serville, 1835 and Acanthocinus, Dejean, 1821 (Coleoptera: Cerambycidae, Lamiinae, Acanthocinini) in Asia, with descriptions of six new species of Leiopus from China, pp. 1-36 in Zootaxa 3326 on page 11, DOI: 10.5281/zenodo.28120

    Leiopus (Carinopus) flavomaculatus Wallin, Kvamme & Lin, 2012, sp. nov.

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    Leiopus (Carinopus) flavomaculatus sp. nov. Figs. 9, 10, 29, 36, 50, 61, 75, 89. Type locality: China, Guizhou, Leigong Shan, Leishan-Fangxiang. Holotype: Male (length 7.6 mm, width 2.5 mm) China, Prov. Guizhou SE Kaili, Leishan Co., Leigong Shan, pass Leishan-Fangxiang, N 26 ° 22 ' 7 '', E 108 ° 12 ' 99 '', altitude 1700 m, 2001.06.14– 24, leg. C. Holzschuh, CCH with identity = 1.122. Paratypes: 1 male and 1 female, China, Prov. Guizhou SE Kaili, Leishan Co., Leigong Shan, pass Leishan- Fangxiang, N 26 ° 22 ' 7 '', E 108 ° 12 ' 99 '', altitude 1700 m, 2001.06.14– 24, leg. C. Holzschuh, CCH.Published as part of Wallin, Henrik, Kvamme, Torstein & Lin, Meiying, 2012, A review of the genera Leiopus Audinet-Serville, 1835 and Acanthocinus, Dejean, 1821 (Coleoptera: Cerambycidae, Lamiinae, Acanthocinini) in Asia, with descriptions of six new species of Leiopus from China, pp. 1-36 in Zootaxa 3326 on page 9, DOI: 10.5281/zenodo.28120
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