1,720,962 research outputs found
Ab initio thermal expansion and thermoelastic properties of ringwoodite ( γ-Mg2SiO4) at mantle transition zone conditions
Full text linkThermal convection in the Earth's mantle is driven by lateral variations in temperature and density, which are substantially controlled by the local volume thermal expansion of the constituent mineral phases. Ringwoodite is a major component of the lower mantle transition zone, but its thermal expansivity and thermoelastic properties are still affected by large uncertainties. Ambient thermal expansion coefficient (αV0ggggggg), for instance, can vary as much as 100g% according to different experimental investigations available from the literature. In this work, we perform ab initio density functional theory calculations of vibrational properties of spinel-structured Mg2SiO4 ringwoodite in order to provide reliable thermophysical data up to mantle transition zone conditions. Temperature- and pressure-dependent thermal expansivity has been obtained by phonon dispersion calculations in the framework of quasi-harmonic approximation (QHA) up to 25gGPa and 2000gK. Theoretical analysis of vibrational spectra reveals that accurate prediction of IR and silent modes, along with their relative mode Grüneisen parameters, is crucial to define thermal expansivity. A six-parameter analytical function is able to reproduce ab initio values fairly well in the whole investigated P-T range, i.e., αV(P,T)Combining double low line(1.6033×10-5+8.839×10-9T+11.586×10-3T-1-6.055T-2+804.31T-3)g×expĝ (-2.52×10-2P), with temperature in kelvin and pressure in gigapascal. Ab initio static and isothermal bulk moduli have been derived for ringwoodite along with their P, T and cross derivatives, i.e., K0gCombining double low lineg184.3gGPa, KT,300KgCombining double low lineg176.6gGPa, K0′gCombining double low lineg4.13, KT,300K′gCombining double low lineg4.16, g KTg TPgCombining double low lineg-0.0233gGPagK-1 and g 2KTg Pg T0Combining double low line1.0×10-4gK-1. Computed thermal expansivity and thermoelastic properties support the evidence that QHA performs remarkably well for Mg2SiO4 ringwoodite up to mantle transition zone temperatures. Since volume thermal expansion of ringwoodite is strongly pressure-dependent and its pressure dependence becomes more marked with the increasing temperature, internally consistent assessments and empirical extrapolation of thermoelastic data to deep mantle conditions should be taken with care to avoid inaccurate or spurious predictions in phase equilibrium and mantle convection numerical modeling
Commensurate Growth of Magnetite Microinclusions in Olivine under Mantle Conditions
No full textMagnetite-bearing multiphase solid inclusions hosted in metamorphic olivine have been interpreted as final products of the trapping of the aqueous fluid produced by the subduction-zone dehydration of former serpentinites. We provide here a careful analysis performed by microfocus single-crystal X-ray diffraction of inclusions found in harzburgites from the Almirez Complex (Bétic Cordillera, Spain) to determine the occurrence of preferential crystallographic orientation relationships between the olivine host and the magnetite inclusion. The results demonstrate that the magnetite-olivine interface selectively displays parallelism between crystallographic planes (111) and (100) and between crystallographic directions ⟨110»and ⟨011⟩, respectively. This evidence points to a clear epitaxial growth of magnetite on olivine. The calculation of the geometrical misfit between the two lattices in contact as a function of their relative azimuthal orientation shows that, under the aforementioned reciprocal orientation, a perfect commensurism is achieved; i.e., all of the nodes of the magnetite lattice coincide with nodes of the olivine lattice. This particular relationship must be interpreted as a unique occurrence, playing a fundamental role in favoring the heterogeneous nucleation of magnetite on olivine
Going Beyond Counting First Authors in Author Co-citation Analysis
Full text linkThe present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation
counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings
are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that
only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into
account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed
Epitactic magnetite growth in fluid inclusions as driving force for olivine oxidation coupled with hydrogen production at high pressure
No full textVariations on the Author
Full text link“Variations on the Author” discusses two of Eduardo Coutinho’s recent films (Um Dia na Vida, from 2010, and Últimas Conversas, posthumously released in 2015) and their contribution to the general question of documentary authorship. The director’s filmography is characterized by a consistent yet self-effacing form of authorial self-inscription: Coutinho often features as an interviewer that rather than express opinions propels discourses; an interviewer that is good at listening. This mode of self-inscription characterizes him as an author who is not expressive but who is nonetheless markedly present on the screen. In Um Dia na Vida, however, Coutinho is completely absent form the image, while Últimas Conversas, on the contrary, includes a confessional prologue that moves the director from the margins to the center of his films. This article examines the ways in which these works stand out in the filmography of a director who offers new insights into the notion of cinematic authorship
Appropriate Similarity Measures for Author Cocitation Analysis
Full text linkWe provide a number of new insights into the methodological discussion about author cocitation analysis. We first argue that the use of the Pearson correlation for measuring the similarity between authors’ cocitation profiles is not very satisfactory. We then discuss what kind of similarity measures may be used as an alternative to the Pearson correlation. We consider three similarity measures in particular. One is the well-known cosine. The other two similarity measures have not been used before in the bibliometric literature. Finally, we show by means of an example that our findings have a high practical relevance.information science;Pearson correlation;cosine;similarity measure;author cocitation analysis
Dispelling the Myths Behind First-author Citation Counts
Full text linkWe conducted a full-scale evaluative citation analysis study of scholars in the XML research field to explore just how different from each other author rankings resulting from different citation counting methods actually are, and to demonstrate the capability of emerging data and tools on the Web in supporting more realistic citation counting methods. Our results contest some common arguments for the continued
use of first-author citation counts in the evaluation of scholars, such as high correlations between author rankings by first-author citation counts and other citation
counting methods, and high costs of using more realistic citation counting methods that are not well-supported by the ISI databases. It is argued that increasingly available digital full text research papers make it possible for citation analysis studies to go beyond what the ISI databases have directly supported and to employ more
sophisticated methods
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